Home / Publications / Eight new trifluoromethyl derivatives of [60]fullerene, C60(CF3)16

Eight new trifluoromethyl derivatives of [60]fullerene, C60(CF3)16

2
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Tamm N. B., Troyanov S. I. Eight new trifluoromethyl derivatives of [60]fullerene, C60(CF3)16 // Mendeleev Communications. 2025. Vol. 35. No. 1. pp. 45-46.
GOST all authors (up to 50) Copy
Tamm N. B., Troyanov S. I. Eight new trifluoromethyl derivatives of [60]fullerene, C60(CF3)16 // Mendeleev Communications. 2025. Vol. 35. No. 1. pp. 45-46.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.71267/mencom.7552
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7552
TI - Eight new trifluoromethyl derivatives of [60]fullerene, C60(CF3)16
T2 - Mendeleev Communications
AU - Tamm, Nadezhda Borisovna
AU - Troyanov, Sergey Igorevich
PY - 2025
DA - 2025/01/24
PB - Mendeleev Communications
SP - 45-46
IS - 1
VL - 35
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2025_Tamm,
author = {Nadezhda Borisovna Tamm and Sergey Igorevich Troyanov},
title = {Eight new trifluoromethyl derivatives of [60]fullerene, C60(CF3)16},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7552},
number = {1},
pages = {45--46},
doi = {10.71267/mencom.7552}
}
MLA
Cite this
MLA Copy
Tamm, Nadezhda Borisovna, and Sergey Igorevich Troyanov. “Eight new trifluoromethyl derivatives of [60]fullerene, C60(CF3)16.” Mendeleev Communications, vol. 35, no. 1, Jan. 2025, pp. 45-46. https://mendcomm.colab.ws/publications/10.71267/mencom.7552.

Keywords

fullerene C60
HPLC separation
structure elucidation
synchrotron radiation
trifluoromethylation

Abstract

Eight new C60(CF3)16 isomers have been synthesized by high-temperature trifluoromethylation of [60]fullerene with gaseous CF3I, isolated by HPLC, and structurally characterized by single crystal X-ray diffraction using synchrotron radiation.

Funders

Ministry of Education and Science of the Russian Federation
121031300039-1

References

.
Generalized Gradient Approximation Made Simple
Perdew J.P., Burke K., Ernzerhof M.
Physical Review Letters, 1996
.
Perfluoroalkylfullerenes
Boltalina O.V., Popov A.A., Kuvychko I.V., Shustova N.B., Strauss S.H.
Chemical Reviews, 2015
.
Electrochemical, spectroscopic, and DFT study of C60(CF3)n frontier orbitals (n = 2-18): the link between double bonds in pentagons and reduction potentials.
Popov A.A., Kareev I.E., Shustova N.B., Stukalin E.B., Lebedkin S.F., Seppelt K., Strauss S.H., Boltalina O.V., Dunsch L.
Journal of the American Chemical Society, 2007
.
Thermally Stable Perfluoroalkylfullerenes with the Skew-Pentagonal-Pyramid Pattern:  C60(C2F5)4O, C60(CF3)4O, and C60(CF3)6
Kareev I.E., Shustova N.B., Kuvychko I.V., Lebedkin S.F., Miller S.M., Anderson O.P., Popov A.A., Strauss S.H., Boltalina O.V.
Journal of the American Chemical Society, 2006
.
Tamm N.B., Brotsman V.A., Troyanov S.I.
Mendeleev Communications, 2023
.
Isolation of C60(CF3)n (n = 2, 4, 6, 8, 10) with high compositional purity
Goryunkov A.A., Kuvychko I.V., Ioffe I.N., Dick D.L., Sidorov L.N., Strauss S.H., Boltalina O.V.
Journal of Fluorine Chemistry, 2003
.
Synthesis, Structure, and 19F NMR Spectra of 1,3,7,10,14,17,23,28,31,40-C60(CF3)10
Kareev I.E., Kuvychko I.V., Lebedkin S.F., Miller S.M., Anderson O.P., Seppelt K., Strauss S.H., Boltalina O.V.
Journal of the American Chemical Society, 2005
.
Synthesis and structures of poly(perfluoroethyl)[60]fullerenes: 1,7,16,36,46,49-C60(C2F5)6and 1,6,11,18,24,27,32,35-C60(C2F5)8
Kareev I.E., Kuvychko I.V., Lebedkin S.F., Miller S.M., Anderson O.P., Strauss S.H., Boltalina O.V.
Chemical Communications, 2006
.
1,6,11,18,24,27,52,55-Octakis(trifluoromethyl)-1,6,11,18,24,27,52,55-octahydro(C60-Ih)[5,6]fullerene
Kareev I.E., Shustova N.B., Newell B.S., Miller S.M., Anderson O.P., Strauss S.H., Boltalina O.V.
Acta Crystallographica Section E Structure Reports Online, 2006
.
Synthesis, Structure, and Theoretical Study of Lower Trifluoromethyl Derivatives of [60]Fullerene
Dorozhkin E.I., Goryunkov A.A., Ioffe I.N., Avdoshenko S.M., Markov V.Y., Tamm N.B., Ignat'eva D.V., Sidorov L.N., Troyanov S.I.
European Journal of Organic Chemistry, 2007
.
Structures and structure-related electronic properties of new C60(CF3)10 isomers
Bukovsky E.V., Larson B.W., Clikeman T.T., Chen Y., Popov A.A., Boltalina O.V., Strauss S.H.
Journal of Fluorine Chemistry, 2016
.
Higher trifluoromethylated derivatives of C60, C60(CF3)16 and C60(CF3)18
Troyanov S.I., Goryunkov A.A., Dorozhkin E.I., Ignat’eva D.V., Tamm N.B., Avdoshenko S.M., Ioffe I.N., Markov V.Y., Sidorov L.N., Scheurel K., Kemnitz E.
Journal of Fluorine Chemistry, 2007