Home / Publications / CsPbBr3 and Cs4PbBr6 perovskite nanoparticles: hidden potential of Cs4PbBr6 or ineffective fluorescence?

CsPbBr3 and Cs4PbBr6 perovskite nanoparticles: hidden potential of Cs4PbBr6 or ineffective fluorescence?

Alexandra Grigorievna Son 1
Alexandra Grigorievna Son
Valeria Anatol'evna Gushchina 1
Valeria Anatol'evna Gushchina
Anastasia Aleksandrovna Egorova 1
Anastasia Aleksandrovna Egorova
Alexey Aleksandrovich Sadovnikov 1
Alexey Aleksandrovich Sadovnikov
Nikolay Alekseevich Bert 2
Nikolay Alekseevich Bert
Alexey Raisovich Tameev 3
Alexey Raisovich Tameev
Sergei Aleksandrovich Kozyukhin 1
Sergei Aleksandrovich Kozyukhin
Published 2025-02-18
CommunicationVolume 35, Issue 2, 193-195
0
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Son A. G. et al. CsPbBr3 and Cs4PbBr6 perovskite nanoparticles: hidden potential of Cs4PbBr6 or ineffective fluorescence? // Mendeleev Communications. 2025. Vol. 35. No. 2. pp. 193-195.
GOST all authors (up to 50) Copy
Son A. G., Gushchina V. A., Egorova A. A., Sadovnikov A. A., Bert N. A., Tameev A. R., Kozyukhin S. A. CsPbBr3 and Cs4PbBr6 perovskite nanoparticles: hidden potential of Cs4PbBr6 or ineffective fluorescence? // Mendeleev Communications. 2025. Vol. 35. No. 2. pp. 193-195.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.71267/mencom.7612
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7612
TI - CsPbBr3 and Cs4PbBr6 perovskite nanoparticles: hidden potential of Cs4PbBr6 or ineffective fluorescence?
T2 - Mendeleev Communications
AU - Son, Alexandra Grigorievna
AU - Gushchina, Valeria Anatol'evna
AU - Egorova, Anastasia Aleksandrovna
AU - Sadovnikov, Alexey Aleksandrovich
AU - Bert, Nikolay Alekseevich
AU - Tameev, Alexey Raisovich
AU - Kozyukhin, Sergei Aleksandrovich
PY - 2025
DA - 2025/02/18
PB - Mendeleev Communications
SP - 193-195
IS - 2
VL - 35
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2025_Son,
author = {Alexandra Grigorievna Son and Valeria Anatol'evna Gushchina and Anastasia Aleksandrovna Egorova and Alexey Aleksandrovich Sadovnikov and Nikolay Alekseevich Bert and Alexey Raisovich Tameev and Sergei Aleksandrovich Kozyukhin},
title = {CsPbBr3 and Cs4PbBr6 perovskite nanoparticles: hidden potential of Cs4PbBr6 or ineffective fluorescence?},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7612},
number = {2},
pages = {193--195},
doi = {10.71267/mencom.7612}
}
MLA
Cite this
MLA Copy
Son, Alexandra Grigorievna, et al. “CsPbBr3 and Cs4PbBr6 perovskite nanoparticles: hidden potential of Cs4PbBr6 or ineffective fluorescence?.” Mendeleev Communications, vol. 35, no. 2, Feb. 2025, pp. 193-195. https://mendcomm.colab.ws/publications/10.71267/mencom.7612.

Keywords

Cs4PbBr6
CsPbBr3
luminescence
nanoparticles
optical absorbance
perovskite

Abstract

All-inorganic perovskite CsPbBr3 and Cs4PbBr6 nanoparticles are intensively studied for their unique optical properties, though synthesizing single-phase nanoparticles has posed challenges. Detailed synthesis method of CsPbBr3 and Cs4PbBr6 single-phase nanoparticles and their chemical and phase analysis are described. Distinctive optical characteristics, such as photoluminescence, optical band gap and the Urbach tail region, are revealed and explained within the current conception of perovskite band structures.

Funders

Russian Science Foundation
23-19-00884

References

1.
Nanocrystals of Cesium Lead Halide Perovskites (CsPbX3, X = Cl, Br, and I): Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut
Protesescu L., Yakunin S., Bodnarchuk M.I., Krieg F., Caputo R., Hendon C.H., Yang R.X., Walsh A., Kovalenko M.V.
Nano Letters, 2015
2.
Highly Luminescent Cesium Lead Halide Perovskite Nanocrystals with Tunable Composition and Thickness by Ultrasonication
Tong Y., Bladt E., Aygüler M.F., Manzi A., Milowska K.Z., Hintermayr V.A., Docampo P., Bals S., Urban A.S., Polavarapu L., Feldmann J.
Angewandte Chemie - International Edition, 2016
4.
All‐Inorganic CsPbX 3 Perovskite Solar Cells: Progress and Prospects
Zhang J., Hodes G., Jin Z., Liu S.(.
Angewandte Chemie - International Edition, 2019
5.
Recombination Kinetics in Organic-Inorganic Perovskites: Excitons, Free Charge, and Subgap States
Stranks S.D., Burlakov V.M., Leijtens T., Ball J.M., Goriely A., Snaith H.J.
Physical Review Applied, 2014
6.
Nearly Monodisperse Insulator Cs4PbX6 (X = Cl, Br, I) Nanocrystals, Their Mixed Halide Compositions, and Their Transformation into CsPbX3 Nanocrystals
Akkerman Q.A., Park S., Radicchi E., Nunzi F., Mosconi E., De Angelis F., Brescia R., Rastogi P., Prato M., Manna L.
Nano Letters, 2017
7.
Unveiling the Two-Step Formation Pathway of Cs4PbBr6 Nanocrystals
Hui J., Jiang Y., Gökçinar Ö.Ö., Tang J., Yu Q., Zhang M., Yu K.
Chemistry of Materials, 2020
8.
Ligand Mediated Transformation of Cesium Lead Bromide Perovskite Nanocrystals to Lead Depleted Cs4PbBr6 Nanocrystals.
Liu Z., Bekenstein Y., Ye X., Nguyen S.C., Swabeck J., Zhang D., Lee S., Yang P., Ma W., Alivisatos A.P.
Journal of the American Chemical Society, 2017
9.
Molecular behavior of zero-dimensional perovskites
Yin J., Maity P., De Bastiani M., Dursun I., Bakr O.M., Brédas J., Mohammed O.F.
Science advances, 2017
10.
Intrinsic doping limit and defect-assisted luminescence in Cs4PbBr6
Jung Y., Calbo J., Park J., Whalley L.D., Kim S., Walsh A.
Journal of Materials Chemistry A, 2019
12.
Shining Emitter in Stable Host: Design Halide Perovskite Scintillators for X-Ray Imaging from Commercial Concept.
Cao F., Yu D., Ma W., Xu X., Cai B., Yang Y.M., Liu S., He L., Ke Y., Lan S., Choy K., Zeng H.
ACS Nano, 2019
13.
Effect of Thermal and Structural Disorder on the Electronic Structure of Hybrid Perovskite Semiconductor CH3NH3PbI3.
Singh S., Li C., Panzer F., Narasimhan K.L., Graeser A., Gujar T.P., Köhler A., Thelakkat M., Huettner S., Kabra D.
Journal of Physical Chemistry Letters, 2016
14.
Efficient Luminescence from Perovskite Quantum Dot Solids.
Kim Y., Yassitepe E., Voznyy O., Comin R., Walters G., Gong X., Kanjanaboos P., Nogueira A.F., Sargent E.H.
ACS applied materials & interfaces, 2015
15.
Fundamental optical absorption of Cs4PbCl6
Kondo S., Amaya K., Higuchi S., Saito T., Asada H., Ishikane M.
Solid State Communications, 2001
16.
Photocarrier recombination dynamics in perovskite CH3NH3PbI3 for solar cell applications.
Yamada Y., Nakamura T., Endo M., Wakamiya A., Kanemitsu Y.
Journal of the American Chemical Society, 2014
17.
CsPbBr3 perovskite detectors with 1.4% energy resolution for high-energy γ-rays
He Y., Petryk M., Liu Z., Chica D.G., Hadar I., Leak C., Ke W., Spanopoulos I., Lin W., Chung D.Y., Wessels B.W., He Z., Kanatzidis M.G.
Nature Photonics, 2020
18.
Highly Luminescent CsPbBr3@Cs4PbBr6 Nanocrystals and Their Application in Electroluminescent Emitters
Bao Z., Chiu H., Wang W., Su Q., Yamada T., Chang Y., Chen S., Kanemitsu Y., Chung R., Liu R.
Journal of Physical Chemistry Letters, 2020
19.
Static Disorder in Lead Halide Perovskites
Zeiske S., Sandberg O.J., Zarrabi N., Wolff C.M., Raoufi M., Peña-Camargo F., Gutierrez-Partida E., Meredith P., Stolterfoht M., Armin A.
Journal of Physical Chemistry Letters, 2022
20.
Ambient Fabrication of Organic–Inorganic Hybrid Perovskite Solar Cells
Zhang Y., Kirs A., Ambroz F., Lin C., Bati A.S., Parkin I.P., Shapter J.G., Batmunkh M., Macdonald T.J.
Small Methods, 2020
21.
In Situ Characterization for Understanding the Degradation in Perovskite Solar Cells
Meng X., Tian X., Zhang S., Zhou J., Zhang Y., Liu Z., Chen W.
Solar RRL, 2022
22.
Highly efficient sky-blue light-emitting diodes based on Cu-treated halide perovskite nanocrystals
Chen F., Xu L., Li Y., Fang T., Wang T., Salerno M., Prato M., Song J.
Journal of Materials Chemistry C, 2020
25.
The Optical Properties of Solids
Tauc J., Scott T.A.
Physics Today, 1967
26.
ZnBr2 mediated transformation from nonluminescent Cs4PbBr6 to green-emitting Zn-doped CsPbBr3/Cs4PbBr6 nanocrystals for electroluminescent light-emitting diodes
Sun S., Lu M., Guo J., Zhang F., Lu P., Fu Y., Bai X., Shi Z., Wu Z., Yu W.W., Zhang Y.
Chemical Engineering Journal, 2022
29.
Synthesis, Structures, and Optical Properties of Semiconductor Perovskite Nanoparticles CsBX3 (B = Pb, Mn; X = Br, Cl)
Gushchina V.A., Son A.G., Egorova A.A., Arkhipenko A.A., Teplonogova M.A., Efimov N.N., Kozyukhin S.A.
Russian Journal of Inorganic Chemistry, 2024
31.
Nemygina E.M., Udalova N.N., Marchenko E.I., Moskalenko A.K., Goodilin E.A., Tarasov A.B.
Mendeleev Communications, 2024
32.
Solar Cell Efficiency Tables (Version 65)
Green M., Dunlop E., Yoshita M., Kopidakis N., Bothe K., Siefer G., Hao X., Jiang J.
Progress in Photovoltaics: Research and Applications, 2024