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Transfer hydrodechlorination of chlorobenzene over Ni--Mo sulfide system and effect of HCl neutralizer

Alexander Sergeyevich Romanov 1
Alexander Sergeyevich Romanov
, 
Nikolay Sergeevich Nesterov 1
Nikolay Sergeevich Nesterov
, 
Anna Anatol'evna Salomatina 1
Anna Anatol'evna Salomatina
,  , 
Vera P Pakharukova 1
Vera P Pakharukova
, 
Alexey Alexandrovich Philippov 1
Alexey Alexandrovich Philippov
, 
Ivan Vasil'evich Kozhevnikov 1
Ivan Vasil'evich Kozhevnikov
, 
Andrei Mikhailovich Chibiryaev 1
Andrei Mikhailovich Chibiryaev
, 
Oleg Nikolaevich Martyanov 1
Oleg Nikolaevich Martyanov
1 G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation
10.71267/mencom.7630
Published 2025-03-31
Communication , Volume 35, Issue 3, 351-352
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Romanov A. S. et al. Transfer hydrodechlorination of chlorobenzene over Ni--Mo sulfide system and effect of HCl neutralizer // Mendeleev Communications. 2025. Vol. 35. No. 3. pp. 351-352.
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Romanov A. S., Nesterov N. S., Salomatina A. A., Klimov O. V., Pakharukova V. P., Philippov A. A., Kozhevnikov I. V., Chibiryaev A. M., Martyanov O. N. Transfer hydrodechlorination of chlorobenzene over Ni--Mo sulfide system and effect of HCl neutralizer // Mendeleev Communications. 2025. Vol. 35. No. 3. pp. 351-352.
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TY - JOUR
DO - 10.71267/mencom.7630
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7630
TI - Transfer hydrodechlorination of chlorobenzene over Ni--Mo sulfide system and effect of HCl neutralizer
T2 - Mendeleev Communications
AU - Romanov, Alexander Sergeyevich
AU - Nesterov, Nikolay Sergeevich
AU - Salomatina, Anna Anatol'evna
AU - Klimov, Oleg Vladimirovich
AU - Pakharukova, Vera P
AU - Philippov, Alexey Alexandrovich
AU - Kozhevnikov, Ivan Vasil'evich
AU - Chibiryaev, Andrei Mikhailovich
AU - Martyanov, Oleg Nikolaevich
PY - 2025
DA - 2025/03/31
PB - Mendeleev Communications
SP - 351-352
IS - 3
VL - 35
ER -
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@article{2025_Romanov,
author = {Alexander Sergeyevich Romanov and Nikolay Sergeevich Nesterov and Anna Anatol'evna Salomatina and Oleg Vladimirovich Klimov and Vera P Pakharukova and Alexey Alexandrovich Philippov and Ivan Vasil'evich Kozhevnikov and Andrei Mikhailovich Chibiryaev and Oleg Nikolaevich Martyanov},
title = {Transfer hydrodechlorination of chlorobenzene over Ni--Mo sulfide system and effect of HCl neutralizer},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7630},
number = {3},
pages = {351--352},
doi = {10.71267/mencom.7630}
}
MLA
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Romanov, Alexander Sergeyevich, et al. “Transfer hydrodechlorination of chlorobenzene over Ni--Mo sulfide system and effect of HCl neutralizer.” Mendeleev Communications, vol. 35, no. 3, Mar. 2025, pp. 351-352. https://mendcomm.colab.ws/publications/10.71267/mencom.7630.

Keywords

2-propanol
benzene.
chlorobenzene
nickel�molybdenum sulfide system
transfer hydrodechlorination

Abstract

Catalytic transfer hydrodechlorination of chlorobenzene using 2-propanol as the hydrogen donor and a mixed Ni-Mo sulfide phase deposited on alumina as the catalyst is studied at temperatures 250-300 °C. When triethylamine is applied as the HCl neutralizer, benzene is the only product, whereas with inorganic bases (iso)propylbenzenes are also formed.

Funders

Russian Science Foundation
24-23-20054

References

.
The Golden Age of Transfer Hydrogenation
Wang D., Astruc D.
Chemical Reviews, 2015
.
Catalytic Hydrodeoxygenation of Algae Bio-oil over Bimetallic Ni–Cu/ZrO2 Catalysts
Guo Q., Wu M., Wang K., Zhang L., Xu X.
Industrial & Engineering Chemistry Research, 2015
.
Synthesis of Catalytic Precursors Based on Mixed Ni-Al Oxides by Supercritical Antisolvent Co-Precipitation
Nesterov N.S., Pakharukova V.P., Philippov A.A., Gerasimov E.Y., Tsybulya S.V., Martyanov O.N.
Catalysts, 2022
.
Advanced High-Loaded Ni–Cu Catalysts in Transfer Hydrogenation of Anisole: Unexpected Effect of Cu Addition
Philippov A., Nesterov N., Pakharukova V., Kozhevnikov I., Martyanov O.
Catalysts, 2022
.
Catalytic conversion of waste plastics: focus on waste PVC
Keane M.A.
Journal of Chemical Technology and Biotechnology, 2007
.
Hydrodechlorination of 4-chlorophenol in aqueous phase with Pt–Al pillared clays using formic acid as hydrogen source
Molina C.B., Calvo L., Gilarranz M.A., Casas J.A., Rodriguez J.J.
Applied Clay Science, 2009
.
Effect of the reducing agent on the hydrodechlorination of dioxins over 2wt.% Pd/γ-Al2O3
Cobo M., Conesa J.A., Montes de Correa C.
Applied Catalysis B: Environmental, 2009
.
Hashimoto Y., Uemichi Y., Ayame A.
Journal of the Japan Petroleum Institute, 2005
.
Primary alcohols as killers of Ni-based catalysts in transfer hydrogenation
Nesterov N., Philippov A., Pakharukova V., Gerasimov E., Yakushkin S., Martyanov O.
Chinese Journal of Catalysis, 2024