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Preparation of organozinc compounds from 3-chloroheptafluorotoluene and zinc: the participation of C–F bonds

Vyacheslav Ivanovich Krasnov 1
Vyacheslav Ivanovich Krasnov
, 
Andrey Sergeevich Vinogradov 1
Andrey Sergeevich Vinogradov
, 
Vyacheslav Evdokimovich Platonov 1
Vyacheslav Evdokimovich Platonov
10.1070/MC2006v016n03ABEH002266
Published 2006-07-06
Communication , Volume 16, Issue 3, 168-170
7
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Krasnov V. I., Vinogradov A. S., Platonov V. E. Preparation of organozinc compounds from 3-chloroheptafluorotoluene and zinc: the participation of C–F bonds // Mendeleev Communications. 2006. Vol. 16. No. 3. pp. 168-170.
GOST all authors (up to 50) Copy
Krasnov V. I., Vinogradov A. S., Platonov V. E. Preparation of organozinc compounds from 3-chloroheptafluorotoluene and zinc: the participation of C–F bonds // Mendeleev Communications. 2006. Vol. 16. No. 3. pp. 168-170.
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TY - JOUR
DO - 10.1070/MC2006v016n03ABEH002266
UR - https://mendcomm.colab.ws/publications/10.1070/MC2006v016n03ABEH002266
TI - Preparation of organozinc compounds from 3-chloroheptafluorotoluene and zinc: the participation of C–F bonds
T2 - Mendeleev Communications
AU - Krasnov, Vyacheslav Ivanovich
AU - Vinogradov, Andrey Sergeevich
AU - Platonov, Vyacheslav Evdokimovich
PY - 2006
DA - 2006/07/06
PB - Mendeleev Communications
SP - 168-170
IS - 3
VL - 16
ER -
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@article{2006_Krasnov,
author = {Vyacheslav Ivanovich Krasnov and Andrey Sergeevich Vinogradov and Vyacheslav Evdokimovich Platonov},
title = {Preparation of organozinc compounds from 3-chloroheptafluorotoluene and zinc: the participation of C–F bonds},
journal = {Mendeleev Communications},
year = {2006},
volume = {16},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2006v016n03ABEH002266},
number = {3},
pages = {168--170},
doi = {10.1070/MC2006v016n03ABEH002266}
}
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Krasnov, Vyacheslav Ivanovich, et al. “Preparation of organozinc compounds from 3-chloroheptafluorotoluene and zinc: the participation of C–F bonds.” Mendeleev Communications, vol. 16, no. 3, Jul. 2006, pp. 168-170. https://mendcomm.colab.ws/publications/10.1070/MC2006v016n03ABEH002266.

Abstract

Organozinc compounds were obtained from 3-chloroheptafluorotoluene and Zn in DMF; the C–Cl bond is mainly involved in this reaction; the addition of SnCl2 changes the main reaction course in the direction of the participation of the C–F bond (para to the CF3 group).

References

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Wakefield
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The Reaction of Active Zinc with Organic Bromides
Guijarro A., Rosenberg D.M., Rieke R.D.
Journal of the American Chemical Society, 1999