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α-Pentafluoroethylated amines: a new synthetic approach

Martin Holger Königsmann 1, 2
Martin Holger Königsmann
, 
Enno Lork 2
Enno Lork
, 
Irina Leonovna Odinets 3
Irina Leonovna Odinets
, 
Valentin Georgievich Nenajdenko 4
Valentin Georgievich Nenajdenko
, 
Nikolaj Evgenievich Shevchenko 4
Nikolaj Evgenievich Shevchenko
, 
Gerd-Volker Röschenthaler 2
Gerd-Volker Röschenthaler
10.1070/MC2006v016n03ABEH002348
Published 2006-07-06
Communication , Volume 16, Issue 3, 141-143
5
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Königsmann M. H. et al. α-Pentafluoroethylated amines: a new synthetic approach // Mendeleev Communications. 2006. Vol. 16. No. 3. pp. 141-143.
GOST all authors (up to 50) Copy
Königsmann M. H., Lork E., Odinets I. L., Nenajdenko V. G., Shevchenko N. E., Röschenthaler G. α-Pentafluoroethylated amines: a new synthetic approach // Mendeleev Communications. 2006. Vol. 16. No. 3. pp. 141-143.
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TY - JOUR
DO - 10.1070/MC2006v016n03ABEH002348
UR - https://mendcomm.colab.ws/publications/10.1070/MC2006v016n03ABEH002348
TI - α-Pentafluoroethylated amines: a new synthetic approach
T2 - Mendeleev Communications
AU - Königsmann, Martin Holger
AU - Lork, Enno
AU - Odinets, Irina Leonovna
AU - Nenajdenko, Valentin Georgievich
AU - Shevchenko, Nikolaj Evgenievich
AU - Röschenthaler, Gerd-Volker
PY - 2006
DA - 2006/07/06
PB - Mendeleev Communications
SP - 141-143
IS - 3
VL - 16
ER -
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@article{2006_Königsmann,
author = {Martin Holger Königsmann and Enno Lork and Irina Leonovna Odinets and Valentin Georgievich Nenajdenko and Nikolaj Evgenievich Shevchenko and Gerd-Volker Röschenthaler},
title = {α-Pentafluoroethylated amines: a new synthetic approach},
journal = {Mendeleev Communications},
year = {2006},
volume = {16},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2006v016n03ABEH002348},
number = {3},
pages = {141--143},
doi = {10.1070/MC2006v016n03ABEH002348}
}
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Cite this
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Königsmann, Martin Holger, et al. “α-Pentafluoroethylated amines: a new synthetic approach.” Mendeleev Communications, vol. 16, no. 3, Jul. 2006, pp. 141-143. https://mendcomm.colab.ws/publications/10.1070/MC2006v016n03ABEH002348.

Abstract

Pentafluoroethyllithium generated from pentafluoroethane and n-butyl lithium added to selected imines, which were activated using BF3 etherate, furnished α-pentafluoroethylated amines and, unexpectedly, depending on the stoichiometry of the reactants, bis(pentafluoroethyl)fluoro-N-(isopropyl)diisopropyliminium borate, whose molecular structure was confirmed by X-ray diffraction.

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