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Zinc complex as a source of highly labile non-shielded o-iminoquinone

Tatiana N Kocherova 1
Tatiana N Kocherova
,  ,  ,  , 
10.71267/mencom.7864
Published 2025-11-29
Communication , Volume 36, Issue 1, 114-116
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Kocherova T. N. et al. Zinc complex as a source of highly labile non-shielded o-iminoquinone // Mendeleev Communications. 2025. Vol. 36. No. 1. pp. 114-116.
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Kocherova T. N., Rumyantcev R. V., Kuropatov V. A., Piskunov A. V., Druzhkov N. O. Zinc complex as a source of highly labile non-shielded o-iminoquinone // Mendeleev Communications. 2025. Vol. 36. No. 1. pp. 114-116.
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TY - JOUR
DO - 10.71267/mencom.7864
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7864
TI - Zinc complex as a source of highly labile non-shielded o-iminoquinone
T2 - Mendeleev Communications
AU - Kocherova, Tatiana N
AU - Rumyantcev, Roman Valeryevich
AU - Kuropatov, Viacheslav Aleksandrovich
AU - Piskunov, Aleksandr Vladimirovich
AU - Druzhkov, Nikolay O
PY - 2025
DA - 2025/11/29
PB - Mendeleev Communications
SP - 114-116
IS - 1
VL - 36
ER -
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@article{2025_Kocherova,
author = {Tatiana N Kocherova and Roman Valeryevich Rumyantcev and Viacheslav Aleksandrovich Kuropatov and Aleksandr Vladimirovich Piskunov and Nikolay O Druzhkov},
title = {Zinc complex as a source of highly labile non-shielded o-iminoquinone},
journal = {Mendeleev Communications},
year = {2025},
volume = {36},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7864},
number = {1},
pages = {114--116},
doi = {10.71267/mencom.7864}
}
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Kocherova, Tatiana N., et al. “Zinc complex as a source of highly labile non-shielded o-iminoquinone.” Mendeleev Communications, vol. 36, no. 1, Nov. 2025, pp. 114-116. https://mendcomm.colab.ws/publications/10.71267/mencom.7864.
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Keywords

nickel complexes
o-iminoquinone
o-iminosemiquinone
redox-active ligand
X-ray diffraction
zinc complexes

Abstract

Noval unstable o-iminobenzoquinone, namely, 3,4-dibenzhydryl-6-[(2,6-diisopropylphenyl)imino]cyclohex-2-en-1-one, bearing non-shielded chelating site was synthesized in the zinc coordination sphere as a neutral ligand. The bis-o-iminosemiquinonate NII compound was prepared by the reaction of zinc o-iminoquinolate complex with Ni(CO)4 and characterized by NMR spectroscopy and X-ray diffraction analysis.

Funders

Russian Science Foundation
22-13-00351-P

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