Home / Publications / Polyfluorinated Blatter radicals

Polyfluorinated Blatter radicals

Dmitry Aleksandrovich Gulyaev 1
Dmitry Aleksandrovich Gulyaev
, 
Nurlan V. Gadimov 1, 2
Nurlan V. Gadimov
, 
Nina Pavlovna Gritsan 3
Nina Pavlovna Gritsan
, 
Evgeny Mikhailovich Kadilenko 3
Evgeny Mikhailovich Kadilenko
, 
Pavel Germanovich Shangin 1
Pavel Germanovich Shangin
, 
Mikhail Aleksandrovich Syroeshkin 1
Mikhail Aleksandrovich Syroeshkin
, 
Egor Aleksandrovich Sosunov 2, 4
Egor Aleksandrovich Sosunov
, 
Eugene Viktorovich Tretyakov 1
Eugene Viktorovich Tretyakov
2 D. Mendeleev University of Chemical Technology of Russia, 125047 Moscow, Russian Federation
3 V. V. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation
10.71267/mencom.7724
Published 2025-02-18
Communication , Volume 35, Issue 2, 169-171
0
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Gulyaev D. A. et al. Polyfluorinated Blatter radicals // Mendeleev Communications. 2025. Vol. 35. No. 2. pp. 169-171.
GOST all authors (up to 50) Copy
Gulyaev D. A., Gadimov N. V., Gritsan N. P., Kadilenko E. M., Shangin P. G., Syroeshkin M. A., Sosunov E. A., Tretyakov E. V. Polyfluorinated Blatter radicals // Mendeleev Communications. 2025. Vol. 35. No. 2. pp. 169-171.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.71267/mencom.7724
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7724
TI - Polyfluorinated Blatter radicals
T2 - Mendeleev Communications
AU - Gulyaev, Dmitry Aleksandrovich
AU - Gadimov, Nurlan V.
AU - Gritsan, Nina Pavlovna
AU - Kadilenko, Evgeny Mikhailovich
AU - Shangin, Pavel Germanovich
AU - Syroeshkin, Mikhail Aleksandrovich
AU - Sosunov, Egor Aleksandrovich
AU - Tretyakov, Eugene Viktorovich
PY - 2025
DA - 2025/02/18
PB - Mendeleev Communications
SP - 169-171
IS - 2
VL - 35
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2025_Gulyaev,
author = {Dmitry Aleksandrovich Gulyaev and Nurlan V. Gadimov and Nina Pavlovna Gritsan and Evgeny Mikhailovich Kadilenko and Pavel Germanovich Shangin and Mikhail Aleksandrovich Syroeshkin and Egor Aleksandrovich Sosunov and Eugene Viktorovich Tretyakov},
title = {Polyfluorinated Blatter radicals},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7724},
number = {2},
pages = {169--171},
doi = {10.71267/mencom.7724}
}
MLA
Cite this
MLA Copy
Gulyaev, Dmitry Aleksandrovich, et al. “Polyfluorinated Blatter radicals.” Mendeleev Communications, vol. 35, no. 2, Feb. 2025, pp. 169-171. https://mendcomm.colab.ws/publications/10.71267/mencom.7724.

Keywords

1,2,4-benzotriazin-4-yls
Heterocycles
magnetostructural correlations
organic radicals
organofluorine compounds

Abstract

The first benzotriazinyl radicals containing fluorine atoms in both aryl substituents were synthesized from polyfluorophenylhydrazines and 4-fluoro-N-phenylbenzimidoyl chloride. Their crystal structure and magnetic properties were studied thus revealing strong antiferromagnetic interactions (J/kB from –160 to –185 K).

References

2.
Liquid crystalline derivatives of heterocyclic radicals
Kaszyński P., Kapuściński S., Ciastek-Iskrzycka S.
Advances in Heterocyclic Chemistry, 2019
3.
Ziarani G.M., Mostofi M., Gholamzadeh P., Mohammadi-Khanaposhtani M., Yavari H.
Arkivoc, 2019
4.
Benzotriazinyl-mediated controlled radical polymerization of styrene
Demetriou M., Berezin A.A., Koutentis P.A., Krasia-Christoforou T.
Polymer International, 2013
5.
Triazine-mediated controlled radical polymerization: new unimolecular initiators
Areephong J., Mattson K.M., Treat N.J., Poelma S.O., Kramer J.W., Sprafke H.A., Latimer A.A., Read de Alaniz J., Hawker C.J.
Polymer Chemistry, 2016
6.
Recent advances of stable Blatter radicals: synthesis, properties and applications
Ji Y., Long L., Zheng Y.
Materials Chemistry Frontiers, 2020
7.
Recent advances in the chemistry of benzo[e][1,2,4]triazinyl radicals
Rogers F.J., Norcott P.L., Coote M.L.
Organic and Biomolecular Chemistry, 2020
9.
Substituent-Dependent Magnetic Behavior of Discotic Benzo[e][1,2,4]triazinyls
Jasiński M., Szczytko J., Pociecha D., Monobe H., Kaszyński P.
Journal of the American Chemical Society, 2016
10.
Temperature Tunable Self‐Doping in Stable Diradicaloid Thin‐Film Devices
Zhang Y., Zheng Y., Zhou H., Miao M., Wudl F., Nguyen T.
Advanced Materials, 2015
11.
From radical to triradical thin film processes: the Blatter radical derivatives
Calzolari A., Rajca A., Casu M.B.
Journal of Materials Chemistry C, 2021
12.
A Solid‐State Effect Responsible for an Organic Quintet State at Room Temperature and Ambient Pressure
Zheng Y., Miao M., Dantelle G., Eisenmenger N.D., Wu G., Yavuz I., Chabinyc M.L., Houk K.N., Wudl F.
Advanced Materials, 2015
13.
Blatter‐Radical‐Grafted Mesoporous Silica as Prospective Nanoplatform for Spin Manipulation at Ambient Conditions
Poryvaev A.S., Gjuzi E., Polyukhov D.M., Hoffmann F., Fröba M., Fedin M.V.
Angewandte Chemie - International Edition, 2021
15.
New Blatter-type radicals from a bench-stable carbene
Grant J.A., Lu Z., Tucker D.E., Hockin B.M., Yufit D.S., Fox M.A., Kataky R., Chechik V., O’Donoghue A.C.
Nature Communications, 2017
18.
Expedient synthesis of 1,2,4-triazinyl substituted benzo[c]coumarins via double oxidation strategy
Fatykhov R.F., Khalymbadzha I.A., Sharapov A.D., Potapova A.P., Starnovskaya E.S., Kopchuk D.S., Chupakhin O.N.
Chimica Techno Acta, 2023
19.
Buravlev A.A., Makarov A.Y., Rakitin O.A., Zibarev A.V.
Mendeleev Communications, 2023
20.
Effects of Difluorophenyl Substituents on Structural, Redox, and Magnetic Properties of Blatter Radicals
Gulyaev D., Serykh A., Tretyakov E., Akyeva A., Syroeshkin M., Gorbunov D.E., Maltseva S.V., Gritsan N.P., Romanenko G., Bogomyakov A.
Catalysts, 2023
22.
Polyfluorophenyl-Substituted Blatter Radicals: Synthesis and Structure–Property Correlations
Gulyaev D., Serykh A., Gorbunov D., Gritsan N., Akyeva A., Syroeshkin M., Romanenko G., Tretyakov E.
Crystal Growth and Design, 2024