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Thermal isomerisation of 1-chloro-1-fluoro-2-vinylcyclopropanes: competition between the vinylcyclopropane–cyclopentene rearrangement and cyclopropyl–allyl transformation

Nikolai Vasilevich Volchkov 1
Nikolai Vasilevich Volchkov
, 
Maria Borisovna Lipkind 1
Maria Borisovna Lipkind
, 
Alexander Vasilyvich Zabolotskikh 1
Alexander Vasilyvich Zabolotskikh
, 
Anatolii Victorovich Ignatenko 1
Anatolii Victorovich Ignatenko
, 
Oleg Matveevich Nefedov 1
Oleg Matveevich Nefedov
10.1070/MC2006v016n03ABEH002324
Published 2006-07-06
Communication , Volume 16, Issue 3, 153-155
5
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Volchkov N. V. et al. Thermal isomerisation of 1-chloro-1-fluoro-2-vinylcyclopropanes: competition between the vinylcyclopropane–cyclopentene rearrangement and cyclopropyl–allyl transformation // Mendeleev Communications. 2006. Vol. 16. No. 3. pp. 153-155.
GOST all authors (up to 50) Copy
Volchkov N. V., Lipkind M. B., Zabolotskikh A. V., Ignatenko A. V., Nefedov O. M. Thermal isomerisation of 1-chloro-1-fluoro-2-vinylcyclopropanes: competition between the vinylcyclopropane–cyclopentene rearrangement and cyclopropyl–allyl transformation // Mendeleev Communications. 2006. Vol. 16. No. 3. pp. 153-155.
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TY - JOUR
DO - 10.1070/MC2006v016n03ABEH002324
UR - https://mendcomm.colab.ws/publications/10.1070/MC2006v016n03ABEH002324
TI - Thermal isomerisation of 1-chloro-1-fluoro-2-vinylcyclopropanes: competition between the vinylcyclopropane–cyclopentene rearrangement and cyclopropyl–allyl transformation
T2 - Mendeleev Communications
AU - Volchkov, Nikolai Vasilevich
AU - Lipkind, Maria Borisovna
AU - Zabolotskikh, Alexander Vasilyvich
AU - Ignatenko, Anatolii Victorovich
AU - Nefedov, Oleg Matveevich
PY - 2006
DA - 2006/07/06
PB - Mendeleev Communications
SP - 153-155
IS - 3
VL - 16
ER -
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@article{2006_Volchkov,
author = {Nikolai Vasilevich Volchkov and Maria Borisovna Lipkind and Alexander Vasilyvich Zabolotskikh and Anatolii Victorovich Ignatenko and Oleg Matveevich Nefedov},
title = {Thermal isomerisation of 1-chloro-1-fluoro-2-vinylcyclopropanes: competition between the vinylcyclopropane–cyclopentene rearrangement and cyclopropyl–allyl transformation},
journal = {Mendeleev Communications},
year = {2006},
volume = {16},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2006v016n03ABEH002324},
number = {3},
pages = {153--155},
doi = {10.1070/MC2006v016n03ABEH002324}
}
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Volchkov, Nikolai Vasilevich, et al. “Thermal isomerisation of 1-chloro-1-fluoro-2-vinylcyclopropanes: competition between the vinylcyclopropane–cyclopentene rearrangement and cyclopropyl–allyl transformation.” Mendeleev Communications, vol. 16, no. 3, Jul. 2006, pp. 153-155. https://mendcomm.colab.ws/publications/10.1070/MC2006v016n03ABEH002324.

Abstract

The gas-phase pyrolysis of 1-chloro-1-fluoro-2-vinylcyclopropane and 1-chloro-1-fluoro-2-methyl-2-vinylcyclopropane at 305–360 °C afforded 4-chloro-4-fluorocyclopentenes and chlorofluorobutadienes as a result of competitive vinylcyclopropane–cyclopentene rearrangement and cyclopropyl–allyl isomerisation.

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