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Selective hydrogenation of nitrobenzene to aniline over LaNiO3

Olga P. Tkachenko 1
Olga P. Tkachenko
, 
Elena Vladimirovna Shuvalova 1
Elena Vladimirovna Shuvalova
, 
Petr Vital'evich Zemlianskii 1
Petr Vital'evich Zemlianskii
,  , 
Leonid Modestovich Kustov 1, 2
Leonid Modestovich Kustov
10.71267/mencom.7599
Published 2025-02-18
Communication , Volume 35, Issue 2, 228-230
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Tkachenko O. P. et al. Selective hydrogenation of nitrobenzene to aniline over LaNiO3 // Mendeleev Communications. 2025. Vol. 35. No. 2. pp. 228-230.
GOST all authors (up to 50) Copy
Tkachenko O. P., Shuvalova E. V., Zemlianskii P. V., Davshan N. A., Kustov L. M. Selective hydrogenation of nitrobenzene to aniline over LaNiO3 // Mendeleev Communications. 2025. Vol. 35. No. 2. pp. 228-230.
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TY - JOUR
DO - 10.71267/mencom.7599
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7599
TI - Selective hydrogenation of nitrobenzene to aniline over LaNiO3
T2 - Mendeleev Communications
AU - Tkachenko, Olga P.
AU - Shuvalova, Elena Vladimirovna
AU - Zemlianskii, Petr Vital'evich
AU - Davshan, Nikolay Alekseevich
AU - Kustov, Leonid Modestovich
PY - 2025
DA - 2025/02/18
PB - Mendeleev Communications
SP - 228-230
IS - 2
VL - 35
ER -
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@article{2025_Tkachenko,
author = {Olga P. Tkachenko and Elena Vladimirovna Shuvalova and Petr Vital'evich Zemlianskii and Nikolay Alekseevich Davshan and Leonid Modestovich Kustov},
title = {Selective hydrogenation of nitrobenzene to aniline over LaNiO3},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7599},
number = {2},
pages = {228--230},
doi = {10.71267/mencom.7599}
}
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Tkachenko, Olga P., et al. “Selective hydrogenation of nitrobenzene to aniline over LaNiO3.” Mendeleev Communications, vol. 35, no. 2, Feb. 2025, pp. 228-230. https://mendcomm.colab.ws/publications/10.71267/mencom.7599.

Keywords

aniline
hydrogenation
LaNiO3
nitrobenzene
SEM-EDS.
XPS
XRD

Abstract

Perovskite LaNiO3 prepared by the glycine-nitrate method was studied by XPS, XRD and SEM-EDS. This substance was tested as the catalyst in the hydrogenation of nitrobenzene to aniline in ethanol (150 °C, 1.5 MPa H2). The selectivity for aniline was 95.6% with a conversion of 98.7%. According to XPS data, La and Ni do not change their electronic state in the course of the reaction.

Funders

Ministry of Education and Science of the Russian Federation
075-15-2023-585

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