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Synthesis of BODIPY derivatives with iodinated cobalt bis(dicarbollide)

Anna Aleksandrovna Druzina 1
Anna Aleksandrovna Druzina
, 
Nadezhda Vadimovna Dudarova 1
Nadezhda Vadimovna Dudarova
, 
Olga Borisovna Zhidkova 1
Olga Borisovna Zhidkova
,  , 
Ivan Vyacheslavovich Ananyev 2
Ivan Vyacheslavovich Ananyev
, 
Igor Borisovich Sivaev 1
Igor Borisovich Sivaev
, 
Vladimir Iosifovich Bregadze 1
Vladimir Iosifovich Bregadze
10.71267/mencom.7812
Published 2025-10-21
Communication , Volume 35, Issue 6, 673-675
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Druzina A. A. et al. Synthesis of BODIPY derivatives with iodinated cobalt bis(dicarbollide) // Mendeleev Communications. 2025. Vol. 35. No. 6. pp. 673-675.
GOST all authors (up to 50) Copy
Druzina A. A., Dudarova N. V., Zhidkova O. B., Kosenko I. D., Ananyev I. V., Sivaev I. B., Bregadze V. I. Synthesis of BODIPY derivatives with iodinated cobalt bis(dicarbollide) // Mendeleev Communications. 2025. Vol. 35. No. 6. pp. 673-675.
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TY - JOUR
DO - 10.71267/mencom.7812
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7812
TI - Synthesis of BODIPY derivatives with iodinated cobalt bis(dicarbollide)
T2 - Mendeleev Communications
AU - Druzina, Anna Aleksandrovna
AU - Dudarova, Nadezhda Vadimovna
AU - Zhidkova, Olga Borisovna
AU - Kosenko, Irina Dmitrievna
AU - Ananyev, Ivan Vyacheslavovich
AU - Sivaev, Igor Borisovich
AU - Bregadze, Vladimir Iosifovich
PY - 2025
DA - 2025/10/21
PB - Mendeleev Communications
SP - 673-675
IS - 6
VL - 35
ER -
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@article{2025_Druzina,
author = {Anna Aleksandrovna Druzina and Nadezhda Vadimovna Dudarova and Olga Borisovna Zhidkova and Irina Dmitrievna Kosenko and Ivan Vyacheslavovich Ananyev and Igor Borisovich Sivaev and Vladimir Iosifovich Bregadze},
title = {Synthesis of BODIPY derivatives with iodinated cobalt bis(dicarbollide)},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7812},
number = {6},
pages = {673--675},
doi = {10.71267/mencom.7812}
}
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Druzina, Anna Aleksandrovna, et al. “Synthesis of BODIPY derivatives with iodinated cobalt bis(dicarbollide).” Mendeleev Communications, vol. 35, no. 6, Oct. 2025, pp. 673-675. https://mendcomm.colab.ws/publications/10.71267/mencom.7812.

Keywords

�click� reaction
alkynes
azides
BODIPY
boron neutron capture therapy.
cobalt bis(dicarbollide)
fluorescent labeling

Abstract

The solid-state molecular structure of azido derivative of BODIPY was determined by a single-crystal X-ray diffraction; this compound was subjected to a CuI-catalyzed azide--alkyne cycloaddition with ethynyl-containing iodine cobalt bis(dicarbollides) to give the corresponding new 1,2,3-triazole conjugates. Their study by absorption-- emission spectroscopy showed that the addition of a boron cluster weakened the fluorescence of the starting azido BODIPY.

Funders

Russian Science Foundation
24-73-10090