Home / Publications / Eluotropic strength of solvents for parallel-displaced π–π interaction chromatography

Eluotropic strength of solvents for parallel-displaced π–π interaction chromatography

Evgeny Vital'evich Upyrenko 1
Evgeny Vital'evich Upyrenko
, 
Dmitriy Andreevich Kurgachev 1
Dmitriy Andreevich Kurgachev
, 
Abdigali Abdimanapovich Bakibaev 1
Abdigali Abdimanapovich Bakibaev
1 Department of Chemistry, National Research Tomsk State University, 634050 Tomsk, Russian Federation
10.71267/mencom.7576
Published 2025-02-18
Communication , Volume 35, Issue 2, 237-239
0
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Upyrenko E. V., Kurgachev D. A., Bakibaev A. A. Eluotropic strength of solvents for parallel-displaced π–π interaction chromatography // Mendeleev Communications. 2025. Vol. 35. No. 2. pp. 237-239.
GOST all authors (up to 50) Copy
Upyrenko E. V., Kurgachev D. A., Bakibaev A. A. Eluotropic strength of solvents for parallel-displaced π–π interaction chromatography // Mendeleev Communications. 2025. Vol. 35. No. 2. pp. 237-239.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.71267/mencom.7576
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7576
TI - Eluotropic strength of solvents for parallel-displaced π–π interaction chromatography
T2 - Mendeleev Communications
AU - Upyrenko, Evgeny Vital'evich
AU - Kurgachev, Dmitriy Andreevich
AU - Bakibaev, Abdigali Abdimanapovich
PY - 2025
DA - 2025/02/18
PB - Mendeleev Communications
SP - 237-239
IS - 2
VL - 35
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2025_Upyrenko,
author = {Evgeny Vital'evich Upyrenko and Dmitriy Andreevich Kurgachev and Abdigali Abdimanapovich Bakibaev},
title = {Eluotropic strength of solvents for parallel-displaced π–π interaction chromatography},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7576},
number = {2},
pages = {237--239},
doi = {10.71267/mencom.7576}
}
MLA
Cite this
MLA Copy
Upyrenko, Evgeny Vital'evich, et al. “Eluotropic strength of solvents for parallel-displaced π–π interaction chromatography.” Mendeleev Communications, vol. 35, no. 2, Feb. 2025, pp. 237-239. https://mendcomm.colab.ws/publications/10.71267/mencom.7576.

Keywords

PYE
pyrenylethyl stationary phase
quasi-normal phase
solvent eluotropic series
π–interactions

Abstract

A solvent eluotropic strength series for liquid chromatography in the parallel-displaced π–π interaction mode was established. Experiments were carried out on a pyrenylethyl group bonded stationary phase with 1,3-initrobenzene as a marker compound and a 40 : 60 isopropanol–n-hexane mixture as the initial mobile phase, in which 1, 3, 5, 10, 15 and 20% were replaced by the solvent under study.

References

.
Investigation of the properties of hypercrosslinked polystyrene as a stationary phase for high-performance liquid chromatography
Penner N.A., Nesterenko P.N., Ilyin M.M., Tsyurupa M.P., Davankov V.A.
Chromatographia, 1999
.
Hypercrosslinked polystyrene as a novel type of high-performance liquid chromatography column packing material
Davankov V.A., Sychov C.S., Ilyin M.M., Sochilina K.O.
Journal of Chromatography A, 2003
.
Interactions with Aromatic Rings in Chemical and Biological Recognition
Meyer E.A., Castellano R.K., Diederich F.
Angewandte Chemie - International Edition, 2003
.
Synthesis and evaluation of a pentafluorobenzamide stationary phase for HPLC separations in the reversed phase and hydrophilic interaction modes
Ferreira C.D., Gama M.R., da Silva G.S., Almeida W.P., Collins C.H., Jardim I.C.
Journal of Separation Science, 2018
.
Quasi-normal phase chromatography of nitrogen-containing adamantane derivatives
Prokopov S.V., Tyrina E.V., Davankov V.A., Il’in M.M., Kurbatova S.V.
Russian Journal of Physical Chemistry A, 2012
.
HPLC Separation of Different Groups of Small Polar Compounds on a Novel Amide-Embedded Stationary Phase
Aral H., Aral T., Çelik K.S., Ziyadanoğulları B., Ziyadanoğulları R.
Chromatographia, 2014
.
Effects of π‐π Interactions on the Separation of PAHs on Phenyl‐Type Stationary Phases
Stevenson P.G., Kayillo S., Dennis G.R., Shalliker R.A.
Journal of Liquid Chromatography and Related Technologies, 2007
.
The Nature and Applications of π–π Interactions: A Perspective
Thakuria R., Nath N.K., Saha B.K.
Crystal Growth and Design, 2019
.
A versatile polar-embedded polyphenyl phase for multimodal separation in liquid chromatography
Zhang Y., Li Q., Dai B., Zhou S., Zhang M., Han H., Qiu H.
Journal of Chromatography A, 2018