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Electrochemical behavior of bridged 1,2,4-dioxazolidine derivative in acetonitrile medium on the smooth gold

Mikhail V. Polyakov 1
Mikhail V. Polyakov
, 
Marina Dmitrievna Vedenyapina 1
Marina Dmitrievna Vedenyapina
, 
Alexandr Mordukhaevich Skundin 2
Alexandr Mordukhaevich Skundin
,  ,  , 
Yulia Yuryevna Belyakova 1
Yulia Yuryevna Belyakova
10.71267/mencom.7714
Published 2025-05-21
Communication , Volume 35, Issue 4, 417-419
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Polyakov M. V. et al. Electrochemical behavior of bridged 1,2,4-dioxazolidine derivative in acetonitrile medium on the smooth gold // Mendeleev Communications. 2025. Vol. 35. No. 4. pp. 417-419.
GOST all authors (up to 50) Copy
Polyakov M. V., Vedenyapina M. D., Skundin A. M., Yaremenko I. A., Radulov P. S., Belyakova Y. Y. Electrochemical behavior of bridged 1,2,4-dioxazolidine derivative in acetonitrile medium on the smooth gold // Mendeleev Communications. 2025. Vol. 35. No. 4. pp. 417-419.
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TY - JOUR
DO - 10.71267/mencom.7714
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7714
TI - Electrochemical behavior of bridged 1,2,4-dioxazolidine derivative in acetonitrile medium on the smooth gold
T2 - Mendeleev Communications
AU - Polyakov, Mikhail V.
AU - Vedenyapina, Marina Dmitrievna
AU - Skundin, Alexandr Mordukhaevich
AU - Yaremenko, Ivan Andreevich
AU - Radulov, Peter Sergeyevich
AU - Belyakova, Yulia Yuryevna
PY - 2025
DA - 2025/05/21
PB - Mendeleev Communications
SP - 417-419
IS - 4
VL - 35
ER -
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@article{2025_Polyakov,
author = {Mikhail V. Polyakov and Marina Dmitrievna Vedenyapina and Alexandr Mordukhaevich Skundin and Ivan Andreevich Yaremenko and Peter Sergeyevich Radulov and Yulia Yuryevna Belyakova},
title = {Electrochemical behavior of bridged 1,2,4-dioxazolidine derivative in acetonitrile medium on the smooth gold},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {May},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7714},
number = {4},
pages = {417--419},
doi = {10.71267/mencom.7714}
}
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Polyakov, Mikhail V., et al. “Electrochemical behavior of bridged 1,2,4-dioxazolidine derivative in acetonitrile medium on the smooth gold.” Mendeleev Communications, vol. 35, no. 4, May. 2025, pp. 417-419. https://mendcomm.colab.ws/publications/10.71267/mencom.7714.

Keywords

1
2
4-dioxazolidines
6
7-dioxa-8-azabicyclo-[3.2.1]octane.
anodic oxidation
cathodic reduction
cyclic voltammetry
gold
peroxides

Abstract

Bridged bicyclic peroxide with 1,2,4-dioxazolidine core, namely, ethyl 2-(4-chlorobenzyl)-1,5-dimethyl-6,7-dioxa-8- azabicyclo[3.2.1]octane-2-carboxylate, was studied by cyclic voltammetry in acetonitrile medium on a smooth gold electrode. During the cathode process, two electrons are transferred, with the first electron transfer being reversible; a mechanism of cathode reduction of the substrate involves acetonitrile as the source of protons. The anodic oxidation involves the formation of colloidal gold particles due to corrosion of the gold electrode.

Funders

Ministry of Education and Science of the Russian Federation
FFZZ-2022-03

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