Keywords
3D printing
acetylene.
additive manufacturing
azide–alkyne cycloaddition
fused filament fabrication
thermoplastic
Abstract
The feasibility of fabricating catalytically active structures based on thermoplastic polylactide, polyethylene terephthalate glycol (PETG) and acrylonitrile-butadiene-styrene using 3D printing of sleeves for magnetic stir bars was investigated. It was shown that the correct selection of solvents for thermoplastic modification and reaction performance plays a key role. PETG-based catalytic stir bars demonstrated the best efficiency and recyclability in the azide-alkyne cycloaddition reaction and allowed to synthesize a variety of triazoles from acetylene.
Funders
Russian Science Foundation
24-73-10165
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