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Alkali metal reduction of 1,3,2-diazagallol-2-ylidene radical derived from acenaphthene-1,2-diimine

Natalia L'vovna Bazyakina 1
Natalia L'vovna Bazyakina
, 
Alexandra Anatol'evna Skatova 1
Alexandra Anatol'evna Skatova
, 
Eugeny Vladimirovich Baranov 1
Eugeny Vladimirovich Baranov
, 
Igor Leonidovich Fedushkin 1
Igor Leonidovich Fedushkin
10.71267/mencom.7680
Published 2025-05-21
Communication , Volume 35, Issue 4, 424-426
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Bazyakina N. L. et al. Alkali metal reduction of 1,3,2-diazagallol-2-ylidene radical derived from acenaphthene-1,2-diimine // Mendeleev Communications. 2025. Vol. 35. No. 4. pp. 424-426.
GOST all authors (up to 50) Copy
Bazyakina N. L., Skatova A. A., Baranov E. V., Fedushkin I. L. Alkali metal reduction of 1,3,2-diazagallol-2-ylidene radical derived from acenaphthene-1,2-diimine // Mendeleev Communications. 2025. Vol. 35. No. 4. pp. 424-426.
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TY - JOUR
DO - 10.71267/mencom.7680
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7680
TI - Alkali metal reduction of 1,3,2-diazagallol-2-ylidene radical derived from acenaphthene-1,2-diimine
T2 - Mendeleev Communications
AU - Bazyakina, Natalia L'vovna
AU - Skatova, Alexandra Anatol'evna
AU - Baranov, Eugeny Vladimirovich
AU - Fedushkin, Igor Leonidovich
PY - 2025
DA - 2025/05/21
PB - Mendeleev Communications
SP - 424-426
IS - 4
VL - 35
ER -
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@article{2025_Bazyakina,
author = {Natalia L'vovna Bazyakina and Alexandra Anatol'evna Skatova and Eugeny Vladimirovich Baranov and Igor Leonidovich Fedushkin},
title = {Alkali metal reduction of 1,3,2-diazagallol-2-ylidene radical derived from acenaphthene-1,2-diimine},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {May},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7680},
number = {4},
pages = {424--426},
doi = {10.71267/mencom.7680}
}
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Bazyakina, Natalia L'vovna, et al. “Alkali metal reduction of 1,3,2-diazagallol-2-ylidene radical derived from acenaphthene-1,2-diimine.” Mendeleev Communications, vol. 35, no. 4, May. 2025, pp. 424-426. https://mendcomm.colab.ws/publications/10.71267/mencom.7680.

Keywords

alkali metals
diimines
low-valent gallium species
redox-active ligands
reduction

Abstract

Reduction of the open-shell gallylene [(ArBIG-bian)Ga:] {ArBIG-bian = 1,2-bis[(2,6-dibenzhydryl-4-methylphenyl)imino]acenaphthene} with one equivalent of lithium or sodium metal in THF followed by recrystallization from DME or diethyl ether affords the lithium and sodium salts of the anionic 1,3,2-diazagallol, [(ArBIG-bian)GaLi(DME)3] and [(ArBIG-bian)GaNa(Et2O)2(THF)2]. In contrast, reaction of [(ArBIG-bian)Ga:] with potassium gives the solvent-free derivative [(ArBIG-bian)K] and gallium metal.

Funders

Russian Science Foundation
24-13-00369