Home / Publications / Protonation of sodium 1,2-diphospha-3,4,5-triphenylcyclopentadienide: the first example of [2 + 2] cycloaddition reaction for phosphacyclopentadiene

Protonation of sodium 1,2-diphospha-3,4,5-triphenylcyclopentadienide: the first example of [2 + 2] cycloaddition reaction for phosphacyclopentadiene

Vasily Anatol'evich Miluykov 1
Vasily Anatol'evich Miluykov
, 
Alexander Vladimirovich Kataev 1
Alexander Vladimirovich Kataev
,  , 
Peter Lönnecke 2
Peter Lönnecke
, 
Evamarie Hey-Hawkins 2
Evamarie Hey-Hawkins
10.1070/MC2006v016n04ABEH002365
Published 2006-09-01
Communication , Volume 16, Issue 4, 204-206
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Miluykov V. A. et al. Protonation of sodium 1,2-diphospha-3,4,5-triphenylcyclopentadienide: the first example of [2 + 2] cycloaddition reaction for phosphacyclopentadiene // Mendeleev Communications. 2006. Vol. 16. No. 4. pp. 204-206.
GOST all authors (up to 50) Copy
Miluykov V. A., Kataev A. V., Sinyashin O. G., Lönnecke P., Hey-Hawkins E. Protonation of sodium 1,2-diphospha-3,4,5-triphenylcyclopentadienide: the first example of [2 + 2] cycloaddition reaction for phosphacyclopentadiene // Mendeleev Communications. 2006. Vol. 16. No. 4. pp. 204-206.
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TY - JOUR
DO - 10.1070/MC2006v016n04ABEH002365
UR - https://mendcomm.colab.ws/publications/10.1070/MC2006v016n04ABEH002365
TI - Protonation of sodium 1,2-diphospha-3,4,5-triphenylcyclopentadienide: the first example of [2 + 2] cycloaddition reaction for phosphacyclopentadiene
T2 - Mendeleev Communications
AU - Miluykov, Vasily Anatol'evich
AU - Kataev, Alexander Vladimirovich
AU - Sinyashin, Oleg Gerol'dovich
AU - Lönnecke, Peter
AU - Hey-Hawkins, Evamarie
PY - 2006
DA - 2006/09/01
PB - Mendeleev Communications
SP - 204-206
IS - 4
VL - 16
ER -
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@article{2006_Miluykov,
author = {Vasily Anatol'evich Miluykov and Alexander Vladimirovich Kataev and Oleg Gerol'dovich Sinyashin and Peter Lönnecke and Evamarie Hey-Hawkins},
title = {Protonation of sodium 1,2-diphospha-3,4,5-triphenylcyclopentadienide: the first example of [2 + 2] cycloaddition reaction for phosphacyclopentadiene},
journal = {Mendeleev Communications},
year = {2006},
volume = {16},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2006v016n04ABEH002365},
number = {4},
pages = {204--206},
doi = {10.1070/MC2006v016n04ABEH002365}
}
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Miluykov, Vasily Anatol'evich, et al. “Protonation of sodium 1,2-diphospha-3,4,5-triphenylcyclopentadienide: the first example of [2 + 2] cycloaddition reaction for phosphacyclopentadiene.” Mendeleev Communications, vol. 16, no. 4, Sep. 2006, pp. 204-206. https://mendcomm.colab.ws/publications/10.1070/MC2006v016n04ABEH002365.

Abstract

Protonation of sodium 1,2-diphospha-3,4,5-triphenylcyclopentadienide occurs with a [1,5]-proton shift and leads to rac-trans-1,2,6,7-tetraphosphatricyclo[5.3.0.02,6]-3,9-decadiene, the product of an unusual [2 + 2] cycloaddition reaction

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