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A novel natural chlorin metal complex containing gold(I) in the macrocycle periphery

Viktor Alekseevich Pogorilyy 1
Viktor Alekseevich Pogorilyy
, 
Valeria I. Efimova 1
Valeria I. Efimova
, 
Julia S. Kartava 1
Julia S. Kartava
, 
Sergey I. Tikhonov 1
Sergey I. Tikhonov
, 
Maxim Nikolaevich Usachev 1
Maxim Nikolaevich Usachev
, 
Mikhail Alexandrovich Grin 1
Mikhail Alexandrovich Grin
1 M. V. Lomonosov Institute of Fine Chemical Technologies, MIREA -- Russian Technological University, 119571 Moscow, Russian Federation
10.71267/mencom.7810
Published 2025-10-21
Communication , Volume 35, Issue 6, 664-666
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Pogorilyy V. A. et al. A novel natural chlorin metal complex containing gold(I) in the macrocycle periphery // Mendeleev Communications. 2025. Vol. 35. No. 6. pp. 664-666.
GOST all authors (up to 50) Copy
Pogorilyy V. A., Efimova V. I., Kartava J. S., Tikhonov S. I., Usachev M. N., Grin M. A. A novel natural chlorin metal complex containing gold(I) in the macrocycle periphery // Mendeleev Communications. 2025. Vol. 35. No. 6. pp. 664-666.
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TY - JOUR
DO - 10.71267/mencom.7810
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7810
TI - A novel natural chlorin metal complex containing gold(I) in the macrocycle periphery
T2 - Mendeleev Communications
AU - Pogorilyy, Viktor Alekseevich
AU - Efimova, Valeria I.
AU - Kartava, Julia S.
AU - Tikhonov, Sergey I.
AU - Usachev, Maxim Nikolaevich
AU - Grin, Mikhail Alexandrovich
PY - 2025
DA - 2025/10/21
PB - Mendeleev Communications
SP - 664-666
IS - 6
VL - 35
ER -
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@article{2025_Pogorilyy,
author = {Viktor Alekseevich Pogorilyy and Valeria I. Efimova and Julia S. Kartava and Sergey I. Tikhonov and Maxim Nikolaevich Usachev and Mikhail Alexandrovich Grin},
title = {A novel natural chlorin metal complex containing gold(I) in the macrocycle periphery},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7810},
number = {6},
pages = {664--666},
doi = {10.71267/mencom.7810}
}
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Pogorilyy, Viktor Alekseevich, et al. “A novel natural chlorin metal complex containing gold(I) in the macrocycle periphery.” Mendeleev Communications, vol. 35, no. 6, Oct. 2025, pp. 664-666. https://mendcomm.colab.ws/publications/10.71267/mencom.7810.

Keywords

chlorophyll A
combined action
gold(I) complexes
pheophorbide
sulfur-containing compounds
thiocarbonyl compounds

Abstract

An original synthesis of methyl ester of 131-thioketone pyropheophorbide A containing a gold(I) complex at the periphery of the macrocycle (at the E exocycle) via the formation of an S–Au bond is performed. The stability of this complex in aqueous solutions at various pH values as well as the effectiveness of its binding to DNA are evidenced.

Funders

Program of Strategic Academic Leadership Prioritet-2030