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Acid-catalysed degradation of the organomercury intermediates of pentafluorophenylmercury bromide reduction near a mercury electrode

Vladimir Alexandrovich Kurmaz 1
Vladimir Alexandrovich Kurmaz
, 
Alexander Borisovich Ershler 2
Alexander Borisovich Ershler
10.1070/MC2006v016n04ABEH002259
Published 2006-09-01
Communication , Volume 16, Issue 4, 234-237
4
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Kurmaz V. A., Ershler A. B. Acid-catalysed degradation of the organomercury intermediates of pentafluorophenylmercury bromide reduction near a mercury electrode // Mendeleev Communications. 2006. Vol. 16. No. 4. pp. 234-237.
GOST all authors (up to 50) Copy
Kurmaz V. A., Ershler A. B. Acid-catalysed degradation of the organomercury intermediates of pentafluorophenylmercury bromide reduction near a mercury electrode // Mendeleev Communications. 2006. Vol. 16. No. 4. pp. 234-237.
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TY - JOUR
DO - 10.1070/MC2006v016n04ABEH002259
UR - https://mendcomm.colab.ws/publications/10.1070/MC2006v016n04ABEH002259
TI - Acid-catalysed degradation of the organomercury intermediates of pentafluorophenylmercury bromide reduction near a mercury electrode
T2 - Mendeleev Communications
AU - Kurmaz, Vladimir Alexandrovich
AU - Ershler, Alexander Borisovich
PY - 2006
DA - 2006/09/01
PB - Mendeleev Communications
SP - 234-237
IS - 4
VL - 16
ER -
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@article{2006_Kurmaz,
author = {Vladimir Alexandrovich Kurmaz and Alexander Borisovich Ershler},
title = {Acid-catalysed degradation of the organomercury intermediates of pentafluorophenylmercury bromide reduction near a mercury electrode},
journal = {Mendeleev Communications},
year = {2006},
volume = {16},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2006v016n04ABEH002259},
number = {4},
pages = {234--237},
doi = {10.1070/MC2006v016n04ABEH002259}
}
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Kurmaz, Vladimir Alexandrovich, and Alexander Borisovich Ershler. “Acid-catalysed degradation of the organomercury intermediates of pentafluorophenylmercury bromide reduction near a mercury electrode.” Mendeleev Communications, vol. 16, no. 4, Sep. 2006, pp. 234-237. https://mendcomm.colab.ws/publications/10.1070/MC2006v016n04ABEH002259.

Abstract

The acid-catalysed protolysis of intermediates, formed either during one-electron reduction of substituted arylmercury salt (C6F5HgBr) or by the adsorption of bis(arylalkynyl)mercury compound [(PhC≡C)2Hg] on a Hg electrode has been found in lowacidic media (3 < pH < 6), whereas it was not observed in alkylmercury salt (PrnHgOAc).

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