Home / Publications / In situ electrolytic reduction of copper ions in the mesoporous matrices based on poly(ethylene terephthalate)

In situ electrolytic reduction of copper ions in the mesoporous matrices based on poly(ethylene terephthalate)

Ol'ga Vladimirovna Arzhakova 1
Ol'ga Vladimirovna Arzhakova
, 
Anastasia Vladimirovna Bolshakova 1
Anastasia Vladimirovna Bolshakova
, 
Aleksandr Yuryevich Kopnov 1
Aleksandr Yuryevich Kopnov
,  , 
Aleksandra Aleksandrovna Zvonova 1
Aleksandra Aleksandrovna Zvonova
, 
Sofiya Andreevna Sorochinskaya 1
Sofiya Andreevna Sorochinskaya
, 
Larisa Mikhailovna Yarysheva 1
Larisa Mikhailovna Yarysheva
, 
Alena Yur'evna Yarysheva 1
Alena Yur'evna Yarysheva
10.71267/mencom.7720
Published 2025-07-17
Communication , Volume 35, Issue 5, 580-582
0
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Arzhakova O. V. et al. In situ electrolytic reduction of copper ions in the mesoporous matrices based on poly(ethylene terephthalate) // Mendeleev Communications. 2025. Vol. 35. No. 5. pp. 580-582.
GOST all authors (up to 50) Copy
Arzhakova O. V., Bolshakova A. V., Kopnov A. Y., Chaplygin D. K., Zvonova A. A., Sorochinskaya S. A., Yarysheva L. M., Yarysheva A. Y. In situ electrolytic reduction of copper ions in the mesoporous matrices based on poly(ethylene terephthalate) // Mendeleev Communications. 2025. Vol. 35. No. 5. pp. 580-582.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.71267/mencom.7720
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7720
TI - In situ electrolytic reduction of copper ions in the mesoporous matrices based on poly(ethylene terephthalate)
T2 - Mendeleev Communications
AU - Arzhakova, Ol'ga Vladimirovna
AU - Bolshakova, Anastasia Vladimirovna
AU - Kopnov, Aleksandr Yuryevich
AU - Chaplygin, Denis Kirillovich
AU - Zvonova, Aleksandra Aleksandrovna
AU - Sorochinskaya, Sofiya Andreevna
AU - Yarysheva, Larisa Mikhailovna
AU - Yarysheva, Alena Yur'evna
PY - 2025
DA - 2025/07/17
PB - Mendeleev Communications
SP - 580-582
IS - 5
VL - 35
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2025_Arzhakova,
author = {Ol'ga Vladimirovna Arzhakova and Anastasia Vladimirovna Bolshakova and Aleksandr Yuryevich Kopnov and Denis Kirillovich Chaplygin and Aleksandra Aleksandrovna Zvonova and Sofiya Andreevna Sorochinskaya and Larisa Mikhailovna Yarysheva and Alena Yur'evna Yarysheva},
title = {In situ electrolytic reduction of copper ions in the mesoporous matrices based on poly(ethylene terephthalate)},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7720},
number = {5},
pages = {580--582},
doi = {10.71267/mencom.7720}
}
MLA
Cite this
MLA Copy
Arzhakova, Ol'ga Vladimirovna, et al. “In situ electrolytic reduction of copper ions in the mesoporous matrices based on poly(ethylene terephthalate).” Mendeleev Communications, vol. 35, no. 5, Jul. 2025, pp. 580-582. https://mendcomm.colab.ws/publications/10.71267/mencom.7720.

Keywords

composite materials
copper-filled polymers.
crazing
electrolytical reduction
metal-filled polymers
porosity

Abstract

A simple, eco-friendly, reagent-free and cost-effective approach of in situ electrolytic reduction of copper sulfate that allows one to prepare copper-filled thin-film composite materials based on the mesoporous poly(ethylene terephthalate) (PET) films after their deformation via the mechanism of classical crazing with formation of discrete crazes with a fibrillar-porous structure is presented. The structure and properties of the copper-filled polymer materials with different levels of loading with metallic copper have been studied by X-ray analysis and scanning electron microscopy. It has been shown that metallic copper is located within the porous crazes; the degree of loading is controlled by the porosity of the PET films and it can achieve 150 wt%.

Funders

Ministry of Education and Science of the Russian Federation
State Assignment no. AAAA-A21-121011990022-4