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Polyphenylenepyridines and nitrogen-containing carbon materials based on them

Alexey Ivanovich Kovalev 1
Alexey Ivanovich Kovalev
Maria Alekseevna Kovaleva 1
Maria Alekseevna Kovaleva
Sergei Sergeevich Bukalov 1
Sergei Sergeevich Bukalov
Suria Aleksandrovna Babich 1
Suria Aleksandrovna Babich
Natalia Sergeevna Revizorova 1
Natalia Sergeevna Revizorova
Sergey Evgen'evich Lyubimov 1
Sergey Evgen'evich Lyubimov
Irina Anatol'evna Khotina 1
Irina Anatol'evna Khotina
Yaroslav Olegovich Mezhuev 1, 2
Yaroslav Olegovich Mezhuev
Published 2025-03-31
CommunicationVolume 35, Issue 3, 337-340
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Kovalev A. I. et al. Polyphenylenepyridines and nitrogen-containing carbon materials based on them // Mendeleev Communications. 2025. Vol. 35. No. 3. pp. 337-340.
GOST all authors (up to 50) Copy
Kovalev A. I., Naumkin A. V., Kovaleva M. A., Bukalov S. S., Babich S. A., Revizorova N. S., Lyubimov S. E., Khotina I. A., Mezhuev Y. O. Polyphenylenepyridines and nitrogen-containing carbon materials based on them // Mendeleev Communications. 2025. Vol. 35. No. 3. pp. 337-340.
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TY - JOUR
DO - 10.71267/mencom.7659
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7659
TI - Polyphenylenepyridines and nitrogen-containing carbon materials based on them
T2 - Mendeleev Communications
AU - Kovalev, Alexey Ivanovich
AU - Naumkin, Alexander Vasil'evich
AU - Kovaleva, Maria Alekseevna
AU - Bukalov, Sergei Sergeevich
AU - Babich, Suria Aleksandrovna
AU - Revizorova, Natalia Sergeevna
AU - Lyubimov, Sergey Evgen'evich
AU - Khotina, Irina Anatol'evna
AU - Mezhuev, Yaroslav Olegovich
PY - 2025
DA - 2025/03/31
PB - Mendeleev Communications
SP - 337-340
IS - 3
VL - 35
ER -
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@article{2025_Kovalev,
author = {Alexey Ivanovich Kovalev and Alexander Vasil'evich Naumkin and Maria Alekseevna Kovaleva and Sergei Sergeevich Bukalov and Suria Aleksandrovna Babich and Natalia Sergeevna Revizorova and Sergey Evgen'evich Lyubimov and Irina Anatol'evna Khotina and Yaroslav Olegovich Mezhuev},
title = {Polyphenylenepyridines and nitrogen-containing carbon materials based on them},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7659},
number = {3},
pages = {337--340},
doi = {10.71267/mencom.7659}
}
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Kovalev, Alexey Ivanovich, et al. “Polyphenylenepyridines and nitrogen-containing carbon materials based on them.” Mendeleev Communications, vol. 35, no. 3, Mar. 2025, pp. 337-340. https://mendcomm.colab.ws/publications/10.71267/mencom.7659.

Keywords

p-diacetylbenzene
4,4'-diacetylbiphenyl
polyphenylenepyridines
porosity
pyrolysis
pyropolymers
specific surface area, X-ray photoelectron spectroscopy

Abstract

On the basis of p-diacetylbenzene and 4,4'-diacetylbiphenyl, polyphenylenepyridines with a ratio of pyridine to phenylene rings of 1 : 5–6.5 were synthesized. Their heating in argon at 450, 800 and 1000 °C afforded porous polymers with a specific surface area up to 1146 m2 g–1. X-ray photoelectron spectroscopy of these substances showed that nitrogen atoms in them exist mainly in the form of graphite- and pyridine-like systems.

Funders

Russian Science Foundation
19-73-20262P

References

.
Metal-Free Catalysts for Oxygen Reduction Reaction
Dai L., Xue Y., Qu L., Choi H., Baek J.
Chemical Reviews, 2015
.
Exploration of the active center structure of nitrogen-doped graphene-based catalysts for oxygen reduction reaction
Lai L., Potts J.R., Zhan D., Wang L., Poh C.K., Tang C., Gong H., Shen Z., Lin J., Ruoff R.S.
Energy and Environmental Science, 2012
.
Luminescent poly(phenylene vinylene) derivatives withm-terphenyl or 2,6-diphenylpyridine kinked segments along the main chain: Synthesis, characterization, and stimulated emission
Karastatiris P., Mikroyannidis J.A., Spiliopoulos I.K., Fakis M., Persephonis P.
Journal of Polymer Science, Part A: Polymer Chemistry, 2004
.
Khotina I.A., Filippov O.A., Kovalev A.I.
Mendeleev Communications, 2020
.
Oxygen Reduction Electrocatalysts toward Practical Fuel Cells: Progress and Perspectives
Zaman S., Huang L., Douka A.I., Yang H., You B., Xia B.Y.
Angewandte Chemie - International Edition, 2021
.
Ultrahigh Surface Area Three-Dimensional Porous Graphitic Carbon from Conjugated Polymeric Molecular Framework
To J.W., Chen Z., Yao H., He J., Kim K., Chou H., Pan L., Wilcox J., Cui Y., Bao Z.
ACS Central Science, 2015
.
Enriching Atomic Cobalt in an Ultrathin Porous Carbon Shell for Enhanced Electrocatalysis
Zhang T., Cheng F., Zhao C., Liu H., Song X., Li X., Luo W.
ACS applied materials & interfaces, 2021
.
Hyperporous Carbons from Hypercrosslinked Polymers
Lee J.M., Briggs M.E., Hasell T., Cooper A.I.
Advanced Materials, 2016
.
Highly Efficient Electrocatalysts for Oxygen Reduction Reaction Based on 1D Ternary Doped Porous Carbons Derived from Carbon Nanotube Directed Conjugated Microporous Polymers
He Y., Gehrig D., Zhang F., Lu C., Zhang C., Cai M., Wang Y., Laquai F., Zhuang X., Feng X.
Advanced Functional Materials, 2016
.
Carbon‐Supported Divacancy‐Anchored Platinum Single‐Atom Electrocatalysts with Superhigh Pt Utilization for the Oxygen Reduction Reaction
Liu J., Jiao M., Mei B., Tong Y., Li Y., Ruan M., Song P., Sun G., Jiang L., Wang Y., Jiang Z., Gu L., Zhou Z., Xu W.
Angewandte Chemie - International Edition, 2019
.
Metal–Organic Frameworks Based Electrocatalysts for the Oxygen Reduction Reaction
Lu X.F., Xia B.Y., Zang S., Lou X.W.
Angewandte Chemie - International Edition, 2019
.
Nitrogen-doped graphene and its electrochemical applications
Shao Y., Zhang S., Engelhard M.H., Li G., Shao G., Wang Y., Liu J., Aksay I.A., Lin Y.
Journal of Materials Chemistry A, 2010
.
Microporous Polymers Based on Rigid-Chain Di- And Triacetyl Aromatic Compounds
Kovalev A.I., Babich S.A., Kovaleva M.A., Kushakova N.S., Klemenkova Z.S., Blinnikova Z.K., Popov A.Y., Khotina I.A.
Polymer Science - Series B, 2021
.
Polyphenylenes with Phen-1,3,5-triyl Branching Moieties Based on p-Diacetylbenzene: Synthesis and Study of Porosity and Heat Resistance
Kovalev A.I., Pastukhov A.V., Tkachenko E.S., Klemenkova Z.S., Kuvshinov I.R., Khotina I.A.
Polymer Science - Series C, 2020
.
Polyphenylene Gels
Kovalev A.I., Mart’yanova E.S., Khotina I.A., Klemenkova Z.S., Blinnikova Z.K., Volchkova E.V., Loginova T.P., Ponomarev I.I.
Polymer Science - Series B, 2018
.
Identification of active sites for acidic oxygen reduction on carbon catalysts with and without nitrogen doping
Jia Y., Zhang L., Zhuang L., Liu H., Yan X., Wang X., Liu J., Wang J., Zheng Y., Xiao Z., Taran E., Chen J., Yang D., Zhu Z., Wang S., et. al.
Nature Catalysis, 2019
.
Few-layer graphdiyne doped with sp-hybridized nitrogen atoms at acetylenic sites for oxygen reduction electrocatalysis
Zhao Y., Wan J., Yao H., Zhang L., Lin K., Wang L., Yang N., Liu D., Song L., Zhu J., Gu L., Liu L., Zhao H., Li Y., Wang D., et. al.
Nature Chemistry, 2018
.
The promotion effects of graphitic and pyridinic N combinational doping on graphene for ORR
Yan P., Liu J., Yuan S., Liu Y., Cen W., Chen Y.
Applied Surface Science, 2018
.
Nitrogen-doping hollow carbon nanospheres derived from conjugated microporous polymers toward oxygen reduction reaction
Sun H., Zhou P., Ye X., Wang J., Tian Z., Zhu Z., Ma C., Liang W., Li A.
Journal of Colloid and Interface Science, 2022
.
Boosting selective C2H2/CH4, C2H4/CH4 and CO2/CH4 adsorption performance via 1,2,3-triazole functionalized triazine-based porous organic polymers
Liu X., Du J., Ye Y., Liu Y., Wang S., Meng X., Song X., Liang Z., Yan W.
Chinese Journal of Chemical Engineering, 2022
.
Kovalev A.I., Khotina I.A.
Mendeleev Communications, 2022
.
Alternative pathways of the reaction between acetophenone and triethyl orthoformate
Kovaleva M.A., Kovalev A.I., Khotina I.A.
Russian Chemical Bulletin, 2023
.
Polyphenylenepyridines Based on Acetylaromatic Compounds
Kovalev A.I., Khotina I.A., Kovaleva M.A., Naumkin A.V., Ionova I.S., Mezhuev Y.O.
Journal of Composites Science, 2023