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Hydroxycarbonylation of vinyl acetate with formic acid: pathway to lactic acid and lactates

Oleg Leonidovich Eliseev 1
Oleg Leonidovich Eliseev
, 
Tatyana Nikolaevna Bondarenko 1
Tatyana Nikolaevna Bondarenko
, 
Maria Vadimovna Tsapkina 1
Maria Vadimovna Tsapkina
10.71267/mencom.7657
Published 2025-05-21
Communication , Volume 35, Issue 4, 472-474
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Eliseev O. L., Bondarenko T. N., Tsapkina M. V. Hydroxycarbonylation of vinyl acetate with formic acid: pathway to lactic acid and lactates // Mendeleev Communications. 2025. Vol. 35. No. 4. pp. 472-474.
GOST all authors (up to 50) Copy
Eliseev O. L., Bondarenko T. N., Tsapkina M. V. Hydroxycarbonylation of vinyl acetate with formic acid: pathway to lactic acid and lactates // Mendeleev Communications. 2025. Vol. 35. No. 4. pp. 472-474.
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TY - JOUR
DO - 10.71267/mencom.7657
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7657
TI - Hydroxycarbonylation of vinyl acetate with formic acid: pathway to lactic acid and lactates
T2 - Mendeleev Communications
AU - Eliseev, Oleg Leonidovich
AU - Bondarenko, Tatyana Nikolaevna
AU - Tsapkina, Maria Vadimovna
PY - 2025
DA - 2025/05/21
PB - Mendeleev Communications
SP - 472-474
IS - 4
VL - 35
ER -
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@article{2025_Eliseev,
author = {Oleg Leonidovich Eliseev and Tatyana Nikolaevna Bondarenko and Maria Vadimovna Tsapkina},
title = {Hydroxycarbonylation of vinyl acetate with formic acid: pathway to lactic acid and lactates},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {May},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7657},
number = {4},
pages = {472--474},
doi = {10.71267/mencom.7657}
}
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Eliseev, Oleg Leonidovich, et al. “Hydroxycarbonylation of vinyl acetate with formic acid: pathway to lactic acid and lactates.” Mendeleev Communications, vol. 35, no. 4, May. 2025, pp. 472-474. https://mendcomm.colab.ws/publications/10.71267/mencom.7657.

Keywords

acetoxypropionic acid.
carbon monoxide
formic acid
hydroxycarbonylation
palladium
vinyl acetate

Abstract

The Pd-catalyzed hydroxycarbonylation of vinyl acetate in the presence of formic acid into 2-acetoxypropionic acid is reported. The reaction proceeds chemo- and regioselectively under very mild conditions of 80 °C and 3-6 bar CO.