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Synthesis and luminescent properties of a new manganese complex based on N-substituted bis(diphenylphosphoryl)pyrrolidine

Dmitry S Ionov 2
Dmitry S Ionov
Alexander Dmitrievich Volodin 1
Alexander Dmitrievich Volodin
Alexander Aleksandrovich Korlyukov
Yuriy Nikolaevich Kononevich 1
Yuriy Nikolaevich Kononevich
2 Photochemistry Center, Kurchatov Complex of Crystallography and Photonics, National Research Center 'Kurchatov Institute', 119421 Moscow, Russian Federation
Published 2025-01-24
CommunicationVolume 35, Issue 1, 42-44
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Kim E. E. et al. Synthesis and luminescent properties of a new manganese complex based on N-substituted bis(diphenylphosphoryl)pyrrolidine // Mendeleev Communications. 2025. Vol. 35. No. 1. pp. 42-44.
GOST all authors (up to 50) Copy
Kim E. E., Ionov D. S., Volodin A. D., Korlyukov A. A., Kononevich Y. N., Brel V. K. Synthesis and luminescent properties of a new manganese complex based on N-substituted bis(diphenylphosphoryl)pyrrolidine // Mendeleev Communications. 2025. Vol. 35. No. 1. pp. 42-44.
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TY - JOUR
DO - 10.71267/mencom.7577
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7577
TI - Synthesis and luminescent properties of a new manganese complex based on N-substituted bis(diphenylphosphoryl)pyrrolidine
T2 - Mendeleev Communications
AU - Kim, Eleonora E
AU - Ionov, Dmitry S
AU - Volodin, Alexander Dmitrievich
AU - Korlyukov, Alexander Aleksandrovich
AU - Kononevich, Yuriy Nikolaevich
AU - Brel, Valery Kuzmich
PY - 2025
DA - 2025/01/24
PB - Mendeleev Communications
SP - 42-44
IS - 1
VL - 35
ER -
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@article{2025_Kim,
author = {Eleonora E Kim and Dmitry S Ionov and Alexander Dmitrievich Volodin and Alexander Aleksandrovich Korlyukov and Yuriy Nikolaevich Kononevich and Valery Kuzmich Brel},
title = {Synthesis and luminescent properties of a new manganese complex based on N-substituted bis(diphenylphosphoryl)pyrrolidine},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7577},
number = {1},
pages = {42--44},
doi = {10.71267/mencom.7577}
}
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Kim, Eleonora E., et al. “Synthesis and luminescent properties of a new manganese complex based on N-substituted bis(diphenylphosphoryl)pyrrolidine.” Mendeleev Communications, vol. 35, no. 1, Jan. 2025, pp. 42-44. https://mendcomm.colab.ws/publications/10.71267/mencom.7577.

Keywords

luminescence
manganese(II) complexes
NMR spectroscopy
phosphorus-containing ligands
X-ray diffraction analysis

Abstract

A new luminescent MnII complex based on 1-benzyl-3,4-bis(diphenylphosphoryl)pyrrolidine ligand has been synthesized and fully characterized. This complex exhibits intense luminescence in the solid state (λem = 585 nm) with a high quantum yield (60%) as well as luminescence lifetime of 17 ms.

Funders

Russian Science Foundation
20-13-00329

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