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A novel approach to the preparation of hollow fiber membranes from heat-resistant polynaphthoylenebenzimidazole

Lydia Alexandrovna Varfolomeeva 1
Lydia Alexandrovna Varfolomeeva
Andrey Fedorovich Vashchenko 1
Andrey Fedorovich Vashchenko
Igor Igorevich Ponomarev 2
Igor Igorevich Ponomarev
Alexander Yur'evich Alentiev 1
Alexander Yur'evich Alentiev
Roman Yur'evich Nikifirov 1
Roman Yur'evich Nikifirov
Timofey Dmitrievich Patsaev 3
Timofey Dmitrievich Patsaev
Valerii Grigor'evich Kulichikhin 1
Valerii Grigor'evich Kulichikhin
Published 2025-03-31
CommunicationVolume 35, Issue 3, 334-336
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Varfolomeeva L. A. et al. A novel approach to the preparation of hollow fiber membranes from heat-resistant polynaphthoylenebenzimidazole // Mendeleev Communications. 2025. Vol. 35. No. 3. pp. 334-336.
GOST all authors (up to 50) Copy
Varfolomeeva L. A., Vashchenko A. F., Ponomarev I. I., Alentiev A. Y., Nikifirov R. Y., Patsaev T. D., Kulichikhin V. G. A novel approach to the preparation of hollow fiber membranes from heat-resistant polynaphthoylenebenzimidazole // Mendeleev Communications. 2025. Vol. 35. No. 3. pp. 334-336.
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TY - JOUR
DO - 10.71267/mencom.7658
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7658
TI - A novel approach to the preparation of hollow fiber membranes from heat-resistant polynaphthoylenebenzimidazole
T2 - Mendeleev Communications
AU - Varfolomeeva, Lydia Alexandrovna
AU - Vashchenko, Andrey Fedorovich
AU - Ponomarev, Igor Igorevich
AU - Alentiev, Alexander Yur'evich
AU - Nikifirov, Roman Yur'evich
AU - Patsaev, Timofey Dmitrievich
AU - Kulichikhin, Valerii Grigor'evich
PY - 2025
DA - 2025/03/31
PB - Mendeleev Communications
SP - 334-336
IS - 3
VL - 35
ER -
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@article{2025_Varfolomeeva,
author = {Lydia Alexandrovna Varfolomeeva and Andrey Fedorovich Vashchenko and Igor Igorevich Ponomarev and Alexander Yur'evich Alentiev and Roman Yur'evich Nikifirov and Timofey Dmitrievich Patsaev and Valerii Grigor'evich Kulichikhin},
title = {A novel approach to the preparation of hollow fiber membranes from heat-resistant polynaphthoylenebenzimidazole},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7658},
number = {3},
pages = {334--336},
doi = {10.71267/mencom.7658}
}
MLA
Cite this
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Varfolomeeva, Lydia Alexandrovna, et al. “A novel approach to the preparation of hollow fiber membranes from heat-resistant polynaphthoylenebenzimidazole.” Mendeleev Communications, vol. 35, no. 3, Mar. 2025, pp. 334-336. https://mendcomm.colab.ws/publications/10.71267/mencom.7658.

Keywords

gas separation characteristics
hollow fiber
membrane
poly(o-aminophenylene)naphthoylenimide
polynaphthoylenebenzimidazole
rheology

Abstract

For the first time, hollow fiber polynaphthoylenebenzimidazole (PNBI) membranes were obtained by a two-stage acid-free method through a precursor fiber made of poly(o-aminophenylene)naphthoylenimide (PANI-O) by its subsequent heat treatment, leading to the formation of PNBI. The gas separation characteristics of such fiber at room temperature for H2, He, O2 and CO2 were studied by an integral method. It was shown that PNBI is one of the most promising polymers for the manufacture of thermally stable gas separation membranes with high productivity.

Funders

Russian Science Foundation
23-19-00222

References

1.
Membranes for hydrogen separation: a significant review
Sazali N., Mohamed M.A., Salleh W.N.
International Journal of Advanced Manufacturing Technology, 2020
2.
Membranes for Hydrogen Separation
Ockwig N.W., Nenoff T.M.
Chemical Reviews, 2007
3.
New Approach to Preparation of Heat-Resistant “Lola-M” Fiber
Ponomarev I.I., Skvortsov I.Y., Volkova Y.A., Ponomarev I.I., Varfolomeeva L.A., Razorenov D.Y., Skupov K.M., Kuzin M.S., Serenko O.A.
Materials, 2019
4.
Solubility, Rheology, and Coagulation Kinetics of Poly-(O-Aminophenylene)Naphthoylenimide Solutions
Skvortsov I.Y., Kulichikhin V.G., Ponomarev I.I., Varfolomeeva L.A., Kuzin M.S., Skupov K.M., Volkova Y.A., Razorenov D.Y., Serenko O.A.
Polymers, 2020
5.
Some Specifics of Defect-Free Poly-(o-aminophenylene)naphthoylenimide Fibers Preparation by Wet Spinning
Skvortsov I.Y., Kulichikhin V.G., Ponomarev I.I., Varfolomeeva L.A., Kuzin M.S., Razorenov D.Y., Skupov K.M.
Materials, 2022
6.
Improving the hydrogen selectivity of graphene oxide membranes by reducing non-selective pores with intergrown ZIF-8 crystals
Wang X., Chi C., Tao J., Peng Y., Ying S., Qian Y., Dong J., Hu Z., Gu Y., Zhao D.
Chemical Communications, 2016
7.
Elevated-temperature H2 separation using a dense electron and proton mixed conducting polybenzimidazole-based membrane with 2D sulfonated graphene
Jin Y., Gao B., Bian C., Meng X., Meng B., Wong S.I., Yang N., Sunarso J., Tan X., Liu S.
Green Chemistry, 2021
10.
Investigation of the thermal properties of mixtures of heat-resistant polymers by the DTG method
Khudoshev I.F., Fedorova R.G., Serova L.D., Krasnykh L.F., Babushkina M.P., Koretskaya A.I.
Fibre chemistry, 1981
11.
Facile hydrogen/nitrogen separation through graphene oxide membranes supported on YSZ ceramic hollow fibers
Zhu J., Meng X., Zhao J., Jin Y., Yang N., Zhang S., Sunarso J., Liu S.
Journal of Membrane Science, 2017
12.
Polybenzimidazole (PBI) high temperature polymers and blends
Dawkins B.G., Qin F., Gruender M., Copeland G.S.
2014
13.
Novel Trends in Ladder Polyheteroarylenes
Korshak V.V., Rusanov A.L.
Journal of Macromolecular Science Part C- Polymer Reviews, 1981
14.
Thermally stable polymers for advanced high-performance gas separation membranes
Rezakazemi M., Sadrzadeh M., Matsuura T.
Progress in Energy and Combustion Science, 2018
15.
The stepwise synthesis of polynaphthoylenebenzimidazoles
Korshak V.V., Berestneva G.L., Petrovskii P.V., Ormotsadze P.S., Rusanov A.L., Berlin A.M., Adyrkhayeva F.I.
Polymer Science U S S R, 1981
16.
Polynaphthoylenebenzimidazoles for gas separation – Unexpected PIM relatives
Ponomarev I.I., Volkova Y.A., Ponomarev I.I., Razorenov D.Y., Skupov K.M., Nikiforov R.Y., Chirkov S.V., Ryzhikh V.E., Belov N.A., Alentiev A.Y.
Polymer, 2022
17.
A more environmentally friendly path to the family of the flame-resistant semi-ladder “Lola” fibers
Skvortsov I.Y., Ponomarev I.I., Varfolomeeva L.A., Kuzin M.S., Razorenov D.Y., Skupov K.M., Ponomarev I.I., Zuev K.V., Levin I.S., Shandryuk G., Kulichikhin V.G.
Polymer, 2022
18.
Materials and techniques for hydrogen separation from methane-containing gas mixtures
Lider A., Kudiiarov V., Kurdyumov N., Lyu J., Koptsev M., Travitzky N., Hotza D.
International Journal of Hydrogen Energy, 2023
19.
Skvortsov I.Y., Varfolomeeva L.A., Vashchenko A.F., Ponomarev I.I., Patsaev T.D., Alentiev A.Y., Kulichikhin V.G.
Mendeleev Communications, 2024