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Symmetrical and unsymmetrical thiophosphoryl–thiocarbamate pincer ligands: cyclopalladation in solution and under solvent-free conditions

Vladimir Andreevich Kozlov 1
Vladimir Andreevich Kozlov
,  , 
Yulia Vladimirovna Nelyubina 2
Yulia Vladimirovna Nelyubina
, 
Svetlana A Soloveva 3, 4
Svetlana A Soloveva
, 
Aleksandr Mikhailovich Shakhov 5
Aleksandr Mikhailovich Shakhov
, 
Zinaida Sergeevna Klemenkova 1
Zinaida Sergeevna Klemenkova
10.71267/mencom.7705
Published 2025-05-21
Communication , Volume 35, Issue 4, 420-423
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Kozlov V. A. et al. Symmetrical and unsymmetrical thiophosphoryl–thiocarbamate pincer ligands: cyclopalladation in solution and under solvent-free conditions // Mendeleev Communications. 2025. Vol. 35. No. 4. pp. 420-423.
GOST all authors (up to 50) Copy
Kozlov V. A., Aleksanyan D. V., Nelyubina Y. V., Soloveva S. A., Shakhov A. M., Klemenkova Z. S. Symmetrical and unsymmetrical thiophosphoryl–thiocarbamate pincer ligands: cyclopalladation in solution and under solvent-free conditions // Mendeleev Communications. 2025. Vol. 35. No. 4. pp. 420-423.
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TY - JOUR
DO - 10.71267/mencom.7705
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7705
TI - Symmetrical and unsymmetrical thiophosphoryl–thiocarbamate pincer ligands: cyclopalladation in solution and under solvent-free conditions
T2 - Mendeleev Communications
AU - Kozlov, Vladimir Andreevich
AU - Aleksanyan, Diana Vladimirovna
AU - Nelyubina, Yulia Vladimirovna
AU - Soloveva, Svetlana A
AU - Shakhov, Aleksandr Mikhailovich
AU - Klemenkova, Zinaida Sergeevna
PY - 2025
DA - 2025/05/21
PB - Mendeleev Communications
SP - 420-423
IS - 4
VL - 35
ER -
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@article{2025_Kozlov,
author = {Vladimir Andreevich Kozlov and Diana Vladimirovna Aleksanyan and Yulia Vladimirovna Nelyubina and Svetlana A Soloveva and Aleksandr Mikhailovich Shakhov and Zinaida Sergeevna Klemenkova},
title = {Symmetrical and unsymmetrical thiophosphoryl–thiocarbamate pincer ligands: cyclopalladation in solution and under solvent-free conditions},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {May},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7705},
number = {4},
pages = {420--423},
doi = {10.71267/mencom.7705}
}
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Kozlov, Vladimir Andreevich, et al. “Symmetrical and unsymmetrical thiophosphoryl–thiocarbamate pincer ligands: cyclopalladation in solution and under solvent-free conditions.” Mendeleev Communications, vol. 35, no. 4, May. 2025, pp. 420-423. https://mendcomm.colab.ws/publications/10.71267/mencom.7705.

Keywords

cyclometalation
Mechanochemistry
palladium
pincer complexes
solvent-free reactions

Abstract

The modern concept of green chemistry calls for the development of more environmentally benign synthetic protocols and a reduction in the use of auxiliary substances, including solvents. In this work the effect of a thiophosphoryl pendant arm on the cyclopalladation features of both symmetrical and unsymmetrical thiocarbamate pincer ligands was explored. The ligands were 1,3-bis(carbamoyloxy)-5-(diphenylthiophosphoryl)- or 1-carbamoyloxy-3-(diphenylthiophosphoryl)benzenes, the palladium source was (PhCN)2PdCl2.

Funders

Russian Science Foundation
22-13-00267