Home / Publications / Concentration dependence of quadratic nonlinear-optical characteristics of azo-functionalized methacrylic copolymers

Concentration dependence of quadratic nonlinear-optical characteristics of azo-functionalized methacrylic copolymers

Adel Il'darovich Gaysin 1
Adel Il'darovich Gaysin
, 
Tatyana Anatol'evna Vakhonina 1
Tatyana Anatol'evna Vakhonina
, 
Alfira А. Valieva 1
Alfira А. Valieva
, 
Anastasiya V. Sharipova 1
Anastasiya V. Sharipova
, 
Artemii Gennad'evich Shmelev 1, 2
Artemii Gennad'evich Shmelev
, 
Andrei Èduardovich Simanchuk 3
Andrei Èduardovich Simanchuk
, 
Sergei L'vovich Mikerin 3
Sergei L'vovich Mikerin
, 
Airat Raisovich Khamatgalimov 1
Airat Raisovich Khamatgalimov
, 
Marina Yur'evna Balakina 1
Marina Yur'evna Balakina
2 E. K. Zavoisky Physical-Technical Institute, FRC Kazan Scientific Center of Russian Academy of Sciences, 420029 Kazan, Russian Federation
3 Institute of Automation and Electrometry, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation
10.71267/mencom.7870
Published 2026-02-03
Communication , Volume 36, Issue 2, 151-154
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Gaysin A. I. et al. Concentration dependence of quadratic nonlinear-optical characteristics of azo-functionalized methacrylic copolymers // Mendeleev Communications. 2026. Vol. 36. No. 2. pp. 151-154.
GOST all authors (up to 50) Copy
Gaysin A. I., Vakhonina T. A., Valieva A. А., Sharipova A. V., Shmelev A. G., Simanchuk A. È., Mikerin S. L., Khamatgalimov A. R., Balakina M. Y. Concentration dependence of quadratic nonlinear-optical characteristics of azo-functionalized methacrylic copolymers // Mendeleev Communications. 2026. Vol. 36. No. 2. pp. 151-154.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.71267/mencom.7870
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7870
TI - Concentration dependence of quadratic nonlinear-optical characteristics of azo-functionalized methacrylic copolymers
T2 - Mendeleev Communications
AU - Gaysin, Adel Il'darovich
AU - Vakhonina, Tatyana Anatol'evna
AU - Valieva, Alfira А.
AU - Sharipova, Anastasiya V.
AU - Shmelev, Artemii Gennad'evich
AU - Simanchuk, Andrei Èduardovich
AU - Mikerin, Sergei L'vovich
AU - Khamatgalimov, Airat Raisovich
AU - Balakina, Marina Yur'evna
PY - 2026
DA - 2026/02/03
PB - Mendeleev Communications
SP - 151-154
IS - 2
VL - 36
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2026_Gaysin,
author = {Adel Il'darovich Gaysin and Tatyana Anatol'evna Vakhonina and Alfira А. Valieva and Anastasiya V. Sharipova and Artemii Gennad'evich Shmelev and Andrei Èduardovich Simanchuk and Sergei L'vovich Mikerin and Airat Raisovich Khamatgalimov and Marina Yur'evna Balakina},
title = {Concentration dependence of quadratic nonlinear-optical characteristics of azo-functionalized methacrylic copolymers},
journal = {Mendeleev Communications},
year = {2026},
volume = {36},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7870},
number = {2},
pages = {151--154},
doi = {10.71267/mencom.7870}
}
MLA
Cite this
MLA Copy
Gaysin, Adel Il'darovich, et al. “Concentration dependence of quadratic nonlinear-optical characteristics of azo-functionalized methacrylic copolymers.” Mendeleev Communications, vol. 36, no. 2, Feb. 2026, pp. 151-154. https://mendcomm.colab.ws/publications/10.71267/mencom.7870.

Keywords

azo-functionalization
methacrylic copolymers
nonlinear optical response
organic chromophores

Abstract

Azo-functionalization of aniline-containing methacrylic copolymers yielded polymers with side-chain chromophore contents ranging from 4.4 to 39 mol%. The highest nonlinear optical coefficient was achieved with a chromophore content of 17 mol%. The resulting polymers demonstrated good

relaxation stability at elevated temperatures: 98 and 86% at 55 and 65 °C, respectively.

References

1.
Perspective: Nanophotonic electro-optics enabling THz bandwidths, exceptional modulation and energy efficiencies, and compact device footprints
Dalton L.R., Leuthold J., Robinson B.H., Haffner C., Elder D.L., Johnson L.E., Hammond S.R., Heni W., Hosessbacher C., Baeuerle B., De Leo E., Koch U., Habegger P., Fedoryshyn Y., Moor D., et. al.
APL Materials, 2023
6.
Electro‐Optic Activity in Excess of 1000 pm V −1 Achieved via Theory‐Guided Organic Chromophore Design
Xu H., Elder D.L., Johnson L.E., de Coene Y., Hammond S.R., Vander Ghinst W., Clays K., Dalton L.R., Robinson B.H.
Advanced Materials, 2021
7.
Optimization of donors, acceptors and bridges for novel organic electro-optic materials
Wu S., Feng S., Huang Z., Liu C., Zhang Y., Zhang W., He W., Huo F., Liu F.
Journal of Materials Chemistry C, 2024
8.
Push-pull chromophores with π-deficient benzoazine and π-excessive thiophene cores in conjugated bridge as sources of quadratic nonlinear optical activity of composite polymer materials and molecular glasses
Islamova L.N., Kalinin A.A., Shustikov A.A., Fazleeva G.M., Gaysin A.I., Shmelev A.G., Simanchuk A.E., Shalin N.I., Sharipova A.V., Babaeva O.B., Vakhonina T.A., Fominykh O.D., Khamatgalimov A.R., Mikerin S.L., Balakina M.Y., et. al.
Dyes and Pigments, 2023
9.
Evaluation of optical characteristics in electro‐optic chromophores designed for applications at O‐band
Yamada T., Aoki I., Yamada C., Otomo A.
Physica Status Solidi (A) Applications and Materials Science, 2023
10.
Molecular engineering of organic chromophores and polymers for enhanced bulk second-order optical nonlinearity
Li M., Li Y., Zhang H., Wang S., Ao Y., Cui Z.
Journal of Materials Chemistry C, 2017
11.
Design and synthesis of chromophores with enhanced electro-optic activities in both bulk and plasmonic–organic hybrid devices
Xu H., Elder D.L., Johnson L.E., Heni W., de Coene Y., De Leo E., Destraz M., Meier N., Vander Ghinst W., Hammond S.R., Clays K., Leuthold J., Dalton L.R., Robinson B.H.
Materials Horizons, 2022
12.
Azo chromophores for nonlinear-optical application
Selivanova G.A.
Russian Chemical Bulletin, 2021
13.
Stable polymeric materials for nonlinear optics: a review based on azobenzene systems
Yesodha S.K., Sadashiva Pillai C.K., Tsutsumi N.
Progress in Polymer Science, 2004
14.
Supramolecular design principles for efficient photoresponsive polymer–azobenzene complexes
Vapaavuori J., Bazuin C.G., Priimagi A.
Journal of Materials Chemistry C, 2018
15.
Novel pendant azobenzene/polymer systems for second harmonic generation and optical data storage
Spiridon M.C., Iliopoulos K., Jerca F.A., Jerca V.V., Vuluga D.M., Vasilescu D.S., Gindre D., Sahraoui B.
Dyes and Pigments, 2015
16.
Organic–inorganic hybrid electro-optic material with Disperse Red 1 chromophore fabricated by flow chemistry
Ko Y., Kim M., Noh C., Kim M., Lee K., Kim J., Kim S.D., Jee S.S.
Journal of Flow Chemistry, 2021
17.
De Martino S., Mauro F., Netti P.A.
La Rivista del Nuovo Cimento, 2020
19.
Synthesis and Nonlinear Optical Properties of a Peripherally Functionalized Hyperbranched Polymer by DR1 Chromophores
Scarpaci A., Blart E., Montembault V., Fontaine L., Rodriguez V., Odobel F.
ACS applied materials & interfaces, 2009
20.
Outstanding Poling Stability of a New Cross-Linked Nonlinear Optical (NLO) Material from a Low Molecular Weight Chromophore
Borbone F., Carella A., Roviello A., Casalboni M., De Matteis F., Stracci G., della Rovere F., Evangelisti A., Dispenza M.
Journal of Physical Chemistry B, 2011
21.
Designing Efficient Azobenzene and Azothiophene Nonlinear Optical Photochromes
Jaunet-Lahary T., Chantzis A., Chen K.J., Laurent A.D., Jacquemin D.
Journal of Physical Chemistry C, 2014
23.
Nonlinear optically active polymethacrylates with high glass transition temperatures
Eckl M., Müller H., Strohriegl P., Beckmann S., Etzbach K., Eich M., Vydra J.
Macromolecular Chemistry and Physics, 1995
24.
New Cross-Linkable Polymers with Huisgen Reaction Incorporating High μβ Chromophores for Second-Order Nonlinear Optical Applications
Cabanetos C., Bentoumi W., Silvestre V., Blart E., Pellegrin Y., Montembault V., Barsella A., Dorkenoo K., Bretonnière Y., Andraud C., Mager L., Fontaine L., Odobel F.
Chemistry of Materials, 2012
26.
Synthesis and characterization of side-chain poly(methacrylate)s bearing new azo-moieties
Nicolescu F.A., Jerca V.V., Vuluga D.M., Vasilescu D.S.
Polymer Bulletin, 2010
27.
Methacrylic copolymers with quinoxaline chromophores in the side chain exhibiting quadratic nonlinear optical response
Vakhonina T.A., Fazleeva G.M., Kalinin A.A., Gaysin A.I., Shmelev A.G., Islamova L.N., Fominykh O.D., Sharipova A.V., Shalin N.I., Mukhtarov A.S., Khamatgalimov A.R., Balakina M.Y.
Journal of Applied Polymer Science, 2022
28.
Nonlinear optical side-chain polymers post-functionalized with high-β chromophores exhibiting large electro-optic property
Piao X., Zhang X., Mori Y., Koishi M., Nakaya A., Inoue S., Aoki I., Otomo A., Yokoyama S.
Journal of Polymer Science, Part A: Polymer Chemistry, 2010
29.
Synthesis and copolymerization of new methacrylic monomers for the creation of nonlinear optical polymer materials
Gaisin A.I., Vakhonina T.A., Mukhtarov A.S., Shmelev A.G., Balakina M.Y.
Russian Chemical Bulletin, 2021
30.
Gaysin A.I., Vakhonina T.A., Yakovleva E.O., Balakina M.Y., Sinyashin O.G.
Mendeleev Communications, 2024
31.
Synthesis of a new polymer surface bearing grafted azo polymer chains
Poncin-Epaillard F., Beunet J., Bulou A., Bardeau J.
Journal of Polymer Science, Part A: Polymer Chemistry, 2001
34.
Second–harmonic generation in poled polymers: pre–poling history paradigm
Pawlik G., Rau I., Kajzar F., Mitus A.C.
Optics Express, 2010
35.
Photochromism of 4‐acryloxyazobenzene/(−)‐menthyl acrylate copolymers
Altomare A., Carlini C., Ciardelli F., Solaro R., Rosato N.
Journal of Polymer Science Polymer Chemistry Edition, 1984
36.
Synthesis, structure, and properties of bifunctional azobenzene monomers and polymers on their basis
Shulyndin S.V., Vakhonina T.A., Estrina G.A., Rozenberg B.A., Zuev M.B.
Polymer Science - Series A, 2007
37.
Concentration Variation of Quadratic NLO Susceptibility in PMMA-DR1 Side Chain Polymer
Kajzar F., Krupka O., Pawlik G., Mitus A., Rau I.
Molecular Crystals and Liquid Crystals, 2010
38.
The effect of chromophores concentration on the nonlinear optical activity of methacrylic copolymers with azochromophores in the side chain
Smirnov M.A., Mukhtarov A.S., Ivanova N.V., Vakhonina T.A., Semashko V.V., Balakina M.Y.
Journal of Physics: Conference Series, 2014