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1-(Alk-1-ynyl)cyclopropenes: synthesis by interaction of 1-(alk-1-ynyl)-1-halocyclopropanes with lithium N,N-dialkylamides and subsequent additions of the latter

Konstantin Nikolaevich Shavrin 1
Konstantin Nikolaevich Shavrin
, 
Valentin Dmitrievich Gvozdev 1
Valentin Dmitrievich Gvozdev
, 
Dmitry Vladimirovich Budanov 2
Dmitry Vladimirovich Budanov
, 
Serafim Vladimirovich Yurov 3
Serafim Vladimirovich Yurov
, 
Oleg Matveevich Nefedov 1
Oleg Matveevich Nefedov
10.1070/MC2006v016n02ABEH002267
Published 2006-04-14
Communication , Volume 16, Issue 2, 73-76
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Shavrin K. N. et al. 1-(Alk-1-ynyl)cyclopropenes: synthesis by interaction of 1-(alk-1-ynyl)-1-halocyclopropanes with lithium N,N-dialkylamides and subsequent additions of the latter // Mendeleev Communications. 2006. Vol. 16. No. 2. pp. 73-76.
GOST all authors (up to 50) Copy
Shavrin K. N., Gvozdev V. D., Budanov D. V., Yurov S. V., Nefedov O. M. 1-(Alk-1-ynyl)cyclopropenes: synthesis by interaction of 1-(alk-1-ynyl)-1-halocyclopropanes with lithium N,N-dialkylamides and subsequent additions of the latter // Mendeleev Communications. 2006. Vol. 16. No. 2. pp. 73-76.
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TY - JOUR
DO - 10.1070/MC2006v016n02ABEH002267
UR - https://mendcomm.colab.ws/publications/10.1070/MC2006v016n02ABEH002267
TI - 1-(Alk-1-ynyl)cyclopropenes: synthesis by interaction of 1-(alk-1-ynyl)-1-halocyclopropanes with lithium N,N-dialkylamides and subsequent additions of the latter
T2 - Mendeleev Communications
AU - Shavrin, Konstantin Nikolaevich
AU - Gvozdev, Valentin Dmitrievich
AU - Budanov, Dmitry Vladimirovich
AU - Yurov, Serafim Vladimirovich
AU - Nefedov, Oleg Matveevich
PY - 2006
DA - 2006/04/14
PB - Mendeleev Communications
SP - 73-76
IS - 2
VL - 16
ER -
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@article{2006_Shavrin,
author = {Konstantin Nikolaevich Shavrin and Valentin Dmitrievich Gvozdev and Dmitry Vladimirovich Budanov and Serafim Vladimirovich Yurov and Oleg Matveevich Nefedov},
title = {1-(Alk-1-ynyl)cyclopropenes: synthesis by interaction of 1-(alk-1-ynyl)-1-halocyclopropanes with lithium N,N-dialkylamides and subsequent additions of the latter},
journal = {Mendeleev Communications},
year = {2006},
volume = {16},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2006v016n02ABEH002267},
number = {2},
pages = {73--76},
doi = {10.1070/MC2006v016n02ABEH002267}
}
MLA
Cite this
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Shavrin, Konstantin Nikolaevich, et al. “1-(Alk-1-ynyl)cyclopropenes: synthesis by interaction of 1-(alk-1-ynyl)-1-halocyclopropanes with lithium N,N-dialkylamides and subsequent additions of the latter.” Mendeleev Communications, vol. 16, no. 2, Apr. 2006, pp. 73-76. https://mendcomm.colab.ws/publications/10.1070/MC2006v016n02ABEH002267.

Abstract

A new synthetic approach to 1-(alk-1-ynyl)cyclopropenes 2 by the reaction of 1-(alk-1-ynyl)-1-chlorocyclopropanes 1 with lithium N,N-dialkylamides has been developed. Alkynylcyclopropenes 2, obtained by this method in situ or isolated in individual state can add dialkylamide anions across the double bond of the cyclopropene fragment to give hitherto unknown alkynyl-(dialkylamino)cyclopropanes 3, 4.

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