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The role of diglyme and tetraglyme in the formation of ion transport pathways in gel electrolytes based on polyethylene glycol diacrylate

Nikita Andreevich Slesarenko 1
Nikita Andreevich Slesarenko
, 
Alexander Vladimirovich Chernyak 1, 2
Alexander Vladimirovich Chernyak
, 
Vitaly Ivanovich Volkov 1
Vitaly Ivanovich Volkov
, 
Kyunsylu Gumerovna Khatmullina 1, 3
Kyunsylu Gumerovna Khatmullina
, 
Alena Vladimirovna Yudina 1
Alena Vladimirovna Yudina
, 
Galiya Zaynetdinovna Tulibaeva 1
Galiya Zaynetdinovna Tulibaeva
,  , 
Guzaliya Rafikovna Baymuratova 1
Guzaliya Rafikovna Baymuratova
, 
Alexander Fedorovich Shestakov 1, 4
Alexander Fedorovich Shestakov
, 
2 Yu. A. Osipyan Institute of Solid State Physics, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation
3 National Research University ‘Moscow Power Engineering Institute’, 111250 Moscow, Russian Federation
10.71267/mencom.7792
Published 2025-10-21
Communication , Volume 35, Issue 6, 746-748
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Slesarenko N. A. et al. The role of diglyme and tetraglyme in the formation of ion transport pathways in gel electrolytes based on polyethylene glycol diacrylate // Mendeleev Communications. 2025. Vol. 35. No. 6. pp. 746-748.
GOST all authors (up to 50) Copy
Slesarenko N. A., Chernyak A. V., Volkov V. I., Khatmullina K. G., Yudina A. V., Tulibaeva G. Z., Slesarenko A. A., Baymuratova G. R., Shestakov A. F., Yarmolenko O. V. The role of diglyme and tetraglyme in the formation of ion transport pathways in gel electrolytes based on polyethylene glycol diacrylate // Mendeleev Communications. 2025. Vol. 35. No. 6. pp. 746-748.
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TY - JOUR
DO - 10.71267/mencom.7792
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7792
TI - The role of diglyme and tetraglyme in the formation of ion transport pathways in gel electrolytes based on polyethylene glycol diacrylate
T2 - Mendeleev Communications
AU - Slesarenko, Nikita Andreevich
AU - Chernyak, Alexander Vladimirovich
AU - Volkov, Vitaly Ivanovich
AU - Khatmullina, Kyunsylu Gumerovna
AU - Yudina, Alena Vladimirovna
AU - Tulibaeva, Galiya Zaynetdinovna
AU - Slesarenko, Anna Alekseevna
AU - Baymuratova, Guzaliya Rafikovna
AU - Shestakov, Alexander Fedorovich
AU - Yarmolenko, Ol'ga Viktorovna
PY - 2025
DA - 2025/10/21
PB - Mendeleev Communications
SP - 746-748
IS - 6
VL - 35
ER -
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@article{2025_Slesarenko,
author = {Nikita Andreevich Slesarenko and Alexander Vladimirovich Chernyak and Vitaly Ivanovich Volkov and Kyunsylu Gumerovna Khatmullina and Alena Vladimirovna Yudina and Galiya Zaynetdinovna Tulibaeva and Anna Alekseevna Slesarenko and Guzaliya Rafikovna Baymuratova and Alexander Fedorovich Shestakov and Ol'ga Viktorovna Yarmolenko},
title = {The role of diglyme and tetraglyme in the formation of ion transport pathways in gel electrolytes based on polyethylene glycol diacrylate},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7792},
number = {6},
pages = {746--748},
doi = {10.71267/mencom.7792}
}
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Slesarenko, Nikita Andreevich, et al. “The role of diglyme and tetraglyme in the formation of ion transport pathways in gel electrolytes based on polyethylene glycol diacrylate.” Mendeleev Communications, vol. 35, no. 6, Oct. 2025, pp. 746-748. https://mendcomm.colab.ws/publications/10.71267/mencom.7792.
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Keywords

7Li spin relaxation
conductivity
diffusion coefficient.
diglyme
electrochemical impedance
LiBF4
lithium anode
PFG NMR
tetraglyme

Abstract

The methods of 7Li spin relaxation and pulsed field gradient NMR were used to reveal the features of local transport of Li+ cations in two polymer gel electrolytes containing an ionic liquid, the salt LiBF4 and a solvent, diglyme (G2) or tetraglyme (G4). It was found that the macroscopic mass transfer of Li+ cations is affected by their solvate environment from both glyme solvents and the polymer matrix. In the presence of G4, a denser three-dimensional network is formed, hindering the transport of all ions.

Funders

Ministry of Education and Science of the Russian Federation
124013000743-3 (FFSG-2024-0008)