Home / Publications / A new approach to the synthesis of phosphoranes based on the reaction of benzo[d]-1,3,2-dioxaphospholes having a β- or γ-carbonyl group in exocyclic substituent with hexafluoroacetone

A new approach to the synthesis of phosphoranes based on the reaction of benzo[d]-1,3,2-dioxaphospholes having a β- or γ-carbonyl group in exocyclic substituent with hexafluoroacetone

Liliya Misbakhovna Abdrakhmanova 1
Liliya Misbakhovna Abdrakhmanova
,  , 
Tamara Aleksandrovna Baronova 1
Tamara Aleksandrovna Baronova
, 
Mudaris Nurgaleevich Dimukhametov 1
Mudaris Nurgaleevich Dimukhametov
, 
Dmitry Borisovich Krivolapov 1
Dmitry Borisovich Krivolapov
, 
Igor Anatol'evich Litvinov 1
Igor Anatol'evich Litvinov
, 
Alsu Azatovna Balandina 1
Alsu Azatovna Balandina
, 
Shamil Kamil'evich Latypov 1
Shamil Kamil'evich Latypov
, 
Aleksandr Ivanovich Konovalov 1
Aleksandr Ivanovich Konovalov
10.1070/MC2006v016n06ABEH002414
Published 2006-12-06
Communication , Volume 16, Issue 6, 320-323
19
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Abdrakhmanova L. M. et al. A new approach to the synthesis of phosphoranes based on the reaction of benzo[d]-1,3,2-dioxaphospholes having a β- or γ-carbonyl group in exocyclic substituent with hexafluoroacetone // Mendeleev Communications. 2006. Vol. 16. No. 6. pp. 320-323.
GOST all authors (up to 50) Copy
Abdrakhmanova L. M., Mironov V. F., Baronova T. A., Dimukhametov M. N., Krivolapov D. B., Litvinov I. A., Balandina A. A., Latypov S. K., Konovalov A. I. A new approach to the synthesis of phosphoranes based on the reaction of benzo[d]-1,3,2-dioxaphospholes having a β- or γ-carbonyl group in exocyclic substituent with hexafluoroacetone // Mendeleev Communications. 2006. Vol. 16. No. 6. pp. 320-323.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC2006v016n06ABEH002414
UR - https://mendcomm.colab.ws/publications/10.1070/MC2006v016n06ABEH002414
TI - A new approach to the synthesis of phosphoranes based on the reaction of benzo[d]-1,3,2-dioxaphospholes having a β- or γ-carbonyl group in exocyclic substituent with hexafluoroacetone
T2 - Mendeleev Communications
AU - Abdrakhmanova, Liliya Misbakhovna
AU - Mironov, Vladimir Fedorovich
AU - Baronova, Tamara Aleksandrovna
AU - Dimukhametov, Mudaris Nurgaleevich
AU - Krivolapov, Dmitry Borisovich
AU - Litvinov, Igor Anatol'evich
AU - Balandina, Alsu Azatovna
AU - Latypov, Shamil Kamil'evich
AU - Konovalov, Aleksandr Ivanovich
PY - 2006
DA - 2006/12/06
PB - Mendeleev Communications
SP - 320-323
IS - 6
VL - 16
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2006_Abdrakhmanova,
author = {Liliya Misbakhovna Abdrakhmanova and Vladimir Fedorovich Mironov and Tamara Aleksandrovna Baronova and Mudaris Nurgaleevich Dimukhametov and Dmitry Borisovich Krivolapov and Igor Anatol'evich Litvinov and Alsu Azatovna Balandina and Shamil Kamil'evich Latypov and Aleksandr Ivanovich Konovalov},
title = {A new approach to the synthesis of phosphoranes based on the reaction of benzo[d]-1,3,2-dioxaphospholes having a β- or γ-carbonyl group in exocyclic substituent with hexafluoroacetone},
journal = {Mendeleev Communications},
year = {2006},
volume = {16},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2006v016n06ABEH002414},
number = {6},
pages = {320--323},
doi = {10.1070/MC2006v016n06ABEH002414}
}
MLA
Cite this
MLA Copy
Abdrakhmanova, Liliya Misbakhovna, et al. “A new approach to the synthesis of phosphoranes based on the reaction of benzo[d]-1,3,2-dioxaphospholes having a β- or γ-carbonyl group in exocyclic substituent with hexafluoroacetone.” Mendeleev Communications, vol. 16, no. 6, Dec. 2006, pp. 320-323. https://mendcomm.colab.ws/publications/10.1070/MC2006v016n06ABEH002414.

Abstract

The reaction of 2-(2-oxo-1,2-diphenylethoxy)- and 2-(1-methyl-3-oxobut-2-en-1-yloxy)benzo[d]-1,3,2-dioxaphospholes with hexafluoroacetone is a versatile approach to the synthesis of 6,6-bis(trifluoromethyl)-3,4-diphenyl-1,1-phenylenedioxy- 1-phospha-2,5,7-trioxabicyclo[2.2.1]heptane and 3,5-dimethyl-7,7-bis(trifluoromethyl)-1,1-phenylenedioxy-1-phospha-2,6,8-trioxabicyclo[2.2.1]oct-3-ene, respectively, in high yields

References

2.
New Features in Pentacoordinate Phosphorus Chemistry
Kumara Swamy K.C., Satish Kumar N.
Accounts of Chemical Research, 2006
4.
10.1070/MC2006v016n06ABEH002414_bib4
Mironov
Zh. Obshch. Khim., 2006
5.
10.1070/MC2006v016n06ABEH002414_bib5_1
Croasmun
Two-Dimensional NMR Spectroscopy, 1987
6.
10.1070/MC2006v016n06ABEH002414_bib5_2
Derome
Modern NMR Techniques for Chemistry Research, 1988
7.
10.1070/MC2006v016n06ABEH002414_bib5_3
Atta-ur-Rahman
One and Two Dimensional NMR Spectroscopy, 1989
8.
Ab initio calculations of the NMR chemical shift
de Dios A.C.
Progress in Nuclear Magnetic Resonance Spectroscopy, 1996
10.
Comparison of different theory models and basis sets in the calculation of13C NMR chemical shifts of natural products
Cimino P., Gomez-Paloma L., Duca D., Riccio R., Bifulco G.
Magnetic Resonance in Chemistry, 2004
12.
Structure-NMR chemical shift relationships for novel functionalized derivatives of quinoxalines
Balandina A., Kalinin A., Mamedov V., Figadère B., Latypov S.
Magnetic Resonance in Chemistry, 2005
13.
10.1070/MC2006v016n06ABEH002414_bib6_6
Mironov
Izv. Akad. Nauk, Ser. Khim., 2004
14.
10.1070/MC2006v016n06ABEH002414_bib6_7
Mironov
Arkivoc, 2004
15.
E-map improvement in direct procedures
Altomare A., Cascarano G., Giacovazzo C., Viterbo D.
Acta Crystallographica Section A Foundations of Crystallography, 1991
16.
10.1070/MC2006v016n06ABEH002414_bib8
Sheldrick
SHELXL97. A Computer Program for Crystal Structure Determination, 1997
17.
WinGXsuite for small-molecule single-crystal crystallography
Farrugia L.J.
Journal of Applied Crystallography, 1999
18.
L. H. Straver and A. J. Schierbeek. MOLEN. Structure Determination System, Nonius B.V. Delft, Netherlands, 1994, vols. 1, 2.
19.
Structure of dioxo[2‐(salicylidenamino)phenolato(2‐)‐O,N,O'][tris(dimethylamino)phosphine oxide]tungsten(VI)
Spek A.L., Terheijden J., Kraaykamp J.G., Timmer K.
Acta Crystallographica Section C Crystal Structure Communications, 1990