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Rearrangement of carbocations derived from 1,8-bis(dimethylamino)naphthyl-2-methanols into 4-R-1,1,3-trimethyl-2,3-dihydroperimidinium salts

Oksana Vladimirovna Ryabtsova 1
Oksana Vladimirovna Ryabtsova
, 
Alexander Fedorovich Pozharskii 1
Alexander Fedorovich Pozharskii
, 
Alexander Vasil'evich Degtyarev 1
Alexander Vasil'evich Degtyarev
, 
Valery Anatol'evich Ozeryanskii 1
Valery Anatol'evich Ozeryanskii
10.1070/MC2006v016n06ABEH002399
Published 2006-12-06
Communication , Volume 16, Issue 6, 313-316
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Ryabtsova O. V. et al. Rearrangement of carbocations derived from 1,8-bis(dimethylamino)naphthyl-2-methanols into 4-R-1,1,3-trimethyl-2,3-dihydroperimidinium salts // Mendeleev Communications. 2006. Vol. 16. No. 6. pp. 313-316.
GOST all authors (up to 50) Copy
Ryabtsova O. V., Pozharskii A. F., Degtyarev A. V., Ozeryanskii V. A. Rearrangement of carbocations derived from 1,8-bis(dimethylamino)naphthyl-2-methanols into 4-R-1,1,3-trimethyl-2,3-dihydroperimidinium salts // Mendeleev Communications. 2006. Vol. 16. No. 6. pp. 313-316.
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TY - JOUR
DO - 10.1070/MC2006v016n06ABEH002399
UR - https://mendcomm.colab.ws/publications/10.1070/MC2006v016n06ABEH002399
TI - Rearrangement of carbocations derived from 1,8-bis(dimethylamino)naphthyl-2-methanols into 4-R-1,1,3-trimethyl-2,3-dihydroperimidinium salts
T2 - Mendeleev Communications
AU - Ryabtsova, Oksana Vladimirovna
AU - Pozharskii, Alexander Fedorovich
AU - Degtyarev, Alexander Vasil'evich
AU - Ozeryanskii, Valery Anatol'evich
PY - 2006
DA - 2006/12/06
PB - Mendeleev Communications
SP - 313-316
IS - 6
VL - 16
ER -
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@article{2006_Ryabtsova,
author = {Oksana Vladimirovna Ryabtsova and Alexander Fedorovich Pozharskii and Alexander Vasil'evich Degtyarev and Valery Anatol'evich Ozeryanskii},
title = {Rearrangement of carbocations derived from 1,8-bis(dimethylamino)naphthyl-2-methanols into 4-R-1,1,3-trimethyl-2,3-dihydroperimidinium salts},
journal = {Mendeleev Communications},
year = {2006},
volume = {16},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2006v016n06ABEH002399},
number = {6},
pages = {313--316},
doi = {10.1070/MC2006v016n06ABEH002399}
}
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Ryabtsova, Oksana Vladimirovna, et al. “Rearrangement of carbocations derived from 1,8-bis(dimethylamino)naphthyl-2-methanols into 4-R-1,1,3-trimethyl-2,3-dihydroperimidinium salts.” Mendeleev Communications, vol. 16, no. 6, Dec. 2006, pp. 313-316. https://mendcomm.colab.ws/publications/10.1070/MC2006v016n06ABEH002399.

Abstract

α-Phenylated 1,8-bis(dimethylamino)-2-naphthylmethyl carbocations have been shown to rearrange into 4-R-1,1,3-trimethyl-2,3-dihydroperimidinium cations through an intramolecular hydride shift from the 1-NMe2 group.

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