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Innovative cyclohexanone synthesis via transfer hydrogenation of phenol and cyclohexanol

Alexey Alexandrovich Philippov 1
Alexey Alexandrovich Philippov
Nikolay Sergeevich Nesterov 1
Nikolay Sergeevich Nesterov
Vera P Pakharukova 1
Vera P Pakharukova
Oleg Nikolaevich Martyanov 1
Oleg Nikolaevich Martyanov
1 G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation
Published 2025-02-18
CommunicationVolume 35, Issue 2, 231-233
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Philippov A. A. et al. Innovative cyclohexanone synthesis via transfer hydrogenation of phenol and cyclohexanol // Mendeleev Communications. 2025. Vol. 35. No. 2. pp. 231-233.
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Philippov A. A., Nesterov N. S., Pakharukova V. P., Martyanov O. N. Innovative cyclohexanone synthesis via transfer hydrogenation of phenol and cyclohexanol // Mendeleev Communications. 2025. Vol. 35. No. 2. pp. 231-233.
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TY - JOUR
DO - 10.71267/mencom.7603
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7603
TI - Innovative cyclohexanone synthesis via transfer hydrogenation of phenol and cyclohexanol
T2 - Mendeleev Communications
AU - Philippov, Alexey Alexandrovich
AU - Nesterov, Nikolay Sergeevich
AU - Pakharukova, Vera P
AU - Martyanov, Oleg Nikolaevich
PY - 2025
DA - 2025/02/18
PB - Mendeleev Communications
SP - 231-233
IS - 2
VL - 35
ER -
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@article{2025_Philippov,
author = {Alexey Alexandrovich Philippov and Nikolay Sergeevich Nesterov and Vera P Pakharukova and Oleg Nikolaevich Martyanov},
title = {Innovative cyclohexanone synthesis via transfer hydrogenation of phenol and cyclohexanol},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7603},
number = {2},
pages = {231--233},
doi = {10.71267/mencom.7603}
}
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Philippov, Alexey Alexandrovich, et al. “Innovative cyclohexanone synthesis via transfer hydrogenation of phenol and cyclohexanol.” Mendeleev Communications, vol. 35, no. 2, Feb. 2025, pp. 231-233. https://mendcomm.colab.ws/publications/10.71267/mencom.7603.

Keywords

cyclohexanol
cyclohexanone
Ni catalysts.
phenol
transfer hydrogenation

Abstract

Novel and promising approach for cyclohexanone synthesis via the comproportionation reaction of cyclohexanol and phenol over conventional Raney nickel and Ni/Al2O3 was examined for the first time. Ni/Al2O3 catalyst was prepared by coprecipitation in supercritical CO2.

Funders

Russian Science Foundation
24-23-20044

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