Home / Publications / Amberlyst-15 as a highly efficient and regenerative catalyst in the one-pot synthesis of areno[d][1,2]oxaphospholes

Amberlyst-15 as a highly efficient and regenerative catalyst in the one-pot synthesis of areno[d][1,2]oxaphospholes

Makar А Zaborsky 1
Makar А Zaborsky
Dmitry Anatol'evich Tatarinov 1, 2
Dmitry Anatol'evich Tatarinov
Rezeda М Salakhova 1
Rezeda М Salakhova
Eliza Е Baynazarova 1
Eliza Е Baynazarova
Olga B Babaeva 2
Olga B Babaeva
Vladimir Fedorovich Mironov
Published 2026-02-03
CommunicationVolume 36, Issue 2, 161-163
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Zaborsky M. А. et al. Amberlyst-15 as a highly efficient and regenerative catalyst in the one-pot synthesis of areno[d][1,2]oxaphospholes // Mendeleev Communications. 2026. Vol. 36. No. 2. pp. 161-163.
GOST all authors (up to 50) Copy
Zaborsky M. А., Tatarinov D. A., Salakhova R. М., Baynazarova E. Е., Babaeva O. B., Khayarov K. R., Mironov V. F. Amberlyst-15 as a highly efficient and regenerative catalyst in the one-pot synthesis of areno[d][1,2]oxaphospholes // Mendeleev Communications. 2026. Vol. 36. No. 2. pp. 161-163.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.71267/mencom.7893
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7893
TI - Amberlyst-15 as a highly efficient and regenerative catalyst in the one-pot synthesis of areno[d][1,2]oxaphospholes
T2 - Mendeleev Communications
AU - Zaborsky, Makar А
AU - Tatarinov, Dmitry Anatol'evich
AU - Salakhova, Rezeda М
AU - Baynazarova, Eliza Е
AU - Babaeva, Olga B
AU - Khayarov, Khasan Rafaelevich
AU - Mironov, Vladimir Fedorovich
PY - 2026
DA - 2026/02/03
PB - Mendeleev Communications
SP - 161-163
IS - 2
VL - 36
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2026_Zaborsky,
author = {Makar А Zaborsky and Dmitry Anatol'evich Tatarinov and Rezeda М Salakhova and Eliza Е Baynazarova and Olga B Babaeva and Khasan Rafaelevich Khayarov and Vladimir Fedorovich Mironov},
title = {Amberlyst-15 as a highly efficient and regenerative catalyst in the one-pot synthesis of areno[d][1,2]oxaphospholes},
journal = {Mendeleev Communications},
year = {2026},
volume = {36},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7893},
number = {2},
pages = {161--163},
doi = {10.71267/mencom.7893}
}
MLA
Cite this
MLA Copy
Zaborsky, Makar А., et al. “Amberlyst-15 as a highly efficient and regenerative catalyst in the one-pot synthesis of areno[d][1,2]oxaphospholes.” Mendeleev Communications, vol. 36, no. 2, Feb. 2026, pp. 161-163. https://mendcomm.colab.ws/publications/10.71267/mencom.7893.

Keywords

Abramov reaction
Amberlyst-15
areno[d][1,2]oxaphospholes
Friedel–Crafts reaction
phenols
α-hydroxy phosphonates

Abstract

The highly acidic Amberlyst-15 cationite is shown to be an effective catalyst for the Friedel–Crafts reaction between α-hydroxy phosphonates and phenols, resulting in the novel areno[d]oxaphosphole derivatives. Its advantages over p-toluenesulfonic acid are an increase in the yield of reaction products by 10–20% and the possibility of reusing the catalyst, i.e. reducing the cost of the entire procedure.

References

3.
Pal R., Sarkar T., Khasnobis S.
Arkivoc, 2012
7.
Renewable amberlyst-15 catalyzed highly regioselective tritylation and deprotection of sugar-based diols
Valeru A., Luo Z., Penjarla S., Khan I., Liu B., Sngepu B., Xu Y., Xie J.
Journal of Carbohydrate Chemistry, 2018
9.
Synthesis of enantiopure 2-carba-cyclic phosphatidic acid and effects of its chirality on biological functions
Nozaki E., Gotoh M., Hotta H., Hanazawa S., Kobayashi S., Murakami-Murofushi K.
Biochimica et Biophysica Acta - Molecular and Cell Biology of Lipids, 2011
11.
Synthesis and Anti-Pancreatic Cancer Activity Studies of Novel 3-Amino-2-hydroxybenzofused 2-Phospha-γ-lactones
Balam S.K., Soora Harinath J., Krishnammagari S.K., Gajjala R.R., Polireddy K., Baki V.B., Gu W., Valasani K.R., Avula V.K., Vallela S., Zyryanov G.V., Pasupuleti V.R., Cirandur S.R.
ACS Omega, 2021
12.
ref-10.71267-mendc7414-1-12-1-0
D. W. Chasar
1984
13.
Divergent synthesis of oxaphospholenes and phosphacoumarines via the reaction of 2-alkenylphenols with PCl3 or PCl5
Tatarinov D.A., Mikulenkova E.A., Litvinov I., Khayarov K., Mironov V.F.
Organic and Biomolecular Chemistry, 2024
14.
One-pot synthesis of areno[d][1,2]-oxaphosphole-2-oxides by the reactions of dialkylphosphites with carbonyl compounds and phenols
Zaborsky M.A., Tatarinov D.A., Salakhova R.M., Baynazarova E.E., Babaeva O.B., Khayarov K.R., Litvinov I.A., Mironov V.F.
Tetrahedron, 2025
15.
Mechanism of the interaction of o-hydroxybenzyl alcohol with trialkyl phosphites
Ivanov B.E., Ageeva A.B., Abul'khanov A.G., Zyablikova T.A.
Russian Chemical Bulletin, 1969
18.
ref-10.71267-mendc7414-1-18-1-0
P. H. Lee, S. H. Shin, D. J. Kang, D. H. Eom, Y. R. Kim, Y. S. Jeong and W. S. Choi
2015
19.
Fifty Years of (Benz)oxaphospholene Chemistry
Berton J.K., Heugebaert T.S., Virieux D., Stevens C.V.
Chemistry - A European Journal, 2017
20.
From insertion to multicomponent coupling: temperature dependent reactions of arynes with aliphatic alcohols