Keywords
chemical co-precipitation
composition stability
heteronanostructure (ZnS)(Ag2S)x
oxidation
phase composition
silver
zinc sulfide
Abstract
The stability of the phase composition of sulfide heteronanostructures (ZnS)(Ag2S)x with x = 0.025–0.50 has been investigated for the first time. Annealing of such heteronanostructures in air at temperatures from 298 to 800 K and higher leads to a change in their phase composition due to the oxidation of cubic zinc sulfide to hexagonal zinc oxide. The weight loss that occurs during heating from ~320 to ~700–750 K is associated with the onset of oxidation of zinc sulfide and the formation of zinc oxide.
Funders
state assignment for the Institute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences
FUWF-2024-0010 (124020600013-9)
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