Home / Publications / Synthesis and structure of bis(N-methylaza-15-crown-5)-fused 2,5‑dibenzylidenecyclopentanone and its novel bis-sandwich complex with Ba2+ ions

Synthesis and structure of bis(N-methylaza-15-crown-5)-fused 2,5‑dibenzylidenecyclopentanone and its novel bis-sandwich complex with Ba2+ ions

Svetlana Nikolaevna Dmitrieva 1
Svetlana Nikolaevna Dmitrieva
, 
Artem Igorevich Vedernikov 1
Artem Igorevich Vedernikov
, 
Ludmila G Kuzmina 2
Ludmila G Kuzmina
, 
10.71267/mencom.7851
Published 2025-11-29
Communication , Volume 36, Issue 1, 34-36
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Dmitrieva S. N. et al. Synthesis and structure of bis(N-methylaza-15-crown-5)-fused 2,5‑dibenzylidenecyclopentanone and its novel bis-sandwich complex with Ba2+ ions // Mendeleev Communications. 2025. Vol. 36. No. 1. pp. 34-36.
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Dmitrieva S. N., Vedernikov A. I., Kuzmina L. G., Gromov S. P. Synthesis and structure of bis(N-methylaza-15-crown-5)-fused 2,5‑dibenzylidenecyclopentanone and its novel bis-sandwich complex with Ba2+ ions // Mendeleev Communications. 2025. Vol. 36. No. 1. pp. 34-36.
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TY - JOUR
DO - 10.71267/mencom.7851
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7851
TI - Synthesis and structure of bis(N-methylaza-15-crown-5)-fused 2,5‑dibenzylidenecyclopentanone and its novel bis-sandwich complex with Ba2+ ions
T2 - Mendeleev Communications
AU - Dmitrieva, Svetlana Nikolaevna
AU - Vedernikov, Artem Igorevich
AU - Kuzmina, Ludmila G
AU - Gromov, Sergey P
PY - 2025
DA - 2025/11/29
PB - Mendeleev Communications
SP - 34-36
IS - 1
VL - 36
ER -
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@article{2025_Dmitrieva,
author = {Svetlana Nikolaevna Dmitrieva and Artem Igorevich Vedernikov and Ludmila G Kuzmina and Sergey P Gromov},
title = {Synthesis and structure of bis(N-methylaza-15-crown-5)-fused 2,5‑dibenzylidenecyclopentanone and its novel bis-sandwich complex with Ba2+ ions},
journal = {Mendeleev Communications},
year = {2025},
volume = {36},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7851},
number = {1},
pages = {34--36},
doi = {10.71267/mencom.7851}
}
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Dmitrieva, Svetlana Nikolaevna, et al. “Synthesis and structure of bis(N-methylaza-15-crown-5)-fused 2,5‑dibenzylidenecyclopentanone and its novel bis-sandwich complex with Ba2+ ions.” Mendeleev Communications, vol. 36, no. 1, Nov. 2025, pp. 34-36. https://mendcomm.colab.ws/publications/10.71267/mencom.7851.
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Keywords

azacrown ether
barium complex
cross-conjugated dienone
electronic spectroscopy.
synthesis
X-ray diffraction analysis

Abstract

A symmetrical cyclopentanone-based dienone containing two N-methylbenzoaza-15-crown-5 ether moieties was synthesized. The structures of the dienone and its bis-sandwich complex with barium perchlorate were investigated using X-ray diffraction and electronic spectroscopy.

Funders

Russian Science Foundation
25-73-20016

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