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Unusual binuclear alkoxomolybdenum(V) complex free of oxo groups: synthesis, structure and IR spectra

Nadezhda Vladimirovna Bardina 1
Nadezhda Vladimirovna Bardina
, 
Tamara Aleksandrovna Bazhenova 1
Tamara Aleksandrovna Bazhenova
, 
Konstantin Alexandrovich Lyssenko 2
Konstantin Alexandrovich Lyssenko
, 
Mikhail Yuvenal'evich Antipin 2
Mikhail Yuvenal'evich Antipin
,  , 
Tatyana Aleksandrovna Savinykh 1
Tatyana Aleksandrovna Savinykh
, 
Alexander Fedorovich Shestakov 1
Alexander Fedorovich Shestakov
10.1070/MC2006v016n06ABEH002426
Published 2006-12-06
Communication , Volume 16, Issue 6, 307-308
12
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Bardina N. V. et al. Unusual binuclear alkoxomolybdenum(V) complex free of oxo groups: synthesis, structure and IR spectra // Mendeleev Communications. 2006. Vol. 16. No. 6. pp. 307-308.
GOST all authors (up to 50) Copy
Bardina N. V., Bazhenova T. A., Lyssenko K. A., Antipin M. Y., Shulga Y. M., Savinykh T. A., Shestakov A. F. Unusual binuclear alkoxomolybdenum(V) complex free of oxo groups: synthesis, structure and IR spectra // Mendeleev Communications. 2006. Vol. 16. No. 6. pp. 307-308.
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TY - JOUR
DO - 10.1070/MC2006v016n06ABEH002426
UR - https://mendcomm.colab.ws/publications/10.1070/MC2006v016n06ABEH002426
TI - Unusual binuclear alkoxomolybdenum(V) complex free of oxo groups: synthesis, structure and IR spectra
T2 - Mendeleev Communications
AU - Bardina, Nadezhda Vladimirovna
AU - Bazhenova, Tamara Aleksandrovna
AU - Lyssenko, Konstantin Alexandrovich
AU - Antipin, Mikhail Yuvenal'evich
AU - Shulga, Yurii Makarovich
AU - Savinykh, Tatyana Aleksandrovna
AU - Shestakov, Alexander Fedorovich
PY - 2006
DA - 2006/12/06
PB - Mendeleev Communications
SP - 307-308
IS - 6
VL - 16
ER -
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@article{2006_Bardina,
author = {Nadezhda Vladimirovna Bardina and Tamara Aleksandrovna Bazhenova and Konstantin Alexandrovich Lyssenko and Mikhail Yuvenal'evich Antipin and Yurii Makarovich Shulga and Tatyana Aleksandrovna Savinykh and Alexander Fedorovich Shestakov},
title = {Unusual binuclear alkoxomolybdenum(V) complex free of oxo groups: synthesis, structure and IR spectra},
journal = {Mendeleev Communications},
year = {2006},
volume = {16},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2006v016n06ABEH002426},
number = {6},
pages = {307--308},
doi = {10.1070/MC2006v016n06ABEH002426}
}
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Bardina, Nadezhda Vladimirovna, et al. “Unusual binuclear alkoxomolybdenum(V) complex free of oxo groups: synthesis, structure and IR spectra.” Mendeleev Communications, vol. 16, no. 6, Dec. 2006, pp. 307-308. https://mendcomm.colab.ws/publications/10.1070/MC2006v016n06ABEH002426.

Abstract

The interaction of MoCl5 with NaOMe in methanol led to the formation of a new neutral binuclear molybdenum(V) alkoxo complex with Cl ligands, trans-[Cl(OMe)3Mo(μ-OMe)2Mo(OMe)3Cl]; the complex was characterised by X-ray analysis, IR spectroscopy and DFT quantum-chemical calculations.

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