Home / Publications / Effect of methanol on the kinetics of methane-to-CO2 exchange in gas hydrates

Effect of methanol on the kinetics of methane-to-CO2 exchange in gas hydrates

Dmitry Anatol'evich Strukov 1
Dmitry Anatol'evich Strukov
Sergey Aleksandrovich Kartopol'cev 1
Sergey Aleksandrovich Kartopol'cev
Andrei Yur'evich Manakov 1, 2
Andrei Yur'evich Manakov
Sergey Sergeevich Skiba 1, 3
Sergey Sergeevich Skiba
2 Institute of Geology and Petroleum Technologies, Kazan Federal University, 420008 Kazan, Russian Federation
3 RN-KrasnoyarskNIPINeft LLC, 660098 Krasnoyarsk, Russian Federation
Published 2025-01-24
CommunicationVolume 35, Issue 1, 86-89
0
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Strukov D. A. et al. Effect of methanol on the kinetics of methane-to-CO2 exchange in gas hydrates // Mendeleev Communications. 2025. Vol. 35. No. 1. pp. 86-89.
GOST all authors (up to 50) Copy
Strukov D. A., Kartopol'cev S. A., Manakov A. Y., Skiba S. S. Effect of methanol on the kinetics of methane-to-CO2 exchange in gas hydrates // Mendeleev Communications. 2025. Vol. 35. No. 1. pp. 86-89.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.71267/mencom.7521
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7521
TI - Effect of methanol on the kinetics of methane-to-CO2 exchange in gas hydrates
T2 - Mendeleev Communications
AU - Strukov, Dmitry Anatol'evich
AU - Kartopol'cev, Sergey Aleksandrovich
AU - Manakov, Andrei Yur'evich
AU - Skiba, Sergey Sergeevich
PY - 2025
DA - 2025/01/24
PB - Mendeleev Communications
SP - 86-89
IS - 1
VL - 35
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2025_Strukov,
author = {Dmitry Anatol'evich Strukov and Sergey Aleksandrovich Kartopol'cev and Andrei Yur'evich Manakov and Sergey Sergeevich Skiba},
title = {Effect of methanol on the kinetics of methane-to-CO2 exchange in gas hydrates},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7521},
number = {1},
pages = {86--89},
doi = {10.71267/mencom.7521}
}
MLA
Cite this
MLA Copy
Strukov, Dmitry Anatol'evich, et al. “Effect of methanol on the kinetics of methane-to-CO2 exchange in gas hydrates.” Mendeleev Communications, vol. 35, no. 1, Jan. 2025, pp. 86-89. https://mendcomm.colab.ws/publications/10.71267/mencom.7521.

Keywords

carbon dioxide
catalyst
gas hydrate
methane
methanol.
swapping

Abstract

The effect of methanol on the kinetics of CH4/CO2 exchange in gas hydrate below the ice melting point was studied. It was shown that in the presence of 2.5 wt% of methanol at P = 2.25 MPa and T = 263 K the molar fraction of CH4 replaced with CO2 increased more than three times.

Funders

Russian Science Foundation
23-29-00488

References

.
Adamova T.P., Strukov D.A., Yu. Manakov A., Nesterov A.N.
Mendeleev Communications, 2022
.
Clathrate Hydrates of Natural Gases
Sloan Jr. E.D., Koh C.A., Koh C.A.
2007
.
Influence of N2 on Formation Conditions and Guest Distribution of Mixed CO2 + CH4 Gas Hydrates
Belosludov V., Bozhko Y., Subbotin O., Belosludov R., Zhdanov R., Gets K., Kawazoe Y.
Molecules, 2018
.
Enhanced CH4-CO2 Hydrate Swapping in the Presence of Low Dosage Methanol
Pandey J.S., Karantonidis C., Karcz A.P., von Solms N.
Energies, 2020
.
Fluid Composition and Kinetics of the in Situ Replacement in CH4–CO2 Hydrate System
Falenty A., Qin J., Salamatin A.N., Yang L., Kuhs W.F.
Journal of Physical Chemistry C, 2016
.
Multiscale Analysis on CH4–CO2 Swapping Phenomenon Occurred in Hydrates
Zhou X., Lin F., Liang D.
Journal of Physical Chemistry C, 2016
.
Progress in Global Gas Hydrate Development and Production as a New Energy Resource
LIU L., SUN Z., ZHANG L., WU N., Yichao Q., JIANG Z., GENG W., CAO H., ZHANG X., ZHAI B., XU C., SHEN Z., JIA Y.
Acta Geologica Sinica, 2019
.
Gas hydrates-geological perspective and global change
Kvenvolden K.A.
Reviews of Geophysics, 2004
.
Properties and phenomena relevant to CH4-CO2replacement in hydrate-bearing sediments
Jung J.W., Espinoza D.N., Santamarina J.C.
Journal of Geophysical Research, 2010
.
Ohgaki K., Takano K., Sangawa H., Matsubara T., Nakano S.
Journal of Chemical Engineering of Japan, 2005
.
Natural gas hydrates – A promising source of energy
Makogon Y.F.
Journal of Natural Gas Science and Engineering, 2010
.
Production behavior and numerical analysis for 2017 methane hydrate extraction test of Shenhu, South China Sea
Chen L., Feng Y., Okajima J., Komiya A., Maruyama S.
Journal of Natural Gas Science and Engineering, 2018
.
Moridis G.J., Collett T.S., Boswell R., Hancock S., Rutqvist J., Santamarina C., Kneafsey T., Reagan M.T., Pooladi-Darvish M., Kowalsky M., Sloan E.D., Coh C.
2012
.
Investigation into gas production from natural gas hydrate: A review
Li X., Xu C., Zhang Y., Ruan X., Li G., Wang Y.
Applied Energy, 2016
.
Gas hydrate equilibria for CO2–N2 and CO2–CH4 gas mixtures—Experimental studies and thermodynamic modelling
Herri J.-., Bouchemoua A., Kwaterski M., Fezoua A., Ouabbas Y., Cameirao A.
Fluid Phase Equilibria, 2011
.
Methane recovery from methane hydrate using pressurized CO2
Ota M., Abe Y., Watanabe M., Smith R.L., Inomata H.
Fluid Phase Equilibria, 2005
.
Replacement of CH4 in the hydrate by use of liquid CO2
Ota M., Morohashi K., Abe Y., Watanabe M., Smith, Jr. R.L., Inomata H.
Energy Conversion and Management, 2005
.
Replacement in CH4-CO2 hydrate below freezing point based on abnormal self-preservation differences of CH4 hydrate
Xie Y., Zhu Y., Zheng T., Yuan Q., Sun C., Yang L., Chen G.
Chemical Engineering Journal, 2021
.
Gas hydrate accumulation in deep-water marine sediments
Ginsburg G.D.
Geological Society Special Publication, 2007
.
Insights into the structure of mixed CO2/CH4in gas hydrates
Everett S.M., Rawn C.J., Chakoumakos B.C., Keffer D.J., Huq A., Phelps T.J.
American Mineralogist, 2015
.
Laboratory demonstration of the stability of CO2 hydrates in deep-oceanic sediments
Fahed Qureshi M., Zheng J., Khandelwal H., Venkataraman P., Usadi A., Barckholtz T.A., Mhadeshwar A.B., Linga P.
Chemical Engineering Journal, 2022
.
CO2 hydrate stability in oceanic sediments under brine conditions
Qureshi M.F., Khandelwal H., Usadi A., Barckholtz T.A., Mhadeshwar A.B., Linga P.
Energy, 2022
.
Insights into CO2-CH4 hydrate exchange in porous media using magnetic resonance
Li M., Rojas Zuniga A., Stanwix P.L., Aman Z.M., May E.F., Johns M.L.
Fuel, 2022
.
Achieving effective and simultaneous consolidation breaking and sand removal in solid fluidization development of natural gas hydrate
Xiaoxu D., Jiwei W., Yuan H., Haitao L., Shouwei Z., Junlong Z., Shaohua N., Guorong W., Liang M., Hualin W.
Applied Energy, 2023
.
From catalyst development to reactor Design: A comprehensive review of methanol synthesis techniques
Ebrahimzadeh Sarvestani M., Norouzi O., Di Maria F., Dutta A.
Energy Conversion and Management, 2024
.
Study of the kinetics of methane-carbon dioxide exchange in gas hydrates below the ice melting point. Experimental data and computational model.
Strukov D.A., Kartopol'cev S.A., Sagidullin A.K., Smirnov V.G., Manakov A.Y., Skiba S.S.
Thermochimica Acta, 2024
.
CO2 Gas Hydrate for Carbon Capture and Storage Applications – Part 1
Aminnaji M., Qureshi M.F., Dashti H., Hase A., Mosalanejad A., Jahanbakhsh A., Babaei M., Amiri A., Maroto-Valer M.
Energy, 2024
.
CO2 Gas Hydrate for Carbon Capture and Storage Applications – Part 2
Aminnaji M., Qureshi M.F., Dashti H., Hase A., Mosalanejad A., Jahanbakhsh A., Babaei M., Amiri A., Maroto-Valer M.
Energy, 2024