Home / Publications / 119Sn Mössbauer spectroscopy of nickel zinc orthostannates prepared by self-propagating high-temperature synthesis

119Sn Mössbauer spectroscopy of nickel zinc orthostannates prepared by self-propagating high-temperature synthesis

Maxim Valer'evich Kuznetsov 1
Maxim Valer'evich Kuznetsov
, 
Denis A Pankratov 2, 3
Denis A Pankratov
, 
Yurii Georgievich Morozov 4
Yurii Georgievich Morozov
,  , 
Olga Valentinovna Belousova 4
Olga Valentinovna Belousova
1 All-Russian Research Institute on Problems of Civil Defence and Emergencies, 121352 Moscow, Russian Federation
3 Moscow Institute of Physics and Technology (National Research University), 141700 Dolgoprudny, Moscow Region, Russian Federation
4 A. G. Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation
10.71267/mencom.7804
Published 2025-10-21
Communication , Volume 35, Issue 6, 699-701
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Kuznetsov M. V. et al. 119Sn Mössbauer spectroscopy of nickel zinc orthostannates prepared by self-propagating high-temperature synthesis // Mendeleev Communications. 2025. Vol. 35. No. 6. pp. 699-701.
GOST all authors (up to 50) Copy
Kuznetsov M. V., Pankratov D. A., Morozov Y. G., Safonov A. V., Belousova O. V. 119Sn Mössbauer spectroscopy of nickel zinc orthostannates prepared by self-propagating high-temperature synthesis // Mendeleev Communications. 2025. Vol. 35. No. 6. pp. 699-701.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.71267/mencom.7804
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7804
TI - 119Sn Mössbauer spectroscopy of nickel zinc orthostannates prepared by self-propagating high-temperature synthesis
T2 - Mendeleev Communications
AU - Kuznetsov, Maxim Valer'evich
AU - Pankratov, Denis A
AU - Morozov, Yurii Georgievich
AU - Safonov, Alexey Vladimirovich
AU - Belousova, Olga Valentinovna
PY - 2025
DA - 2025/10/21
PB - Mendeleev Communications
SP - 699-701
IS - 6
VL - 35
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2025_Kuznetsov,
author = {Maxim Valer'evich Kuznetsov and Denis A Pankratov and Yurii Georgievich Morozov and Alexey Vladimirovich Safonov and Olga Valentinovna Belousova},
title = {119Sn Mössbauer spectroscopy of nickel zinc orthostannates prepared by self-propagating high-temperature synthesis},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7804},
number = {6},
pages = {699--701},
doi = {10.71267/mencom.7804}
}
MLA
Cite this
MLA Copy
Kuznetsov, Maxim Valer'evich, et al. “119Sn Mössbauer spectroscopy of nickel zinc orthostannates prepared by self-propagating high-temperature synthesis.” Mendeleev Communications, vol. 35, no. 6, Oct. 2025, pp. 699-701. https://mendcomm.colab.ws/publications/10.71267/mencom.7804.

Keywords

magnetic measurements
microstructure
Mössbauer spectra
nickel zinc orthostannates
self-propagating high-temperature synthesis
SHS
X-ray diffraction
XPS

Abstract

Zinc orthostannate (Zn2SnO4) and nickel zinc orthostannate (Zn1.2Ni0.8SnO4) were prepared by self-propagating hightemperature synthesis (SHS) and characterized by 119Sn Mössbauer spectroscopy. Both orthostannates are cubic spinels exhibiting defect-induced ferromagnetic behavior due to their microstructures. The Mössbauer spectrum of Zn2SnO4 appears as single unresolved doublet [δ = 0.169(3) mm s–1, Δ = 0.45(1) mm s–1], and in the case of Zn1.2Ni0.8SnO4, partial substitution of zinc by nickel is the cause of the appearance of a second doublet of Sn4+ [δ = 0.44(9) mm s–1, Δ = 1.62(1) mm s–1] due to an increase in the occupancy of the 5s orbital of the corresponding tin atoms and the localization of crystallographic defects near them.

Funders

Ministry of Education and Science of the Russian Federation
122030200324-1