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Synthesis of perfluorobiphenyl tetracarboxylic acids via the CuCl2-assisted homocoupling of organozinc reagents

Andrey Sergeevich Vinogradov 1
Andrey Sergeevich Vinogradov
, 
Vladislav Vladimirovich Komarov 1
Vladislav Vladimirovich Komarov
, 
Vyacheslav Evdokimovich Platonov 1
Vyacheslav Evdokimovich Platonov
, 
Tatyana Vladimirovna Mezhenkova 1
Tatyana Vladimirovna Mezhenkova
10.71267/mencom.7682
Published 2025-03-31
Communication , Volume 35, Issue 3, 264-265
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Vinogradov A. S. et al. Synthesis of perfluorobiphenyl tetracarboxylic acids via the CuCl2-assisted homocoupling of organozinc reagents // Mendeleev Communications. 2025. Vol. 35. No. 3. pp. 264-265.
GOST all authors (up to 50) Copy
Vinogradov A. S., Komarov V. V., Platonov V. E., Mezhenkova T. V. Synthesis of perfluorobiphenyl tetracarboxylic acids via the CuCl2-assisted homocoupling of organozinc reagents // Mendeleev Communications. 2025. Vol. 35. No. 3. pp. 264-265.
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TY - JOUR
DO - 10.71267/mencom.7682
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7682
TI - Synthesis of perfluorobiphenyl tetracarboxylic acids via the CuCl2-assisted homocoupling of organozinc reagents
T2 - Mendeleev Communications
AU - Vinogradov, Andrey Sergeevich
AU - Komarov, Vladislav Vladimirovich
AU - Platonov, Vyacheslav Evdokimovich
AU - Mezhenkova, Tatyana Vladimirovna
PY - 2025
DA - 2025/03/31
PB - Mendeleev Communications
SP - 264-265
IS - 3
VL - 35
ER -
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@article{2025_Vinogradov,
author = {Andrey Sergeevich Vinogradov and Vladislav Vladimirovich Komarov and Vyacheslav Evdokimovich Platonov and Tatyana Vladimirovna Mezhenkova},
title = {Synthesis of perfluorobiphenyl tetracarboxylic acids via the CuCl2-assisted homocoupling of organozinc reagents},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7682},
number = {3},
pages = {264--265},
doi = {10.71267/mencom.7682}
}
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Vinogradov, Andrey Sergeevich, et al. “Synthesis of perfluorobiphenyl tetracarboxylic acids via the CuCl2-assisted homocoupling of organozinc reagents.” Mendeleev Communications, vol. 35, no. 3, Mar. 2025, pp. 264-265. https://mendcomm.colab.ws/publications/10.71267/mencom.7682.

Keywords

biphenyl
homocoupling.
organofluorine compounds
organozinc reagents
tetracarboxylic acids
zinc

Abstract

New organozinc reagents were obtained from ethyl esters of tetrafluorophenylene dicarboxylic acids in the reaction with Zn and SnCl2 in DMF. Tetraethyl perfluorobiphenyl tetracarboxylates were synthesized from these organozinc reagents under the action of CuCl2 and then were hydrolyzed into perfluorobiphenyl tetracarboxylic acids.

Funders

Russian Science Foundation
23-23-00547

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