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Palladium-catalyzed amination in the synthesis of novel fluorescent sensors based on 3,3'-diamino substituted 1,1'-bi(2-naphthol)

Kirill S Zazerin 1
Kirill S Zazerin
, 
Alexei Aleksandrovich Yakushev 1
Alexei Aleksandrovich Yakushev
, 
Alexei Dmitrievich Averin 1
Alexei Dmitrievich Averin
, 
10.71267/mencom.7629
Published 2025-01-24
Communication , Volume 35, Issue 1, 11-13
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Zazerin K. S. et al. Palladium-catalyzed amination in the synthesis of novel fluorescent sensors based on 3,3'-diamino substituted 1,1'-bi(2-naphthol) // Mendeleev Communications. 2025. Vol. 35. No. 1. pp. 11-13.
GOST all authors (up to 50) Copy
Zazerin K. S., Yakushev A. A., Averin A. D., Beletskaya I. P. Palladium-catalyzed amination in the synthesis of novel fluorescent sensors based on 3,3'-diamino substituted 1,1'-bi(2-naphthol) // Mendeleev Communications. 2025. Vol. 35. No. 1. pp. 11-13.
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TY - JOUR
DO - 10.71267/mencom.7629
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7629
TI - Palladium-catalyzed amination in the synthesis of novel fluorescent sensors based on 3,3'-diamino substituted 1,1'-bi(2-naphthol)
T2 - Mendeleev Communications
AU - Zazerin, Kirill S
AU - Yakushev, Alexei Aleksandrovich
AU - Averin, Alexei Dmitrievich
AU - Beletskaya, Irina Petrovna
PY - 2025
DA - 2025/01/24
PB - Mendeleev Communications
SP - 11-13
IS - 1
VL - 35
ER -
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@article{2025_Zazerin,
author = {Kirill S Zazerin and Alexei Aleksandrovich Yakushev and Alexei Dmitrievich Averin and Irina Petrovna Beletskaya},
title = {Palladium-catalyzed amination in the synthesis of novel fluorescent sensors based on 3,3'-diamino substituted 1,1'-bi(2-naphthol)},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7629},
number = {1},
pages = {11--13},
doi = {10.71267/mencom.7629}
}
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Zazerin, Kirill S., et al. “Palladium-catalyzed amination in the synthesis of novel fluorescent sensors based on 3,3'-diamino substituted 1,1'-bi(2-naphthol).” Mendeleev Communications, vol. 35, no. 1, Jan. 2025, pp. 11-13. https://mendcomm.colab.ws/publications/10.71267/mencom.7629.

Keywords

1
1'-bi(2-naphthol)
amination
catalysis
detection.
fluorescence
macrocycle
metal cations
palladium

Abstract

The first example of palladium-catalyzed Buchwald-Hartwig amination of 3,3'-dibromo-1,1'-bi(2-naphthol) is reported. Linear and macrocyclic derivatives of N,N'-disubstituted 3,3'-diamino-1,1'-bi(2-naphthols) thus obtained are able to detect metal cations when using UV and fluorescence spectroscopy.

Funders

Russian Science Foundation
23-73-01049

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