Home / Publications / 2-Fluoroanthraquinone-catalyzed photooxidation of benzylic alcohols and aliphatic diols in supercritical carbon dioxide

2-Fluoroanthraquinone-catalyzed photooxidation of benzylic alcohols and aliphatic diols in supercritical carbon dioxide

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Elizaveta A. Ivanova 1
Elizaveta A. Ivanova
,  ,  ,  , 
10.71267/mencom.7855
Published 2025-11-29
Communication , Volume 36, Issue 1, 47-49
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Merkulov V. et al. 2-Fluoroanthraquinone-catalyzed photooxidation of benzylic alcohols and aliphatic diols in supercritical carbon dioxide // Mendeleev Communications. 2025. Vol. 36. No. 1. pp. 47-49.
GOST all authors (up to 50) Copy
Merkulov V., Ivanova E. A., Rusakov S. P., Kuchurov I. V., Zharkov M. N., Zlotin S. G. 2-Fluoroanthraquinone-catalyzed photooxidation of benzylic alcohols and aliphatic diols in supercritical carbon dioxide // Mendeleev Communications. 2025. Vol. 36. No. 1. pp. 47-49.
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TY - JOUR
DO - 10.71267/mencom.7855
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7855
TI - 2-Fluoroanthraquinone-catalyzed photooxidation of benzylic alcohols and aliphatic diols in supercritical carbon dioxide
T2 - Mendeleev Communications
AU - Merkulov, Vladislav
AU - Ivanova, Elizaveta A.
AU - Rusakov, Savva P.
AU - Kuchurov, Ilya Vladimirovich
AU - Zharkov, Mikhail N
AU - Zlotin, Sergei Grigorievich
PY - 2025
DA - 2025/11/29
PB - Mendeleev Communications
SP - 47-49
IS - 1
VL - 36
ER -
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@article{2025_Merkulov,
author = {Vladislav Merkulov and Elizaveta A. Ivanova and Savva P. Rusakov and Ilya Vladimirovich Kuchurov and Mikhail N Zharkov and Sergei Grigorievich Zlotin},
title = {2-Fluoroanthraquinone-catalyzed photooxidation of benzylic alcohols and aliphatic diols in supercritical carbon dioxide},
journal = {Mendeleev Communications},
year = {2025},
volume = {36},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7855},
number = {1},
pages = {47--49},
doi = {10.71267/mencom.7855}
}
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Merkulov, Vladislav, et al. “2-Fluoroanthraquinone-catalyzed photooxidation of benzylic alcohols and aliphatic diols in supercritical carbon dioxide.” Mendeleev Communications, vol. 36, no. 1, Nov. 2025, pp. 47-49. https://mendcomm.colab.ws/publications/10.71267/mencom.7855.

Keywords

aldehydes
benzylic alcohols
diols
Ketones
lactones.
oxidation
photocatalysis
supercritical carbon dioxide

Abstract

Benzylic alcohols are oxidized with molecular oxygen to the corresponding carbonyl compounds and carboxylic acids in supercritical carbon dioxide medium in the presence of 2-fluoroanthraquinone as an organic photocatalyst. The transformation is promoted by blue light irradiation at 405 nm. The similar processing of aliphatic terminal 1,3- and 1,4-diols affords the corresponding diacids, while small changes in the procedure allows one to convert butane-1,4-diol into γ-butyrolactone in one experimental step.

Funders

Russian Science Foundation
23-73-00071

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