Home / Publications / New tricyclic cage compound as allosteric modulator of the glutamatergic system: synthesis and biological activity

New tricyclic cage compound as allosteric modulator of the glutamatergic system: synthesis and biological activity

Elena Andreevna Golubeva 1
Elena Andreevna Golubeva
Mstislav Igorevich Lavrov 1
Mstislav Igorevich Lavrov
Eugene V Radchenko 1
Eugene V Radchenko
Vladimir Lollievich Zamoyski 2
Vladimir Lollievich Zamoyski
Vladimir Viktorovich Grigoriev 1, 2
Vladimir Viktorovich Grigoriev
Vladimir Alexandrovich Palyulin 1
Vladimir Alexandrovich Palyulin
2 Institute of Physiologically Active Compounds, Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation
Published 2025-02-18
CommunicationVolume 35, Issue 2, 142-144
0
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Golubeva E. A. et al. New tricyclic cage compound as allosteric modulator of the glutamatergic system: synthesis and biological activity // Mendeleev Communications. 2025. Vol. 35. No. 2. pp. 142-144.
GOST all authors (up to 50) Copy
Golubeva E. A., Lavrov M. I., Veremeeva P. N., Matthews J., Radchenko E. V., Zamoyski V. L., Grigoriev V. V., Palyulin V. A. New tricyclic cage compound as allosteric modulator of the glutamatergic system: synthesis and biological activity // Mendeleev Communications. 2025. Vol. 35. No. 2. pp. 142-144.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.71267/mencom.7654
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7654
TI - New tricyclic cage compound as allosteric modulator of the glutamatergic system: synthesis and biological activity
T2 - Mendeleev Communications
AU - Golubeva, Elena Andreevna
AU - Lavrov, Mstislav Igorevich
AU - Veremeeva, Polina Nikolaevna
AU - Matthews, James
AU - Radchenko, Eugene V
AU - Zamoyski, Vladimir Lollievich
AU - Grigoriev, Vladimir Viktorovich
AU - Palyulin, Vladimir Alexandrovich
PY - 2025
DA - 2025/02/18
PB - Mendeleev Communications
SP - 142-144
IS - 2
VL - 35
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2025_Golubeva,
author = {Elena Andreevna Golubeva and Mstislav Igorevich Lavrov and Polina Nikolaevna Veremeeva and James Matthews and Eugene V Radchenko and Vladimir Lollievich Zamoyski and Vladimir Viktorovich Grigoriev and Vladimir Alexandrovich Palyulin},
title = {New tricyclic cage compound as allosteric modulator of the glutamatergic system: synthesis and biological activity},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7654},
number = {2},
pages = {142--144},
doi = {10.71267/mencom.7654}
}
MLA
Cite this
MLA Copy
Golubeva, Elena Andreevna, et al. “New tricyclic cage compound as allosteric modulator of the glutamatergic system: synthesis and biological activity.” Mendeleev Communications, vol. 35, no. 2, Feb. 2025, pp. 142-144. https://mendcomm.colab.ws/publications/10.71267/mencom.7654.

Keywords

2-amino-4-methoxybenzoic acid
3,7-diazabicyclo[3.3.1]nonanes
allosteric modulators
AMPA receptor
glutamatergic system
indane derivatives
PAMs
patch clamp

Abstract

A new tricyclic derivative of 1,5-dimethyl-3,7-diazabicyclo[3.3.1]nonane was synthesized in three steps using 2-aminoindane-5-carbonitrile. A positive modulatory activity of this compound towards the glutamatergic system in a wide range of nanomolar and subnanomolar concentrations has been demonstrated in electrophysiological studies in vitro using patch clamp technique. A putative binding mode of this compound has been revealed by means of molecular docking and molecular dynamics simulations.

Funders

Russian Science Foundation
22-15-00041

References

1.
CHARMM36 all-atom additive protein force field: Validation based on comparison to NMR data
2.
GROMACS: High performance molecular simulations through multi-level parallelism from laptops to supercomputers
Abraham M.J., Murtola T., Schulz R., Páll S., Smith J.C., Hess B., Lindahl E.
SoftwareX, 2015
3.
CHARMM general force field: A force field for drug-like molecules compatible with the CHARMM all-atom additive biological force fields
Vanommeslaeghe K., Hatcher E., Acharya C., Kundu S., Zhong S., Shim J., Darian E., Guvench O., Lopes P., Vorobyov I., Mackerell A.D.
Journal of Computational Chemistry, 2009
4.
Quantifying the chemical beauty of drugs
Bickerton G.R., Paolini G.V., Besnard J., Muresan S., Hopkins A.L.
Nature Chemistry, 2012
5.
Online chemical modeling environment (OCHEM): web platform for data storage, model development and publishing of chemical information
Sushko I., Novotarskyi S., Körner R., Pandey A.K., Rupp M., Teetz W., Brandmaier S., Abdelaziz A., Prokopenko V.V., Tanchuk V.Y., Todeschini R., Varnek A., Marcou G., Ertl P., Potemkin V., et. al.
Journal of Computer-Aided Molecular Design, 2011
7.
Computer-aided estimation of the hERG-mediated cardiotoxicity risk of potential drug components
Radchenko E.V., Rulev Y.A., Safanyaev A.Y., Palyulin V.A., Zefirov N.S.
Doklady Biochemistry and Biophysics, 2017
8.
Lavrov M.I., Veremeeva P.N., Karlov D.S., Zamoyski V.L., Grigoriev V.V., Palyulin V.A.
Mendeleev Communications, 2019
9.
Prediction of human intestinal absorption of drug compounds
Radchenko E.V., Dyabina A.S., Palyulin V.A., Zefirov N.S.
Russian Chemical Bulletin, 2016
11.
Novel Positive Allosteric Modulators of AMPA Receptors Based on 3,7-Diazabicyclo[3.3.1]nonane Scaffold
Lavrov M.I., Karlov D.S., Voronina T.A., Grigoriev V.V., Ustyugov A.A., Bachurin S.O., Palyulin V.A.
Molecular Neurobiology, 2019
12.
Positive Allosteric Modulators of the α-Amino-3-hydroxy-5-methyl-4-isoxazolepropionic Acid (AMPA) Receptor
Grove S.J., Jamieson C., Maclean J.K., Morrow J.A., Rankovic Z.
Journal of Medicinal Chemistry, 2010
14.
S 47445 Produces Antidepressant- and Anxiolytic-Like Effects through Neurogenesis Dependent and Independent Mechanisms
Mendez-David I., Guilloux J., Papp M., Tritschler L., Mocaer E., Gardier A.M., Bretin S., David D.J.
Frontiers in Pharmacology, 2017
15.
Antidepressant-Like Effects of CX717, a Positive Allosteric Modulator of AMPA Receptors
Gordillo-Salas M., Pascual-Antón R., Ren J., Greer J., Adell A.
Molecular Neurobiology, 2020
16.
Unusual transformations of anthranilic acid imidazolides
Baranov M.S., Yampolsky I.V.
Chemistry of Heterocyclic Compounds, 2012
20.
AMPA receptor positive allosteric modulators: a patent review
Pirotte B., Francotte P., Goffin E., de Tullio P.
Expert Opinion on Therapeutic Patents, 2013
23.
Effects of chronic systemic low-impact ampakine treatment on neurotrophin expression in rat brain
Radin D.P., Johnson S., Purcell R., Lippa A.S.
Biomedicine and Pharmacotherapy, 2018
24.
Lavrov M.I., Veremeeva P.N., Golubeva E.A., Radchenko E.V., Zamoyski V.L., Grigoriev V.V., Palyulin V.A.
Mendeleev Communications, 2022
25.
Golubeva E.A., Lavrov M.I., Veremeeva P.N., Bovina E.M., Radchenko E.V., Topchiy M.A., Asachenko A.F., Zamoyski V.L., Grigoriev V.V., Palyulin V.A.
Mendeleev Communications, 2023
27.
New Allosteric Modulators of AMPA Receptors: Synthesis and Study of Their Functional Activity by Radioligand-Receptor Binding Analysis
Golubeva E.A., Lavrov M.I., Veremeeva P.N., Vyunova T.V., Shevchenko K.V., Topchiy M.A., Asachenko A.F., Palyulin V.A.
International Journal of Molecular Sciences, 2023