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Dehydrogenation of N-ethyldodecahydrocarbazole over Pt/C catalyst in the hydrogen storage aspect

Leonid Modestovich Kustov 1, 2, 3
Leonid Modestovich Kustov
, 
Alexander Nikolaevich Kalenchuk 1, 2
Alexander Nikolaevich Kalenchuk
, 
Viktor Ignat'evich Bogdan 1, 2
Viktor Ignat'evich Bogdan
10.71267/mencom.7652
Published 2025-03-31
Communication , Volume 35, Issue 3, 356-358
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Kustov L. M., Kalenchuk A. N., Bogdan V. I. Dehydrogenation of N-ethyldodecahydrocarbazole over Pt/C catalyst in the hydrogen storage aspect // Mendeleev Communications. 2025. Vol. 35. No. 3. pp. 356-358.
GOST all authors (up to 50) Copy
Kustov L. M., Kalenchuk A. N., Bogdan V. I. Dehydrogenation of N-ethyldodecahydrocarbazole over Pt/C catalyst in the hydrogen storage aspect // Mendeleev Communications. 2025. Vol. 35. No. 3. pp. 356-358.
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TY - JOUR
DO - 10.71267/mencom.7652
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7652
TI - Dehydrogenation of N-ethyldodecahydrocarbazole over Pt/C catalyst in the hydrogen storage aspect
T2 - Mendeleev Communications
AU - Kustov, Leonid Modestovich
AU - Kalenchuk, Alexander Nikolaevich
AU - Bogdan, Viktor Ignat'evich
PY - 2025
DA - 2025/03/31
PB - Mendeleev Communications
SP - 356-358
IS - 3
VL - 35
ER -
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@article{2025_Kustov,
author = {Leonid Modestovich Kustov and Alexander Nikolaevich Kalenchuk and Viktor Ignat'evich Bogdan},
title = {Dehydrogenation of N-ethyldodecahydrocarbazole over Pt/C catalyst in the hydrogen storage aspect},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7652},
number = {3},
pages = {356--358},
doi = {10.71267/mencom.7652}
}
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Kustov, Leonid Modestovich, et al. “Dehydrogenation of N-ethyldodecahydrocarbazole over Pt/C catalyst in the hydrogen storage aspect.” Mendeleev Communications, vol. 35, no. 3, Mar. 2025, pp. 356-358. https://mendcomm.colab.ws/publications/10.71267/mencom.7652.

Keywords

N-ethyldodecahydrocarbazole
dehydrogenation
Hydrogen storage
hydrogenation
liquid organic hydrogen carriers
Pt/C catalyst

Abstract

The optimum conditions (T = 210 °C and VL = 1 h–1) were determined for the dehydrogenation of N-ethyldodecahydrocarbazole on a 3 wt% Pt/C catalyst in a flow-type catalytic unit at normal pressure. The kinetic parameters (conversion and selectivity) of the dehydrogenation process correlated well with the volumes of released hydrogen. High purity of the thus produced hydrogen was established by chromatography.

Funders

Ministry of Education and Science of the Russian Federation
project 075-15-2023-585

References

1.
Nanostructured materials for low-temperature fuel cells†
Yaroslavtsev A.B., Dobrovolsky Y.A., Shaglaeva N.S., Frolova L.A., Gerasimova E.V., Sanginov E.A.
Russian Chemical Reviews, 2012
2.
Current research trends and perspectives on materials-based hydrogen storage solutions: A critical review
Ren J., Musyoka N.M., Langmi H.W., Mathe M., Liao S.
International Journal of Hydrogen Energy, 2017
3.
Systems for accumulation, storage and release of hydrogen
Kustov L.M., Kalenchuk A.N., Bogdan V.I.
Russian Chemical Reviews, 2020
6.
Size and Structure Effects Controlling the Stability of the Liquid Organic Hydrogen Carrier Dodecahydro-N-ethylcarbazole during Dehydrogenation over Pt Model Catalysts
Amende M., Gleichweit C., Schernich S., Höfert O., Lorenz M.P., Zhao W., Koch M., Obesser K., Papp C., Wasserscheid P., Steinrück H., Libuda J.
Journal of Physical Chemistry Letters, 2014
7.
Model Catalytic Studies of Liquid Organic Hydrogen Carriers: Dehydrogenation and Decomposition Mechanisms of Dodecahydro-N-ethylcarbazole on Pt(111)
Amende M., Gleichweit C., Werner K., Schernich S., Zhao W., Lorenz M.P., Höfert O., Papp C., Koch M., Wasserscheid P., Laurin M., Steinrück H., Libuda J.
ACS Catalysis, 2014
11.
Efficient hydrogen production using cyclohexane and decalin by pulse-spray mode reactor with Pt catalysts
Kariya N., Fukuoka A., Utagawa T., Sakuramoto M., Goto Y., Ichikawa M.
Applied Catalysis A: General, 2003
12.
Dehydrogenation of Dodecahydro-N-ethylcarbazole on Pt(111)
Gleichweit C., Amende M., Schernich S., Zhao W., Lorenz M.P., Höfert O., Brückner N., Wasserscheid P., Libuda J., Steinrück H., Papp C.
ChemSusChem, 2013
14.
Effect of surface hydrophilization on Pt/Sibunit catalytic activity in bicyclohexyl dehydrogenation in hydrogen storage application
Kalenchuk A.N., Bogdan V.I., Dunaev S.F., Kustov L.M.
International Journal of Hydrogen Energy, 2018
15.
Dehydrogenation kinetics and catalysis of organic heteroaromatics for hydrogen storage
Sotoodeh F., Huber B.J., Smith K.J.
International Journal of Hydrogen Energy, 2012
17.
Hydrogen storage by decalin dehydrogenation/naphthalene hydrogenation pair over platinum catalysts supported on activated carbon
Sebastián D., Bordejé E.G., Calvillo L., Lázaro M.J., Moliner R.
International Journal of Hydrogen Energy, 2008