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Oxidation of a cysteinato ligand by peroxodisulfate in a water-methanol solvent

Marián Palcut 1
Marián Palcut
10.1070/MC2006v016n02ABEH002279
Published 2006-04-14
Communication , Volume 16, Issue 2, 106-107
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Palcut M. Oxidation of a cysteinato ligand by peroxodisulfate in a water-methanol solvent // Mendeleev Communications. 2006. Vol. 16. No. 2. pp. 106-107.
GOST all authors (up to 50) Copy
Palcut M. Oxidation of a cysteinato ligand by peroxodisulfate in a water-methanol solvent // Mendeleev Communications. 2006. Vol. 16. No. 2. pp. 106-107.
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TY - JOUR
DO - 10.1070/MC2006v016n02ABEH002279
UR - https://mendcomm.colab.ws/publications/10.1070/MC2006v016n02ABEH002279
TI - Oxidation of a cysteinato ligand by peroxodisulfate in a water-methanol solvent
T2 - Mendeleev Communications
AU - Palcut, Marián
PY - 2006
DA - 2006/04/14
PB - Mendeleev Communications
SP - 106-107
IS - 2
VL - 16
ER -
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@article{2006_Palcut,
author = {Marián Palcut},
title = {Oxidation of a cysteinato ligand by peroxodisulfate in a water-methanol solvent},
journal = {Mendeleev Communications},
year = {2006},
volume = {16},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2006v016n02ABEH002279},
number = {2},
pages = {106--107},
doi = {10.1070/MC2006v016n02ABEH002279}
}
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Palcut, Marián. “Oxidation of a cysteinato ligand by peroxodisulfate in a water-methanol solvent.” Mendeleev Communications, vol. 16, no. 2, Apr. 2006, pp. 106-107. https://mendcomm.colab.ws/publications/10.1070/MC2006v016n02ABEH002279.

Abstract

The rate of peroxodisulfate oxidation of a cysteinato ligand in a water-rich binary solvent decreases with methanol content due to the preferential solvation of {Co(en)2[SCH2CH(COO)NH2]}+.

References

1.
Cobalt(III) complexes of cysteine and cysteine derivatives
Kothari V.M., Busch D.H.
Inorganic Chemistry, 1969
4.
Synthesis, characterization, and reactivity of coordinated sulfenic acids
Adzamli I.K., Libson K., Lydon J.D., Elder R.C., Deutsch E.
Inorganic Chemistry, 1979
5.
10.1070/MC2006v016n02ABEH002279_bib5
English
Metal Ions in Biological Systems, 2001
6.
Solvent effects on the kinetics of oxidation of cysteinatobis(ethylenediamine)cobalt(III) ion by peroxodisulphate
Vollárová O., Benko J.
Journal of the Chemical Society Dalton Transactions, 1983
8.
Kinetics of reactions in aqueous mixtures
Blandamer M.J., Burgess J.
Chemical Society Reviews, 1975
9.
Water: a Comprehensive Treatise, ed. F. Franks, Plenum Press, New York, 1979, p. 144.
10.
Characterization of binary solvent mixtures: the water–acetonitrile mixture
Catalán J., Díaz C., García-Blanco F.
Organic and Biomolecular Chemistry, 2003
13.
Solvent Effect on the Kinetics of Oxidation of [Co(en)2SCH2CH2 NH2]2+ by S2O8 2−
Vollárová O., Grančičová O., Benko J., Holba V.
Transition Metal Chemistry, 1998
16.
Single-ion gibbs energies, enthalpies and entropies of transfer from water to aqueous methanol based on the (Ph4P+, Ph4As+)= Ph4B– assumption
Abraham M.H., Hill T., Ling H.C., Schulz R.A., Watt R.A.
Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases, 1984
18.
Initial state and transition state solvation in inorganic reactions
Blandamer M.J., Burgess J.
Coordination Chemistry Reviews, 1980