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Tetranuclear nickel(II) complex with tetra-coordinated acetate and 1,3,5-tris(2-hydroxyphenyl)-2,4-diazapenta-1,4-diene ligands

Daniil Romanovich Bazanov 1, 2
Daniil Romanovich Bazanov
Ekaterina Igorevna Marchenko 3, 4
Ekaterina Igorevna Marchenko
Alexander V Polezhaev 1
Alexander V Polezhaev
Egor D Korolyov 1
Egor D Korolyov
Konstantin Alexandrovich Lyssenko
Natalia Alexandrovna Lozinskaya
Published 2026-02-03
CommunicationVolume 36, Issue 2, 203-205
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Bazanov D. R. et al. Tetranuclear nickel(II) complex with tetra-coordinated acetate and 1,3,5-tris(2-hydroxyphenyl)-2,4-diazapenta-1,4-diene ligands // Mendeleev Communications. 2026. Vol. 36. No. 2. pp. 203-205.
GOST all authors (up to 50) Copy
Bazanov D. R., Marchenko E. I., Polezhaev A. V., Korolyov E. D., Lyssenko K. A., Lozinskaya N. A. Tetranuclear nickel(II) complex with tetra-coordinated acetate and 1,3,5-tris(2-hydroxyphenyl)-2,4-diazapenta-1,4-diene ligands // Mendeleev Communications. 2026. Vol. 36. No. 2. pp. 203-205.
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TY - JOUR
DO - 10.71267/mencom.7843
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7843
TI - Tetranuclear nickel(II) complex with tetra-coordinated acetate and 1,3,5-tris(2-hydroxyphenyl)-2,4-diazapenta-1,4-diene ligands
T2 - Mendeleev Communications
AU - Bazanov, Daniil Romanovich
AU - Marchenko, Ekaterina Igorevna
AU - Polezhaev, Alexander V
AU - Korolyov, Egor D
AU - Lyssenko, Konstantin Alexandrovich
AU - Lozinskaya, Natalia Alexandrovna
PY - 2026
DA - 2026/02/03
PB - Mendeleev Communications
SP - 203-205
IS - 2
VL - 36
ER -
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@article{2026_Bazanov,
author = {Daniil Romanovich Bazanov and Ekaterina Igorevna Marchenko and Alexander V Polezhaev and Egor D Korolyov and Konstantin Alexandrovich Lyssenko and Natalia Alexandrovna Lozinskaya},
title = {Tetranuclear nickel(II) complex with tetra-coordinated acetate and 1,3,5-tris(2-hydroxyphenyl)-2,4-diazapenta-1,4-diene ligands},
journal = {Mendeleev Communications},
year = {2026},
volume = {36},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7843},
number = {2},
pages = {203--205},
doi = {10.71267/mencom.7843}
}
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Bazanov, Daniil Romanovich, et al. “Tetranuclear nickel(II) complex with tetra-coordinated acetate and 1,3,5-tris(2-hydroxyphenyl)-2,4-diazapenta-1,4-diene ligands.” Mendeleev Communications, vol. 36, no. 2, Feb. 2026, pp. 203-205. https://mendcomm.colab.ws/publications/10.71267/mencom.7843.

Keywords

diazapentadiene
iminium ligand
octahedral nickel
salen complex
salicylic aldehyde
tetra-coordinated carboxylate
tetranuclear complex

Abstract

A new octahedral tetranuclear nickel(II) complex with a diimine ligand has been synthesized and characterized by single-crystal X-ray diffraction. The complex features an unusual tetra-coordinated acetate ion acting as an auxiliary ligand, along with coordinated ethanol and water molecules.

Funders

state assignment of Lomonosov Moscow State University
121021000105-7

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