Home / Publications / Effect of macrocycle stereoisomerism on extraction of Li+ cations from chloride media by solutions of dicyclohexano-14-crown-4 in 1,1,7-trihydrododecafluoroheptanol

Effect of macrocycle stereoisomerism on extraction of Li+ cations from chloride media by solutions of dicyclohexano-14-crown-4 in 1,1,7-trihydrododecafluoroheptanol

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Andrey Fedorovich Asachenko 2
Andrey Fedorovich Asachenko
,  , 
10.71267/mencom.7622
Published 2025-03-31
Communication , Volume 35, Issue 3, 362-363
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Zakurdaeva O. A. et al. Effect of macrocycle stereoisomerism on extraction of Li+ cations from chloride media by solutions of dicyclohexano-14-crown-4 in 1,1,7-trihydrododecafluoroheptanol // Mendeleev Communications. 2025. Vol. 35. No. 3. pp. 362-363.
GOST all authors (up to 50) Copy
Zakurdaeva O. A., Asachenko A. F., Topchiy M. A., Nesterov S. V. Effect of macrocycle stereoisomerism on extraction of Li+ cations from chloride media by solutions of dicyclohexano-14-crown-4 in 1,1,7-trihydrododecafluoroheptanol // Mendeleev Communications. 2025. Vol. 35. No. 3. pp. 362-363.
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TY - JOUR
DO - 10.71267/mencom.7622
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7622
TI - Effect of macrocycle stereoisomerism on extraction of Li+ cations from chloride media by solutions of dicyclohexano-14-crown-4 in 1,1,7-trihydrododecafluoroheptanol
T2 - Mendeleev Communications
AU - Zakurdaeva, Olga Anatol'evna
AU - Asachenko, Andrey Fedorovich
AU - Topchiy, Maxim Anatol'evich
AU - Nesterov, Sergey Vladimirovich
PY - 2025
DA - 2025/03/31
PB - Mendeleev Communications
SP - 362-363
IS - 3
VL - 35
ER -
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@article{2025_Zakurdaeva,
author = {Olga Anatol'evna Zakurdaeva and Andrey Fedorovich Asachenko and Maxim Anatol'evich Topchiy and Sergey Vladimirovich Nesterov},
title = {Effect of macrocycle stereoisomerism on extraction of Li+ cations from chloride media by solutions of dicyclohexano-14-crown-4 in 1,1,7-trihydrododecafluoroheptanol},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7622},
number = {3},
pages = {362--363},
doi = {10.71267/mencom.7622}
}
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Zakurdaeva, Olga Anatol'evna, et al. “Effect of macrocycle stereoisomerism on extraction of Li+ cations from chloride media by solutions of dicyclohexano-14-crown-4 in 1,1,7-trihydrododecafluoroheptanol.” Mendeleev Communications, vol. 35, no. 3, Mar. 2025, pp. 362-363. https://mendcomm.colab.ws/publications/10.71267/mencom.7622.
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Keywords

1,1,7-trihydrododecafluoroheptanol
dicyclohexano-14-crown-4
lithium extraction
Selectivity
stereoisomerism

Abstract

The new extractant based on dicyclohexano-14-crown-4 solution in 1,1,7-trihydrododecafluoroheptanol is proposed for the removal of lithium cations from the chloride media, such as reservoir waters. The stereoisomerism of the macrocyclic ligand is revealed to be a key factor determining the efficiency and selectivity of this system.

Funders

Ministry of Education and Science of the Russian Federation
FFSM-2024-0001

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