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Crystal structure of diaqua[N,N′-bis(tetrafluoropyridyl)diaza-18-crown-6]lead(II) perchlorate: the effect of perfluoroaromatic groups on the stucture of the complex

Petr Kirillovich Sazonov 1
Petr Kirillovich Sazonov
, 
Lidiya Khabibovna Minacheva 2
Lidiya Khabibovna Minacheva
, 
Vladimir Semenovich Sergienko 2
Vladimir Semenovich Sergienko
, 
Galina Anisimovna Artamkina 1
Galina Anisimovna Artamkina
, 
Yurii Fedorovich Oprunenko 1
Yurii Fedorovich Oprunenko
, 
10.1070/MC2006v016n03ABEH002323
Published 2006-07-06
Communication , Volume 16, Issue 3, 147-149
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Sazonov P. K. et al. Crystal structure of diaqua[N,N′-bis(tetrafluoropyridyl)diaza-18-crown-6]lead(II) perchlorate: the effect of perfluoroaromatic groups on the stucture of the complex // Mendeleev Communications. 2006. Vol. 16. No. 3. pp. 147-149.
GOST all authors (up to 50) Copy
Sazonov P. K., Minacheva L. K., Sergienko V. S., Artamkina G. A., Oprunenko Y. F., Beletskaya I. P. Crystal structure of diaqua[N,N′-bis(tetrafluoropyridyl)diaza-18-crown-6]lead(II) perchlorate: the effect of perfluoroaromatic groups on the stucture of the complex // Mendeleev Communications. 2006. Vol. 16. No. 3. pp. 147-149.
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TY - JOUR
DO - 10.1070/MC2006v016n03ABEH002323
UR - https://mendcomm.colab.ws/publications/10.1070/MC2006v016n03ABEH002323
TI - Crystal structure of diaqua[N,N′-bis(tetrafluoropyridyl)diaza-18-crown-6]lead(II) perchlorate: the effect of perfluoroaromatic groups on the stucture of the complex
T2 - Mendeleev Communications
AU - Sazonov, Petr Kirillovich
AU - Minacheva, Lidiya Khabibovna
AU - Sergienko, Vladimir Semenovich
AU - Artamkina, Galina Anisimovna
AU - Oprunenko, Yurii Fedorovich
AU - Beletskaya, Irina Petrovna
PY - 2006
DA - 2006/07/06
PB - Mendeleev Communications
SP - 147-149
IS - 3
VL - 16
ER -
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@article{2006_Sazonov,
author = {Petr Kirillovich Sazonov and Lidiya Khabibovna Minacheva and Vladimir Semenovich Sergienko and Galina Anisimovna Artamkina and Yurii Fedorovich Oprunenko and Irina Petrovna Beletskaya},
title = {Crystal structure of diaqua[N,N′-bis(tetrafluoropyridyl)diaza-18-crown-6]lead(II) perchlorate: the effect of perfluoroaromatic groups on the stucture of the complex},
journal = {Mendeleev Communications},
year = {2006},
volume = {16},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2006v016n03ABEH002323},
number = {3},
pages = {147--149},
doi = {10.1070/MC2006v016n03ABEH002323}
}
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Sazonov, Petr Kirillovich, et al. “Crystal structure of diaqua[N,N′-bis(tetrafluoropyridyl)diaza-18-crown-6]lead(II) perchlorate: the effect of perfluoroaromatic groups on the stucture of the complex.” Mendeleev Communications, vol. 16, no. 3, Jul. 2006, pp. 147-149. https://mendcomm.colab.ws/publications/10.1070/MC2006v016n03ABEH002323.

Abstract

According to X-ray analysis data, in the [PbL(H2O)2]2+ complex cation [L = N,N′-di(tetrafluoropyridyl)diaza-18-crown-6], the Pb atom is coordinated asymmetrically by four O(1)–O(4) atoms of the macrocycle and two O(5), O(6) atoms of water molecules, and, additionally, at longer distances, by the ortho-fluorine atoms F(4), F(5) of two perfluoropyridyl rings and the N(1), N(2) atoms of the macrocycle, thus demonstrating a partial localization of the lone electron pair of Pb. Using 1H NMR, the stability of the complex of L with Pb(ClO4)2 in [2H6]acetone was estimated (log β = 0.9).

References

3.
10.1070/MC2006v016n03ABEH002323_bib3
Sazonov
Zh. Org. Khim, 2006
4.
Thermodynamic and Kinetic Data for Macrocycle Interaction with Cations, Anions, and Neutral Molecules
Izatt R.M., Pawlak K., Bradshaw J.S., Bruening R.L.
Chemical Reviews, 1995
5.
10.1070/MC2006v016n03ABEH002323_bib5
Sazonov
Izv. Akad. Nauk, Ser. Khim., 2005
6.
L. Kh. Minacheva, P. K. Sazonov, V. S. Sergienko, G. A. Artamkina,I. P. Beletskaya and A. Yu. Tsivadze, Zh. Neorg. Khim., 2006, 51, in press.
7.
10.1070/MC2006v016n03ABEH002323_bib7
Sheldrick
SHELXS-97. Program for the Solution of Crystal Structures, 1997
8.
10.1070/MC2006v016n03ABEH002323_bib8
Sheldrick
SHELXL-97. Program for the Refinement of Crystal Structures, 1997
9.
Shelxtl, version 1, Bruker AXS Inc., Madison, Wisconsin, USA, 1998.
10.
10.1070/MC2006v016n03ABEH002323_bib10
Gillespie
The VSEPR Model of Molecular Geometry, 1991
11.
10.1070/MC2006v016n03ABEH002323_bib11
Minacheva
Kristallografiya, 2004
12.
The Cambridge Structural Database: a quarter of a million crystal structures and rising
Allen F.H.
Acta Crystallographica Section B Structural Science, 2002
13.
Structure and ion-complexing properties of an aza-15-crown-5 ether dye: Synthesis, crystallography, NMR spectroscopy, spectrophotometry and potentiometry
Alfimov M.V., Churakov A.V., Fedorov Y.V., Fedorova O.A., Gromov S.P., Hester R.E., Howard J.A., Kuz’mina L.G., Lednev I.K., Moore J.N.
Journal of the Chemical Society Perkin Transactions 2, 1997