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Novel naphthalene benzimidazole-based materials for potassium metal batteries: revealing the importance of molecular weight for material performance

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Baluda Y. I. et al. Novel naphthalene benzimidazole-based materials for potassium metal batteries: revealing the importance of molecular weight for material performance // Mendeleev Communications. 2025. Vol. 36. No. 1. pp. 79-81.
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Baluda Y. I., Mumyatov A. V., Savinykh T. A., Antoshkina E. P., Vasil’ev S. G., Shestakov A. F., Troshin P. A., Kraevaya O. A. Novel naphthalene benzimidazole-based materials for potassium metal batteries: revealing the importance of molecular weight for material performance // Mendeleev Communications. 2025. Vol. 36. No. 1. pp. 79-81.
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TY - JOUR
DO - 10.71267/mencom.7719
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7719
TI - Novel naphthalene benzimidazole-based materials for potassium metal batteries: revealing the importance of molecular weight for material performance
T2 - Mendeleev Communications
AU - Baluda, Yuriy I
AU - Mumyatov, Alexander V
AU - Savinykh, Tatiana A.
AU - Antoshkina, Evgenia P.
AU - Vasil’ev, S. G.
AU - Shestakov, Alexander Fedorovich
AU - Troshin, Pavel A.
AU - Kraevaya, Olga Alexandrovna
PY - 2025
DA - 2025/11/29
PB - Mendeleev Communications
SP - 79-81
IS - 1
VL - 36
ER -
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@article{2025_Baluda,
author = {Yuriy I Baluda and Alexander V Mumyatov and Tatiana A. Savinykh and Evgenia P. Antoshkina and S. G. Vasil’ev and Alexander Fedorovich Shestakov and Pavel A. Troshin and Olga Alexandrovna Kraevaya},
title = {Novel naphthalene benzimidazole-based materials for potassium metal batteries: revealing the importance of molecular weight for material performance},
journal = {Mendeleev Communications},
year = {2025},
volume = {36},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7719},
number = {1},
pages = {79--81},
doi = {10.71267/mencom.7719}
}
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Baluda, Yuriy I., et al. “Novel naphthalene benzimidazole-based materials for potassium metal batteries: revealing the importance of molecular weight for material performance.” Mendeleev Communications, vol. 36, no. 1, Nov. 2025, pp. 79-81. https://mendcomm.colab.ws/publications/10.71267/mencom.7719.
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Keywords

1
4
5
8-naphthalenetetracarboxylic dianhydride
aminophenazines
lithium metal battery
naphthalene benzimidazoles.
organic electrode materials
polyimides
potassium metal battery

Abstract

A family of novel naphthalene benzimidazole (NBI)-based materials with different molecular weights was prepared by condensing 1,4,5,8-naphthalenetetracarboxylic dianhydride with 2,3-diaminophenazine, 2,3,7,8-tetraaminophenazine or their mixture. Of these materials, only intermediate molecular weight NBI provides high specific discharge capacity and exhibits good cycling stability and rate capability in potassium cells, while polymeric NBI also demonstrated decent performance in lithium cells. The results suggest a new approach for further rational design of NBI materials for metal-ion batteries with improved performance.

Funders

Ministry of Education and Science of the Russian Federation
FFSG- 2025-0005 (125032604442-5)

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