Photosensitizing effect of benzene oxidation intermediates on the action spectra of Bi2WO6/TiO2-N composites

Morozova, Maria E; Lyulyukin, Mikhail Nikolaevich; Selishchev, Dmitry Sergeyevich; Kozlov, Denis Vladimirovich

doi:10.71267/mencom.7601

Home / Publications / Photosensitizing effect of benzene oxidation intermediates on the action spectra of Bi₂WO₆/TiO₂-N composites

Photosensitizing effect of benzene oxidation intermediates on the action spectra of Bi₂WO₆/TiO₂-N composites

Maria E Morozova ^{1, 2}

Maria E Morozova

,

Mikhail Nikolaevich Lyulyukin ^{1, 2}

Mikhail Nikolaevich Lyulyukin

,

Dmitry Sergeyevich Selishchev ^{1, 2}

Dmitry Sergeyevich Selishchev

,

Denis Vladimirovich Kozlov ^{1, 2}

Denis Vladimirovich Kozlov

¹ Novosibirsk State University, 630090 Novosibirsk, Russian Federation

² G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation

10.71267/mencom.7601

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Published 2025-02-18

Communication , Volume 35, Issue 2, 183-186

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Morozova M. E. et al. Photosensitizing effect of benzene oxidation intermediates on the action spectra of Bi2WO6/TiO2-N composites // Mendeleev Communications. 2025. Vol. 35. No. 2. pp. 183-186.

GOST all authors (up to 50) Copy

Morozova M. E., Lyulyukin M. N., Selishchev D. S., Kozlov D. V. Photosensitizing effect of benzene oxidation intermediates on the action spectra of Bi2WO6/TiO2-N composites // Mendeleev Communications. 2025. Vol. 35. No. 2. pp. 183-186.

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TY - JOUR

DO - 10.71267/mencom.7601

UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7601

TI - Photosensitizing effect of benzene oxidation intermediates on the action spectra of Bi2WO6/TiO2-N composites

T2 - Mendeleev Communications

AU - Morozova, Maria E

AU - Lyulyukin, Mikhail Nikolaevich

AU - Selishchev, Dmitry Sergeyevich

AU - Kozlov, Denis Vladimirovich

PY - 2025

DA - 2025/02/18

PB - Mendeleev Communications

SP - 183-186

IS - 2

VL - 35

ER -

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@article{2025_Morozova,

author = {Maria E Morozova and Mikhail Nikolaevich Lyulyukin and Dmitry Sergeyevich Selishchev and Denis Vladimirovich Kozlov},

title = {Photosensitizing effect of benzene oxidation intermediates on the action spectra of Bi2WO6/TiO2-N composites},

journal = {Mendeleev Communications},

year = {2025},

volume = {35},

publisher = {Mendeleev Communications},

month = {Feb},

url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7601},

number = {2},

pages = {183--186},

doi = {10.71267/mencom.7601}

}

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Cite this

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Morozova, Maria E., et al. “Photosensitizing effect of benzene oxidation intermediates on the action spectra of Bi2WO6/TiO2-N composites.” Mendeleev Communications, vol. 35, no. 2, Feb. 2025, pp. 183-186. https://mendcomm.colab.ws/publications/10.71267/mencom.7601.

Keywords

action spectrum

benzene

Bi₂WO₆

composite

cyclohexane

oxidation

TiO₂

Abstract

The dependence of the photonic efficiency on the wavelength, i.e. the action spectrum, was established for the test reactions of benzene and cyclohexane oxidation over the Bi₂WO₆/TiO₂-N composites and individual components. It was found that the action spectrum curve for cyclohexane oxidation reproduces the light absorption curve, while that for benzene oxidation indicates some additional activity in the range of 400--550 nm. It was concluded that the intermediate products of benzene oxidation on the catalyst surface exert a photosensitization effect, which significantly increases the photoactivity of Bi₂WO₆/TiO₂-N composites in the visible range.

Funders

Russian Science Foundation

23-23-00505

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