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Synthetic protocol for the preparation of new ([2,2':6',2''-terpyridin]-4'-yl)naphthalene derivatives

Evgenii Nikolaevich Shepelenko 1
Evgenii Nikolaevich Shepelenko
, 
Vitalii Alekseevich Podshibyakin 2
Vitalii Alekseevich Podshibyakin
,  , 
Konstantin E Shepelenko 4
Konstantin E Shepelenko
, 
Viktor Mikhailovich Chernyshev 4
Viktor Mikhailovich Chernyshev
1 Southern Scientific Center of the Russian Academy of Sciences, 344006 Rostov-on-Don, Russian Federation
3 North-Caucasus Federal University, 355017 Stavropol, Russian Federation
4 Platov South-Russian State Polytechnic University, 346428 Novocherkassk, Russian Federation
10.71267/mencom.7579
Published 2025-01-24
Communication , Volume 35, Issue 1, 96-98
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Shepelenko E. N. et al. Synthetic protocol for the preparation of new ([2,2':6',2''-terpyridin]-4'-yl)naphthalene derivatives // Mendeleev Communications. 2025. Vol. 35. No. 1. pp. 96-98.
GOST all authors (up to 50) Copy
Shepelenko E. N., Podshibyakin V. A., Demidov O. P., Shepelenko K. E., Chernyshev V. M. Synthetic protocol for the preparation of new ([2,2':6',2''-terpyridin]-4'-yl)naphthalene derivatives // Mendeleev Communications. 2025. Vol. 35. No. 1. pp. 96-98.
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TY - JOUR
DO - 10.71267/mencom.7579
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7579
TI - Synthetic protocol for the preparation of new ([2,2':6',2''-terpyridin]-4'-yl)naphthalene derivatives
T2 - Mendeleev Communications
AU - Shepelenko, Evgenii Nikolaevich
AU - Podshibyakin, Vitalii Alekseevich
AU - Demidov, Oleg Petrovich
AU - Shepelenko, Konstantin E
AU - Chernyshev, Viktor Mikhailovich
PY - 2025
DA - 2025/01/24
PB - Mendeleev Communications
SP - 96-98
IS - 1
VL - 35
ER -
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@article{2025_Shepelenko,
author = {Evgenii Nikolaevich Shepelenko and Vitalii Alekseevich Podshibyakin and Oleg Petrovich Demidov and Konstantin E Shepelenko and Viktor Mikhailovich Chernyshev},
title = {Synthetic protocol for the preparation of new ([2,2':6',2''-terpyridin]-4'-yl)naphthalene derivatives},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7579},
number = {1},
pages = {96--98},
doi = {10.71267/mencom.7579}
}
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Shepelenko, Evgenii Nikolaevich, et al. “Synthetic protocol for the preparation of new ([2,2':6',2''-terpyridin]-4'-yl)naphthalene derivatives.” Mendeleev Communications, vol. 35, no. 1, Jan. 2025, pp. 96-98. https://mendcomm.colab.ws/publications/10.71267/mencom.7579.

Keywords

2
2':6'
2''-terpyridine
formylation
heterocyclic compounds
ligands
naphthol
terpyridines
X-ray diffraction analysis.

Abstract

An effective synthesis of new functionalized ([2,2':6',2''-terpyridin]-4'-yl)naphthalenes involves demethylation in NaphthOMe group followed by formylation with PhN=CHOEt reagent. The obtained compounds containing aromatic hydroxy and formyl groups can be of interest as ligands for transition metals or as building blocks for the synthesis of polytopic ligands.

Funders

Ministry of Education and Science of the Russian Federation
FENN-2024-0002

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