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Ilia Romanovich Cherkashchenko 1, 2
Ilia Romanovich Cherkashchenko
, 
Rodion Vladislavovich Panin 2
Rodion Vladislavovich Panin
, 
Alexander Victorovich Babkin 2
Alexander Victorovich Babkin
, 
Daniil Andreevich Novichkov 2
Daniil Andreevich Novichkov
, 
Evgenii Viktorovich Antipov 1, 2
Evgenii Viktorovich Antipov
, 
Nellie Rakipovna Khasanova 2
Nellie Rakipovna Khasanova
10.71267/mencom.7637
Published 2025-05-21
Communication , Volume 35, Issue 4, 393-395
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TY - JOUR
DO - 10.71267/mencom.7637
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7637
T2 - Mendeleev Communications
AU - Cherkashchenko, Ilia Romanovich
AU - Panin, Rodion Vladislavovich
AU - Babkin, Alexander Victorovich
AU - Novichkov, Daniil Andreevich
AU - Antipov, Evgenii Viktorovich
AU - Khasanova, Nellie Rakipovna
PY - 2025
DA - 2025/05/21
PB - Mendeleev Communications
SP - 393-395
IS - 4
VL - 35
ER -
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@article{2025_Cherkashchenko,
author = {Ilia Romanovich Cherkashchenko and Rodion Vladislavovich Panin and Alexander Victorovich Babkin and Daniil Andreevich Novichkov and Evgenii Viktorovich Antipov and Nellie Rakipovna Khasanova},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {May},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7637},
number = {4},
pages = {393--395},
doi = {10.71267/mencom.7637}
}

Keywords

NASICON-type phosphate
niobium multielectron redox reaction
sodium-ion battery
sol–gel synthesis
thermal stability

Abstract

The NASICON-structured NaAlNb(PO4)3 phosphate was synthesized via Pechini sol–gel technique. Electrochemical measurements in sodium half-cells have disclosed that NaAlNb(PO4)3 can reversibly intercalate 2Na+ ions per formula unit owing to the Nb5+/Nb4+/Nb3+ multielectron redox processes, which was confirmed by the Nb K-edge XANES measurements. Differential thermal calorimetry has revealed an excellent thermal stability of the sodiated NaAlNb(PO4)3/C electrode material up to the point of electrolyte decomposition.

Funders

Russian Science Foundation
23-13-00071

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