Home / Publications / An additive approach to the a priori determination of activation energies of thermoneutral reactions

An additive approach to the a priori determination of activation energies of thermoneutral reactions

Alexander Fedorovich Shestakov 1
Alexander Fedorovich Shestakov
, 
Tamara Sergeevna Pokidova 1
Tamara Sergeevna Pokidova
10.71267/mencom.7835
Published 2026-02-03
Communication , Volume 36, Issue 2, 242-244
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Shestakov A. F., Pokidova T. S. An additive approach to the a priori determination of activation energies of thermoneutral reactions // Mendeleev Communications. 2026. Vol. 36. No. 2. pp. 242-244.
GOST all authors (up to 50) Copy
Shestakov A. F., Pokidova T. S. An additive approach to the a priori determination of activation energies of thermoneutral reactions // Mendeleev Communications. 2026. Vol. 36. No. 2. pp. 242-244.
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TY - JOUR
DO - 10.71267/mencom.7835
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7835
TI - An additive approach to the a priori determination of activation energies of thermoneutral reactions
T2 - Mendeleev Communications
AU - Shestakov, Alexander Fedorovich
AU - Pokidova, Tamara Sergeevna
PY - 2026
DA - 2026/02/03
PB - Mendeleev Communications
SP - 242-244
IS - 2
VL - 36
ER -
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@article{2026_Shestakov,
author = {Alexander Fedorovich Shestakov and Tamara Sergeevna Pokidova},
title = {An additive approach to the a priori determination of activation energies of thermoneutral reactions},
journal = {Mendeleev Communications},
year = {2026},
volume = {36},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7835},
number = {2},
pages = {242--244},
doi = {10.71267/mencom.7835}
}
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Shestakov, Alexander Fedorovich, and Tamara Sergeevna Pokidova. “An additive approach to the a priori determination of activation energies of thermoneutral reactions.” Mendeleev Communications, vol. 36, no. 2, Feb. 2026, pp. 242-244. https://mendcomm.colab.ws/publications/10.71267/mencom.7835.
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Keywords

activation energy
additive method
enthalpy of reaction
increment
thermoneutral reaction

Abstract

An additive approach for determining the activation energies of thermoneutral reactions is presented, which makes it possible to find the rate constants of radical reactions of H atom abstraction based on the enthalpy of these reactions and the rate constants of the corresponding symmetric reactions.

Funders

Ministry of Education and Science of the Russian Federation
FFSG-2024-0004

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