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Pd-catalyzed isoprene telomerization with nucleophiles over the years: a look into the past and future prospects

, 
Maksim Anatol'evich Topchiy 1
Maksim Anatol'evich Topchiy
, 
Sergey Aleksandrovich Rzhevskiy 1
Sergey Aleksandrovich Rzhevskiy
, 
Andrey Fedorovich Asachenko 1
Andrey Fedorovich Asachenko
10.71267/mencom.7821
Published 2025-10-21
Focus article , Volume 35, Issue 6, 619-626
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Minaeva L. I. et al. Pd-catalyzed isoprene telomerization with nucleophiles over the years: a look into the past and future prospects // Mendeleev Communications. 2025. Vol. 35. No. 6. pp. 619-626.
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Minaeva L. I., Topchiy M. A., Rzhevskiy S. A., Asachenko A. F. Pd-catalyzed isoprene telomerization with nucleophiles over the years: a look into the past and future prospects // Mendeleev Communications. 2025. Vol. 35. No. 6. pp. 619-626.
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TY - JOUR
DO - 10.71267/mencom.7821
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7821
TI - Pd-catalyzed isoprene telomerization with nucleophiles over the years: a look into the past and future prospects
T2 - Mendeleev Communications
AU - Minaeva, Lidiya Igorevna
AU - Topchiy, Maksim Anatol'evich
AU - Rzhevskiy, Sergey Aleksandrovich
AU - Asachenko, Andrey Fedorovich
PY - 2025
DA - 2025/10/21
PB - Mendeleev Communications
SP - 619-626
IS - 6
VL - 35
ER -
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@article{2025_Minaeva,
author = {Lidiya Igorevna Minaeva and Maksim Anatol'evich Topchiy and Sergey Aleksandrovich Rzhevskiy and Andrey Fedorovich Asachenko},
title = {Pd-catalyzed isoprene telomerization with nucleophiles over the years: a look into the past and future prospects},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7821},
number = {6},
pages = {619--626},
doi = {10.71267/mencom.7821}
}
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Minaeva, Lidiya Igorevna, et al. “Pd-catalyzed isoprene telomerization with nucleophiles over the years: a look into the past and future prospects.” Mendeleev Communications, vol. 35, no. 6, Oct. 2025, pp. 619-626. https://mendcomm.colab.ws/publications/10.71267/mencom.7821.
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Keywords

atom-efficient process.
catalytic cycle
isoprene
Pd-complex catalysis
Pd–NHC complex
Selectivity
telomerization

Abstract

The telomerization of 1,3-dienes with the wide range of the nucleophiles is a versatile tool for the synthesis of alcohols, amines, acids, unsaturated esters and other compounds being valuable natural-type products from abundant petrochemical base materials. Being a 100% atom-efficient process, telomerization is very promising for the industrial application, particularly in case of isoprene which is produced in the large scale all over the world and in particular in Russia. This review presents the developments in the field of isoprene telomerization over the years to discuss the variety of products, most efficient catalysts and ligands and the selectivity of the process.

Funders

A. V. Topchiev Institute of Petrochemical Synthesis Russian Academy of Sciences State Program